Syenite is a coarse-grained intrusive

igneous rock Igneous rock ( ), or magmatic rock, is one of the three main rock types, the others being sedimentary and metamorphic. Igneous rocks are formed through the cooling and solidification of magma or lava. The magma can be derived from partial ...

with a general composition similar to that of

granite Granite ( ) is a coarse-grained (phanerite, phaneritic) intrusive rock, intrusive igneous rock composed mostly of quartz, alkali feldspar, and plagioclase. It forms from magma with a high content of silica and alkali metal oxides that slowly coo ...

, but deficient in

quartz Quartz is a hard, crystalline mineral composed of silica (silicon dioxide). The Atom, atoms are linked in a continuous framework of SiO4 silicon–oxygen Tetrahedral molecular geometry, tetrahedra, with each oxygen being shared between two tet ...

, which, if present at all, occurs in relatively small concentrations (< 5%). It is considered a granitoid. Some syenites contain larger proportions of

mafic A mafic mineral or rock is a silicate mineral or igneous rock rich in magnesium and iron. Most mafic minerals are dark in color, and common rock-forming mafic minerals include olivine, pyroxene, amphibole, and biotite. Common mafic rocks include ...

components and smaller amounts of

felsic In geology, felsic is a grammatical modifier, modifier describing igneous rocks that are relatively rich in elements that form feldspar and quartz.Marshak, Stephen, 2009, ''Essentials of Geology,'' W. W. Norton & Company, 3rd ed. It is contrasted ...

material than most granites; those are classed as being of

intermediate composition In igneous petrology, an intermediate composition refers to the chemical composition of a rock that has 51.563 wt% SiO2 being an intermediate between felsic and mafic compositions. Typical intermediate rocks include andesite and trachyandesite ...

. The

extrusive Extrusive rock refers to the mode of igneous volcanic rock formation in which hot magma from inside the Earth flows out (extrudes) onto the surface as lava or explodes violently into the atmosphere to fall back as pyroclastics or tuff. In contr ...

equivalent of syenite is

trachyte Trachyte () is an extrusive igneous rock composed mostly of alkali feldspar. It is usually light-colored and aphanite, aphanitic (fine-grained), with minor amounts of mafic minerals, and is formed by the rapid cooling of lava (or shallow intrus ...

Composition

The

feldspar Feldspar ( ; sometimes spelled felspar) is a group of rock-forming aluminium tectosilicate minerals, also containing other cations such as sodium, calcium, potassium, or barium. The most common members of the feldspar group are the ''plagiocl ...

component of syenite is predominantly

alkaline In chemistry, an alkali (; from the Arabic word , ) is a basic salt of an alkali metal or an alkaline earth metal. An alkali can also be defined as a base that dissolves in water. A solution of a soluble base has a pH greater than 7.0. The ...

in character (usually

orthoclase Orthoclase, or orthoclase feldspar ( endmember formula K Al Si3 O8), is an important tectosilicate mineral which forms igneous rock. The name is from the Ancient Greek for "straight fracture", because its two cleavage planes are at right angles ...

Plagioclase Plagioclase ( ) is a series of Silicate minerals#Tectosilicates, tectosilicate (framework silicate) minerals within the feldspar group. Rather than referring to a particular mineral with a specific chemical composition, plagioclase is a continu ...

feldspars may be present in small proportions, between 10% and 35% of the feldspar content. Such feldspars often are interleaved as perthitic components of the rock. When ferromagnesian minerals are present in syenite at all, they usually occur in the form of

amphibole Amphibole ( ) is a group of inosilicate minerals, forming prism or needlelike crystals, composed of double chain tetrahedra, linked at the vertices and generally containing ions of iron and/or magnesium in their structures. Its IMA symbol is ...

(typically

hornblende Hornblende is a complex silicate minerals#Inosilicates, inosilicate series of minerals. It is not a recognized mineral in its own right, but the name is used as a general or field term, to refer to a dark amphibole. Hornblende minerals are common ...

) and clinopyroxene.

