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Tetramethylethylene is a
hydrocarbon In organic chemistry, a hydrocarbon is an organic compound consisting entirely of hydrogen and carbon. Hydrocarbons are examples of group 14 hydrides. Hydrocarbons are generally colourless and hydrophobic, and their odors are usually weak or ...
with the formula Me2C=CMe2 (Me = methyl). A colorless liquid, it is the simplest tetrasubstituted
alkene In organic chemistry, an alkene is a hydrocarbon containing a carbon–carbon double bond. Alkene is often used as synonym of olefin, that is, any hydrocarbon containing one or more double bonds.H. Stephen Stoker (2015): General, Organic, an ...
.


Synthesis and reactions

It is prepared by base-catalyzed isomerization of 2,3-dimethyl-1-butene. Tetramethylethylene forms metal-alkene complexes with low-valent metals and reacts with
diborane Diborane(6), generally known as diborane, is the chemical compound with the formula B2H6. It is a toxic, colorless, and pyrophoric gas with a repulsively sweet odor. Diborane is a key boron compound with a variety of applications. It has attracte ...
to give the monoalkyborane known as thexylborane.{{cite book, doi=10.1002/9780470132593.ch22, time=Di-μ-Chloro-Bis(η4-1,5-Cyclooctadiene)-Dirhodium(I), title=Inorganic Syntheses, pages=88–90, year=1990, volume=28, last1=Giordano, first1=G., last2=Crabtree, first2=R. H., chapter=Di-μ-Chloro-Bis(η4 -1,5-Cyclooctadiene)-Dirhodium(I), isbn=9780470132593


References

Alkenes