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Sticky-shed syndrome is a condition created by the deterioration of the binders in a magnetic tape, which hold the
ferric oxide Iron(III) oxide or ferric oxide is the inorganic compound with the formula Fe2O3. It is one of the three main oxides of iron, the other two being iron(II) oxide (FeO), which is rare; and iron(II,III) oxide (Fe3O4), which also occurs naturall ...
magnetizable coating to its plastic carrier, or which hold the thinner back-coating on the outside of the tape. This deterioration renders the tape unusable. Some kinds of binder are known to break down over time, due to the absorption of
moisture Moisture is the presence of a liquid, especially water, often in trace amounts. Small amounts of water may be found, for example, in the air (humidity), in foods, and in some commercial products. Moisture also refers to the amount of water vapo ...
(
hydrolysis Hydrolysis (; ) is any chemical reaction in which a molecule of water breaks one or more chemical bonds. The term is used broadly for substitution, elimination, and solvation reactions in which water is the nucleophile. Biological hydrolys ...
). The symptoms of this breakdown can be immediately obvious even when rewinding the tape: tearing sounds and sluggish behavior. If a tape with sticky-shed syndrome is played, the reels will make screeching or squeaking sounds, and the tape will leave dusty, rusty particles on the guides and heads. In some cases, particularly with digital tapes, the symptoms are more subtle, causing intermittent dropouts.


Cause

Some tapes may deteriorate because of a breakdown in the binder (the glue) that holds the oxide particles on the tape, or the back coating on the reverse side, if the tape was from any of the tape manufacturers who had inadvertently used an unstable binder formulation. That binder contained polyurethane that soaks up water (
Hydrolysis Hydrolysis (; ) is any chemical reaction in which a molecule of water breaks one or more chemical bonds. The term is used broadly for substitution, elimination, and solvation reactions in which water is the nucleophile. Biological hydrolys ...
) and causes the urethane to rise to the tape's surface. This problem became known as the 'sticky-shed syndrome'. One explanation offered was that short strands of urethane were commonly used in tapes until it was discovered that mid-sized strands are better and were good at absorbing moisture. Baking the tape at low temperature may temporarily restore the tape by driving the water molecules from the binder so that it can be safely copied to another tape or a different format. After baking, the tape may remain in good condition for approximately a month. If the tape re-deteriorates, it may be possible to bake the tape again.


Affected stock

Many tapes affected by sticky-shed are those that were made by
Ampex Ampex is an American electronics company founded in 1944 by Alexander M. Poniatoff as a spin-off of Dalmo-Victor. The name AMPEX is a portmanteau, created by its founder, which stands for Alexander M. Poniatoff Excellence.AbramsoThe History ...
/
Quantegy Quantegy Inc. was a manufacturer of magnetic tape and professional external hard drives based in Opelika, Alabama. Their tape products were primarily used in analog audio and video recording studios, but they also have some use with digital dat ...
such as 406/407, 456/457, 499, and consumer/audiophile grade back coated tapes such as Grand Master and 20-20+. Tapes made by Scotch/3M are also affected and the most common offenders here are the "pro" tapes such as 206/207, 226/227, 262 (though not all 262 is backcoated and therefore isn't affected), 808, and 986 as well as
audiophile An audiophile is a person who is enthusiastic about high-fidelity sound reproduction. An audiophile seeks to reproduce the sound of a piece of recorded music or a live musical performance, typically inside closed headphones, In-ear monitors, open ...
tapes such as "Classic" and "Master-XS". Though less common, many
Sony , commonly stylized as SONY, is a Japanese multinational conglomerate corporation headquartered in Minato, Tokyo, Japan. As a major technology company, it operates as one of the world's largest manufacturers of consumer and professiona ...
branded tapes such as PR-150, SLH, ULH, and FeCr have also been reported to suffer from sticky-shed. Blank cassettes from the 70s-90s are unaffected because the hygroscopic binder was not used in cassette formulations. However, some cassette tape formulations do suffer from a similar problem caused by fatty acids working to the surface of the tape that can cause sticking to heads and guides and severe modulation of signals through the playback head until it is cleaned. Ampex-branded u-matic cassette tapes are also now exhibiting sticky-shed problems, similar to their reel tape media. As of 2012, there are no documented or proven examples of sticky-shed from
Maxell , commonly known as Maxell, is a Japanese company that manufactures consumer electronics. The company's name is a contraction of "Maximum capacity dry cell". Its main products are batteries, wireless charging products, storage devices, LCD/laser ...
. TDK has been showing signs as of late of shedding its lubricant in the form of a white powder or white/yellowish goo. This has shown up on the TDK SA and some LX and BX tapes. There have been a few reports of some tape from the current manufacturers ATR and
RMGI Recording Media Group International B.V., sometimes also named as Recordable Media Group International (also known as RMGi) was a Dutch manufacturer of magnetic tape products based in Oosterhout. This plant was initially built by Philips in 1968, ...
exhibiting symptoms of sticky-shed. But these may be isolated incidents relating to prototype or single bad batches and are not necessarily indicative of the overall product line integrity.
BASF BASF SE () is a German multinational chemical company and the largest chemical producer in the world. Its headquarters is located in Ludwigshafen, Germany. The BASF Group comprises subsidiaries and joint ventures in more than 80 countries ...
tape production did not use the unstable formulation, and their tape production rarely shows this type of coating instability, although BASF LH Super SM cassettes manufactured in the mid-70s are prone to the problem. Certain batches of Chromdioxid Extra II C-90s, produced around 1989-1991 and sold in the UK, shed a white powder that would coat the record/playback head after a few months of use. The slightly higher performance Chromdioxid Super II and Chromdioxid Maxima C-90 cassettes were unaffected. As of 2015, some 35 mm magnetic fullcoat tapes produced by
Kodak The Eastman Kodak Company (referred to simply as Kodak ) is an American public company that produces various products related to its historic basis in analogue photography. The company is headquartered in Rochester, New York, and is incorpor ...
, such as those used for the audio portion of older IMAX films, are also reported to be exhibiting sticky-shed. As tapes remain in storage for a longer time, it is possible that other binder formulations may develop problems.


