In
quantum mechanics
Quantum mechanics is the fundamental physical Scientific theory, theory that describes the behavior of matter and of light; its unusual characteristics typically occur at and below the scale of atoms. Reprinted, Addison-Wesley, 1989, It is ...
, the total angular momentum quantum number parametrises the total
angular momentum
Angular momentum (sometimes called moment of momentum or rotational momentum) is the rotational analog of Momentum, linear momentum. It is an important physical quantity because it is a Conservation law, conserved quantity – the total ang ...
of a given
particle, by combining its
orbital angular momentum and its intrinsic angular momentum (i.e., its
spin).
If s is the particle's spin angular momentum and ℓ its orbital angular momentum vector, the total angular momentum j is
The associated quantum number is the main total angular momentum quantum number ''j''. It can take the following range of values, jumping only in integer steps:
where ''ℓ'' is the
azimuthal quantum number (parameterizing the orbital angular momentum) and ''s'' is the
spin quantum number (parameterizing the spin).
The relation between the total angular momentum vector j and the total angular momentum quantum number ''j'' is given by the usual relation (see
angular momentum quantum number)
The vector's ''z''-projection is given by
where ''m
j'' is the secondary total angular momentum quantum number, and the
is the
reduced Planck constant
The Planck constant, or Planck's constant, denoted by h, is a fundamental physical constant of foundational importance in quantum mechanics: a photon's energy is equal to its frequency multiplied by the Planck constant, and the wavelength of a ...
. It ranges from −''j'' to +''j'' in steps of one. This generates 2''j'' + 1 different values of ''m''
''j''.
The total angular momentum corresponds to the
Casimir invariant of the
Lie algebra
In mathematics, a Lie algebra (pronounced ) is a vector space \mathfrak g together with an operation called the Lie bracket, an alternating bilinear map \mathfrak g \times \mathfrak g \rightarrow \mathfrak g, that satisfies the Jacobi ident ...
so(3) of the three-dimensional
rotation group.
See also
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Principal quantum number
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Orbital angular momentum quantum number
*
Magnetic quantum number
*
Spin quantum number
*
Angular momentum coupling
In quantum mechanics, angular momentum coupling is the procedure of constructing eigenstates of total angular momentum out of eigenstates of separate angular momenta. For instance, the orbit and spin of a single particle can interact through spi ...
*
Clebsch–Gordan coefficients
*
Angular momentum diagrams (quantum mechanics)
*
Rotational spectroscopy
References
*
*
Albert Messiah, (1966). ''Quantum Mechanics'' (Vols. I & II), English translation from French by G. M. Temmer. North Holland, John Wiley & Sons.
External links
Vector model of angular momentum
Angular momentum
Atomic physics
Quantum numbers
Rotation in three dimensions
Rotational symmetry
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