Biotite Biotite is a common group of phyllosilicate minerals within the mica group, with the approximate chemical formula . It is primarily a solid-solution series between the iron- endmember annite, and the magnesium-endmember phlogopite; more al ...

is rare, because in a syenite magma the formation of feldspar consumes nearly all the aluminium. However less Al-rich

phyllosilicates Silicate minerals are rock-forming minerals made up of silicate groups. They are the largest and most important class of minerals and make up approximately 90 percent of Earth's crust. In mineralogy, the crystalline forms of silica (silicon dio ...

may be included, such as annite. Other common accessory minerals are

apatite Apatite is a group of phosphate minerals, usually hydroxyapatite, fluorapatite and chlorapatite, with high concentrations of Hydroxide, OH−, Fluoride, F− and Chloride, Cl− ion, respectively, in the crystal. The formula of the admixture of ...

, titanite,

zircon Zircon () is a mineral belonging to the group of nesosilicates and is a source of the metal zirconium. Its chemical name is zirconium(IV) silicate, and its corresponding chemical formula is Zr SiO4. An empirical formula showing some of th ...

and other opaques. Most syenites are either peralkaline with high proportions of alkali elements relative to aluminum, or peraluminous with a higher concentration of aluminum relative to

alkali In chemistry, an alkali (; from the Arabic word , ) is a basic salt of an alkali metal or an alkaline earth metal. An alkali can also be defined as a base that dissolves in water. A solution of a soluble base has a pH greater than 7.0. The a ...

(predominantly K and Na) and earth-alkali (predominantly Ca) elements.

Formation

Partial melting

Syenites are products of alkaline igneous activity, generally formed in thick

continental crust Continental crust is the layer of igneous, metamorphic, and sedimentary rocks that forms the geological continents and the areas of shallow seabed close to their shores, known as '' continental shelves''. This layer is sometimes called '' si ...

al areas, or in Cordilleran

subduction Subduction is a geological process in which the oceanic lithosphere and some continental lithosphere is recycled into the Earth's mantle at the convergent boundaries between tectonic plates. Where one tectonic plate converges with a second p ...

zones. The formation of syenites can be theorized to be from the melt of granitic or igneous

protolith A protolith () is the original, unmetamorphosed rock from which a given metamorphic rock is formed. For example, the protolith of a slate is a shale or mudstone. Metamorphic rocks can be derived from any other kind of non-metamorphic rock and ...

to a fairly low degree of partial melting. This is required because potassium is an incompatible element and tends to enter a melt first, whereas higher degrees of partial melting will liberate more calcium and sodium, which produce

plagioclase Plagioclase ( ) is a series of Silicate minerals#Tectosilicates, tectosilicate (framework silicate) minerals within the feldspar group. Rather than referring to a particular mineral with a specific chemical composition, plagioclase is a continu ...

, and hence a

granodiorite Granodiorite ( ) is a coarse-grained (phaneritic) intrusive igneous rock similar to granite, but containing more plagioclase feldspar than orthoclase feldspar. The term banatite is sometimes used informally for various rocks ranging from gra ...

tonalite Tonalite is an igneous rock, igneous, plutonic (Intrusive rock, intrusive) rock (geology), rock, of felsic composition, with phaneritic (coarse-grained) texture. Feldspar is present as plagioclase (typically oligoclase or andesine) with alkali fe ...

. At very low degrees of partial melting a

silica Silicon dioxide, also known as silica, is an oxide of silicon with the chemical formula , commonly found in nature as quartz. In many parts of the world, silica is the major constituent of sand. Silica is one of the most complex and abundant f ...

undersaturated melt is produced, forming a nepheline syenite, where orthoclase is replaced by a

feldspathoid The feldspathoids are a group of tectosilicate minerals which resemble feldspar Feldspar ( ; sometimes spelled felspar) is a group of rock-forming aluminium tectosilicate minerals, also containing other cations such as sodium, calcium, pota ...

such as

leucite Leucite (from the Greek word ''leukos'' meaning white) is a rock-forming mineral of the feldspathoid group, silica-undersaturated and composed of potassium and aluminium tectosilicate KAlSi2O6. Crystals have the form of cubic icositetrahedra b ...

nepheline Nepheline, also called nephelite (), is a rock-forming mineral in the feldspathoid groupa silica-undersaturated aluminosilicate, Na3 K Al4 Si4 O16, that occurs in intrusive and volcanic rocks with low silica, and in their associated pegmatit ...

analcime Analcime (; ) or analcite is a white, gray, or colorless tectosilicate mineral. Analcime consists of hydrated sodium aluminium silicate in cubic crystalline form. Its chemical formula is NaAlSi2O6 · H2O. Minor amounts of potassium and calcium ...

