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Tarnish is a thin layer of
Heavy tarnish can be mechanically removed by using tools such as a file or abrasive materials such as steel wool, sandpaper, emery paper, and heavy
Tarnish is a thin layer of corrosion
Corrosion is a natural process that converts a refined metal into a more chemically stable oxide. It is the gradual deterioration of materials (usually a metal) by chemical or electrochemical reaction with their environment. Corrosion engine ...
that forms over copper
Copper is a chemical element; it has symbol Cu (from Latin ) and atomic number 29. It is a soft, malleable, and ductile metal with very high thermal and electrical conductivity. A freshly exposed surface of pure copper has a pinkish-orang ...
, brass
Brass is an alloy of copper and zinc, in proportions which can be varied to achieve different colours and mechanical, electrical, acoustic and chemical properties, but copper typically has the larger proportion, generally copper and zinc. I ...
, aluminum
Aluminium (or aluminum in North American English) is a chemical element; it has chemical symbol, symbol Al and atomic number 13. It has a density lower than that of other common metals, about one-third that of steel. Aluminium has ...
, magnesium
Magnesium is a chemical element; it has Symbol (chemistry), symbol Mg and atomic number 12. It is a shiny gray metal having a low density, low melting point and high chemical reactivity. Like the other alkaline earth metals (group 2 ...
, neodymium
Neodymium is a chemical element; it has Symbol (chemistry), symbol Nd and atomic number 60. It is the fourth member of the lanthanide series and is considered to be one of the rare-earth element, rare-earth metals. It is a hard (physics), hard, sli ...
and other similar metals as their outermost layer undergoes a chemical reaction. Tarnish does not always result from the sole effects of oxygen in the air. For example, silver needs hydrogen sulfide
Hydrogen sulfide is a chemical compound with the formula . It is a colorless chalcogen-hydride gas, and is toxic, corrosive, and flammable. Trace amounts in ambient atmosphere have a characteristic foul odor of rotten eggs. Swedish chemist ...
to tarnish, although it may tarnish with oxygen over time. It often appears as a dull, gray or black film or coating over metal. Tarnish is a surface phenomenon that is self-limiting, unlike rust. Only the top few layers of the metal react. The layer of tarnish seals and protects the underlying layers from reacting.
Tarnish preserves the underlying metal in outdoor use, and in this form is called chemical patina, an example of which is the green or blue-green form of copper(II) carbonate known as verdigris
Verdigris () is a common name for any of a variety of somewhat toxic copper salt (chemistry), salts of acetic acid, which range in colour from green to a blue-green, bluish-green depending on their chemical composition.H. Kühn, Verdigris and Cop ...
. Unlike patina advantageous in applications such as copper roofing and copper, bronze, and brass statues and fittings exposed to the elements, a chemical patina may be considered undesirable, as on silverware, or a matter of taste or convention, as in toning on coins.
Chemistry
Tarnish is a product of achemical reaction
A chemical reaction is a process that leads to the chemistry, chemical transformation of one set of chemical substances to another. When chemical reactions occur, the atoms are rearranged and the reaction is accompanied by an Gibbs free energy, ...
between a metal
A metal () is a material that, when polished or fractured, shows a lustrous appearance, and conducts electrical resistivity and conductivity, electricity and thermal conductivity, heat relatively well. These properties are all associated wit ...
and a nonmetal compound, especially oxygen
Oxygen is a chemical element; it has chemical symbol, symbol O and atomic number 8. It is a member of the chalcogen group (periodic table), group in the periodic table, a highly reactivity (chemistry), reactive nonmetal (chemistry), non ...
and sulfur dioxide
Sulfur dioxide (IUPAC-recommended spelling) or sulphur dioxide (traditional Commonwealth English) is the chemical compound with the formula . It is a colorless gas with a pungent smell that is responsible for the odor of burnt matches. It is r ...
. It is usually a metal oxide
An oxide () is a chemical compound containing at least one oxygen atom and one other element in its chemical formula. "Oxide" itself is the dianion (anion bearing a net charge of −2) of oxygen, an O2− ion with oxygen in the oxidation st ...
, the product of oxidation
Redox ( , , reduction–oxidation or oxidation–reduction) is a type of chemical reaction in which the oxidation states of the reactants change. Oxidation is the loss of electrons or an increase in the oxidation state, while reduction is ...
; sometimes it is a metal sulfide. The metal oxide sometimes reacts with water to make the hydroxide, or with carbon dioxide to make the carbonate. It is a chemical change. There are various methods to prevent metals from tarnishing.
Prevention and removal
Heavy tarnish can be mechanically removed by using tools such as a file or abrasive materials such as steel wool, sandpaper, emery paper, and heavy polishing
Polishing is the process of creating a smooth and shiny surface by rubbing it or by applying a chemical treatment, leaving a clean surface with a significant specular reflection (still limited by the index of refraction of the material accordi ...
compounds. Lighter tarnish may be abrasively removed with lighter polishing compounds or chemicals such as baking soda
Sodium bicarbonate (IUPAC name: sodium hydrogencarbonate), commonly known as baking soda or bicarbonate of soda (or simply “bicarb” especially in the UK) is a chemical compound with the formula NaHCO3. It is a salt (chemistry), salt compose ...
. Gentler abrasives, such as calcium carbonate
Calcium carbonate is a chemical compound with the chemical formula . It is a common substance found in Rock (geology), rocks as the minerals calcite and aragonite, most notably in chalk and limestone, eggshells, gastropod shells, shellfish skel ...
, are often used by museums to clean tarnished silver
Silver is a chemical element; it has Symbol (chemistry), symbol Ag () and atomic number 47. A soft, whitish-gray, lustrous transition metal, it exhibits the highest electrical conductivity, thermal conductivity, and reflectivity of any metal. ...
, which will not scratch it or leave unwanted residues. Objects such as silverware may have their tarnish non-destructively reversed electrochemically by resting them on a piece of aluminium foil in a pot of boiling water with a small amount of salt or baking soda.
References
{{Reflist Chemical reactions Metals Metalworking terminology Corrosion