Solutions

Current solutions to sticky-shed syndrome seek to safely remove the unwanted moisture from the tape binder. Two different strategies are commonly employed: applying heat to the tape (commonly called 'baking'), and changing the environment to lower the
humidity Humidity is the concentration of water vapor present in the air. Water vapor, the gaseous state of water, is generally invisible to the human eye. Humidity indicates the likelihood for precipitation, dew, or fog to be present. Humidity dep ...
. Baking is widely practiced but can destroy tapes. While modification of humidity by safely controlling the environment may take significantly longer, its major benefit is that it does not irreparably damage the tape. Alternative practices have also been developed by engineers to repair affected tapes.


Baking

Baking is a common practice for temporarily repairing sticky-shed syndrome. There is no standard equipment or practice for baking, so each engineer is left to create their own methods and materials. Generally, tapes are baked at low temperatures for relatively long periods of time, such as 130 °F to 140 °F (54 to 60 °C) for 1 to 8 hours. Wider than 1/4 inch tape formats may take longer. It is commonly thought that baking a tape will temporarily remove the moisture that has accumulated in the binder. A treated tape will reportedly function like new for a few weeks to a few months before it will reabsorb moisture and be unplayable again. Baking cannot be used with acetate tapes, nor is it needed. Baking is also much less effective with
U-matic U-matic is an analogue recording Videocassette#Cassette formats, videocassette format first shown by Sony in prototype in October 1969, and introduced to the market in September 1971. It was among the first video formats to contain the vide ...
tapes as the cases for those tapes prevent effective air circulation within the tape media, limiting its ability to remove moisture.


Necessity

Tape baking is a somewhat risky procedure, since there is a risk of damaging the tape from the heat. However, there are some important signs that show when a tape needs baking. The usual symptom is squealing when the tape passes the playback head or other fixed parts of a tape player. The squealing is audible directly from the tape and usually also transmitted electronically through the output of the tape recorder as a wideband distortion of the playback signal. Continuous use of a squealing tape risks permanently damaging the tape, as oxide is sometimes torn off the tape. This flaking residue can be seen and can feel gummy while still on the tape's surface. There is also a risk of damage to the player. Another symptom is the tape sounding dull and distorted. In a video recording, degradation can be represented by audio-visual dropouts.


References


Further reading

* Holmes, T. (Ed.) (2006). The Routledge guide to music technology. New York: Taylor & Francis Group.


External links


Much info on recovering vintage video(tapes)

Explanation on "sticky-shed" syndrome




* ttps://web.archive.org/web/20071012122634/http://www.amianet.org/publication/resources/guidelines/videofacts/commonprobs.html Association of Moving Image Archives on sticky-shed syndrome for Videotape
Step-by-step guide on tape baking by Dave Luepke

Cups ‘N Strings saves 50 Record Plant live recordings.

Master preservation

Tape Resources Online



Method confirmed and it works
{{DEFAULTSORT:Sticky-Shed Syndrome Audio storage Computer storage tape media Magnetic devices Tape recording Digital preservation