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The Steinhart–Hart equation is a model of the resistance of a
semiconductor A semiconductor is a material which has an electrical conductivity value falling between that of a conductor, such as copper, and an insulator, such as glass. Its resistivity falls as its temperature rises; metals behave in the opposite way. ...
at different
temperature Temperature is a physical quantity that expresses quantitatively the perceptions of hotness and coldness. Temperature is measurement, measured with a thermometer. Thermometers are calibrated in various Conversion of units of temperature, temp ...
s. The equation is : \frac = A + B \ln R + C (\ln R)^3, where : T is the temperature (in
kelvin The kelvin, symbol K, is the primary unit of temperature in the International System of Units (SI), used alongside its prefixed forms and the degree Celsius. It is named after the Belfast-born and University of Glasgow-based engineer and phy ...
s), : R is the resistance at T (in ohms), : A, B, and C are the Steinhart–Hart coefficients, which vary depending on the type and model of
thermistor A thermistor is a type of resistor whose resistance is strongly dependent on temperature, more so than in standard resistors. The word thermistor is a portmanteau of ''thermal'' and ''resistor''. Thermistors are divided based on their conduction ...
and the temperature range of interest.


Uses of the equation

The equation is often used to derive a precise temperature of a thermistor, since it provides a closer approximation to actual temperature than simpler equations, and is useful over the entire working temperature range of the sensor. Steinhart–Hart coefficients are usually published by thermistor manufacturers. Where Steinhart–Hart coefficients are not available, they can be derived. Three accurate measures of resistance are made at precise temperatures, then the coefficients are derived by solving three
simultaneous equations In mathematics, a set of simultaneous equations, also known as a system of equations or an equation system, is a finite set of equations for which common solutions are sought. An equation system is usually classified in the same manner as single e ...
.


Inverse of the equation

To find the resistance of a semiconductor at a given temperature, the inverse of the Steinhart–Hart equation must be used. See th
Application Note
"A, B, C Coefficients for Steinhart–Hart Equation". : R = \exp\left(\sqrt - \sqrt right), where : \begin x &= \frac\left(A - \frac\right), \\ y &= \sqrt. \end


Steinhart–Hart coefficients

To find the coefficients of Steinhart–Hart, we need to know at-least three operating points. For this, we use three values of resistance data for three known temperatures. : \begin 1 & \ln R_1 & \ln^3 R_1 \\ 1 & \ln R_2 & \ln^3 R_2 \\ 1 & \ln R_3 & \ln^3 R_3 \end\begin A \\ B \\ C \end = \begin \frac \\ \frac \\ \frac \end With R_1, R_2 and R_3 values of resistance at the temperatures T_1, T_2 and T_3, one can express A, B and C (all calculations): :\begin L_1 &= \ln R_1, \quad L_2 = \ln R_2, \quad L_3 = \ln R_3 \\ Y_1 &= \frac, \quad Y_2 = \frac, \quad Y_3 = \frac \\ \gamma_2 &= \frac, \quad \gamma_3 = \frac \\ \Rightarrow C &= \left( \frac \right) \left(L_1 + L_2 + L_3\right)^ \\ \Rightarrow B &= \gamma_2 - C \left(L_1^2 + L_1 L_2 + L_2^2\right) \\ \Rightarrow A &= Y_1 - \left(B + L_1^2 C\right) L_1 \end


Developers of the equation

The equation is named after John S. Steinhart and Stanley R. Hart who first published the relationship in 1968.John S. Steinhart, Stanley R. Hart, Calibration curves for thermistors, Deep-Sea Research and Oceanographic Abstracts, Volume 15, Issue 4, August 1968, Pages 497–503, ISSN 0011-7471, . Professor Steinhart (1929–2003), a fellow of the
American Geophysical Union The American Geophysical Union (AGU) is a 501(c)(3) nonprofit organization of Earth, atmospheric, ocean, hydrologic, space, and planetary scientists and enthusiasts that according to their website includes 130,000 people (not members). AGU's a ...
and of the American Association for the Advancement of Science, was a member of the faculty of
University of Wisconsin–Madison A university () is an institution of higher (or tertiary) education and research which awards academic degrees in several academic disciplines. Universities typically offer both undergraduate and postgraduate programs. In the United Stat ...
from 1969 to 1991. Dr. Hart, a Senior Scientist at
Woods Hole Oceanographic Institution The Woods Hole Oceanographic Institution (WHOI, acronym pronounced ) is a private, nonprofit research and higher education facility dedicated to the study of marine science and engineering. Established in 1930 in Woods Hole, Massachusetts, it ...
since 1989 and fellow of the
Geological Society of America The Geological Society of America (GSA) is a nonprofit organization dedicated to the advancement of the geosciences. History The society was founded in Ithaca, New York, in 1888 by Alexander Winchell, John J. Stevenson, Charles H. Hitch ...
, the American Geophysical Union, the
Geochemical Society The Geochemical Society is a nonprofit scientific organization founded to encourage the application of chemistry to solve problems involving geology and cosmology. The society promotes understanding of geochemistry through the annual Goldschmidt Co ...
and the European Association of Geochemistry, was associated with Professor Steinhart at the
Carnegie Institution of Washington The Carnegie Institution of Washington (the organization's legal name), known also for public purposes as the Carnegie Institution for Science (CIS), is an organization in the United States established to fund and perform scientific research. Th ...
when the equation was developed.


Derivation and alternatives

The most general form of the equation can be derived from extending the B parameter equation to an infinite series: : R = R_0 e^ : \frac = \frac + \frac \left(\ln \frac\right) = a_0 + a_1 \ln \frac : \frac = \sum_^\infty a_n \left(\ln \frac\right)^n R_0 is a reference (standard) resistance value. The Steinhart–Hart equation assumes R_0 is 1 ohm. The curve fit is much less accurate when it is assumed a_2=0 and a different value of R_0 such as 1 kΩ is used. However, using the full set of coefficients avoids this problem as it simply results in shifted parameters. In the original paper, Steinhart and Hart remark that allowing a_2 \neq 0 degraded the fit. This is surprising as allowing more freedom would usually improve the fit. It may be because the authors fitted 1/T instead of T, and thus the error in T increased from the extra freedom. Subsequent papers have found great benefit in allowing a_2 \neq 0. The equation was developed through trial-and-error testing of numerous equations, and selected due to its simple form and good fit. However, in its original form, the Steinhart–Hart equation is not sufficiently accurate for modern scientific measurements. For interpolation using a small number of measurements, the series expansion with n=4 has been found to be accurate within 1 mK over the calibrated range. Some authors recommend using n=5. If there are many data points, standard
polynomial regression In statistics, polynomial regression is a form of regression analysis in which the relationship between the independent variable ''x'' and the dependent variable ''y'' is modelled as an ''n''th degree polynomial in ''x''. Polynomial regression fi ...
can also generate accurate curve fits. Some manufacturers have begun providing regression coefficients as an alternative to Steinhart–Hart coefficients.


References


External links


Steinhart-Hart Coefficient Calculator OnlineSteinhart-Hart Coefficient Calculator Java
{{DEFAULTSORT:Steinhart-Hart equation Semiconductors