Vanadium tetrachloride is the
inorganic compound
In chemistry, an inorganic compound is typically a chemical compound that lacks carbon–hydrogen bonds, that is, a compound that is not an organic compound. The study of inorganic compounds is a subfield of chemistry known as '' inorganic chemist ...
with the formula
V Cl4. This bright red liquid serves as a useful
reagent
In chemistry, a reagent ( ) or analytical reagent is a substance or compound added to a system to cause a chemical reaction, or test if one occurs. The terms ''reactant'' and ''reagent'' are often used interchangeably, but reactant specifies a ...
for the preparation of other
vanadium
Vanadium is a chemical element with the symbol V and atomic number 23. It is a hard, silvery-grey, malleable transition metal. The elemental metal is rarely found in nature, but once isolated artificially, the formation of an oxide layer ( pas ...
compounds.
Synthesis, bonding, basic properties
With one more valence electron than
diamagnetic
Diamagnetic materials are repelled by a magnetic field; an applied magnetic field creates an induced magnetic field in them in the opposite direction, causing a repulsive force. In contrast, paramagnetic and ferromagnetic materials are attracted ...
TiCl4, VCl
4 is a
paramagnetic
Paramagnetism is a form of magnetism whereby some materials are weakly attracted by an externally applied magnetic field, and form internal, induced magnetic fields in the direction of the applied magnetic field. In contrast with this behavior, d ...
liquid. It is one of only a few paramagnetic compounds that is liquid at room temperature.
VCl
4 is prepared by chlorination of vanadium metal. VCl
5 does not form in this reaction; Cl
2 lacks the oxidizing power to attack VCl
4.
VCl5 can however be prepared indirectly from
VF5 at −78 °C. In contrast, the heavier analogues
NbCl5 and
TaCl5 are stable and not particularly oxidizing. VF
5 can be prepared directly by fluorination of vanadium metal, reflecting the increased oxidizing power of
F2 vs
Cl2. Indicative of its oxidizing power, VCl
4 releases Cl
2 at its boiling point (standard pressure) to afford
VCl3.
Reactions
Consistent with its high oxidizing power, VCl
4 reacts with HBr at -50 °C to produce
VBr3. The reaction proceeds via VBr
4, which releases Br
2 during warming to room temperature.
:2 VCl
4 + 8 HBr → 2 VBr
3 + 8 HCl + Br
2
VCl
4 forms
adduct
An adduct (from the Latin ''adductus'', "drawn toward" alternatively, a contraction of "addition product") is a product of a direct addition of two or more distinct molecules, resulting in a single reaction product containing all atoms of all co ...
s with many donor ligands, for example, VCl
4(
THF
Tetrahydrofuran (THF), or oxolane, is an organic compound with the formula (CH2)4O. The compound is classified as heterocyclic compound, specifically a cyclic ether. It is a colorless, water- miscible organic liquid with low viscosity. It is ...
)
2.
It is the precursor to
vanadocene dichloride
Vanadocene dichloride is an organometallic complex with formula (hapticity, ''η''5-cyclopentadienyl, C5H5)2VCl2 (commonly abbreviated as Cp2VCl2). It is a structural analogue of titanocene dichloride but with vanadium(IV) instead of titanium(IV). ...
.
Organic chemistry
In
organic synthesis
Organic synthesis is a special branch of chemical synthesis and is concerned with the intentional construction of organic compounds. Organic molecules are often more complex than inorganic compounds, and their synthesis has developed into one o ...
, VCl
4 is used for the
oxidative coupling Oxidative coupling in chemistry is a coupling reaction of two molecular entities through an oxidative process. Usually oxidative couplings are catalysed by a transition metal complex like in classical cross-coupling reactions, although the underly ...
of phenols. For example, it converts
phenol
Phenol (also called carbolic acid) is an aromatic organic compound with the molecular formula . It is a white crystalline solid that is volatile. The molecule consists of a phenyl group () bonded to a hydroxy group (). Mildly acidic, it req ...
into a mixture of 4,4'-, 2,4'-, and 2,2'-
biphenol
In organic chemistry, a biphenol refers to compounds with the formula (C6H4OH)2. Such compounds formally result from the coupling of two phenols.
{{short description, Chemical compound
Three symmetrical isomer
In chemistry, isomers are mol ...
s:
:2 C
6H
5OH + 2 VCl
4 → HOC
6H
4–C
6H
4OH + 2 VCl
3 + 2 HCl
Applications
VCl
4 is a catalyst for the polymerization of alkenes, especially those useful in the rubber industry. The underlying technology is related to
Ziegler–Natta catalysis, which involves the intermediacy of vanadium alkyls.
Safety considerations
VCl
4 is a volatile, aggressive oxidant that readily hydrolyzes to release
HCl HCL may refer to:
Science and medicine
* Hairy cell leukemia, an uncommon and slowly progressing B cell leukemia
* Harvard Cyclotron Laboratory, from 1961 to 2002, a proton accelerator used for research and development
* Hollow-cathode lamp, a spe ...
.
References
{{Chlorides
Vanadium(IV) compounds
Chlorides
Metal halides
Reagents for organic chemistry