. Conversely in certain conditions, large volumes of

anorthite Anorthite (< ''an'' 'not' + ''ortho'' 'straight') is the

calcium

cumulate process as it cools. This leaves a drastically reduced concentration of silica in the remainder of the melt. The segregation of the silica from the melt leaves it in a state that may favour syenite formation.

Fractional crystallization

Some syenites are also theorized to be the product of the fractional crystallization of basaltic magmas.

Occurrence

Bulletin 426 Plate XVI B Bowlder Outcrop of Syenite

Syenite is not a common rock. Regions where it occurs in significant quantities include the following. *In the

Kola Peninsula The Kola Peninsula (; ) is a peninsula in the extreme northwest of Russia, and one of the largest peninsulas of Europe. Constituting the bulk of the territory of Murmansk Oblast, it lies almost completely inside the Arctic Circle and is border ...

of Russia two giant

syenite bodies exists making up the Lovozero Massif and the Khibiny Mountains. These syenites are part of the Kola Alkaline Province. * In North America syenite occurs in

Arkansas Arkansas ( ) is a landlocked state in the West South Central region of the Southern United States. It borders Missouri to the north, Tennessee and Mississippi to the east, Louisiana to the south, Texas to the southwest, and Oklahoma ...

and

Montana Montana ( ) is a landlocked U.S. state, state in the Mountain states, Mountain West subregion of the Western United States. It is bordered by Idaho to the west, North Dakota to the east, South Dakota to the southeast, Wyoming to the south, an ...

. Regions in

New England New England is a region consisting of six states in the Northeastern United States: Connecticut, Maine, Massachusetts, New Hampshire, Rhode Island, and Vermont. It is bordered by the state of New York (state), New York to the west and by the ...

have sizable amounts, and in New York syenite

gneiss Gneiss (pronounced ) is a common and widely distributed type of metamorphic rock. It is formed by high-temperature and high-pressure metamorphic processes acting on formations composed of igneous or sedimentary rocks. This rock is formed under p ...

es occur. The "great syenite dyke" extends from Hanging Rock, South Carolina, through Taxahaw, South Carolina, to the Brewer and Edgeworth mine in

Chesterfield, South Carolina Chesterfield is a town in Chesterfield County, South Carolina, United States. The population was 1,357 as of the 2020 census. It is the county seat of Chesterfield County, and least populous of all South Carolina county seats. History The E ...

. Syenite pebbles, containing

fluorescent Fluorescence is one of two kinds of photoluminescence, the emission of light by a substance that has absorbed light or other electromagnetic radiation. When exposed to ultraviolet radiation, many substances will glow (fluoresce) with color ...

sodalite Sodalite ( ) is a tectosilicate mineral with the formula , with royal blue varieties widely used as an ornamental gemstone. Although massive sodalite samples are opaque, crystals are usually transparent to translucent. Sodalite is a member of th ...

, were moved from Canada to Michigan by glaciers; these

glacial erratic A glacial erratic is a glacially deposited rock (geology), rock differing from the type of country rock (geology), rock native to the area in which it rests. Erratics, which take their name from the Latin word ' ("to wander"), are carried by gla ...

pebbles have been given the trade name "yooperlite". In other parts of the world, these types of rocks are known as sodalite-syenite and occur in Canada, India, other US states, Greenland, Malawi, and Russia. * In Europe syenite may be found in parts of

Switzerland Switzerland, officially the Swiss Confederation, is a landlocked country located in west-central Europe. It is bordered by Italy to the south, France to the west, Germany to the north, and Austria and Liechtenstein to the east. Switzerland ...

Germany Germany, officially the Federal Republic of Germany, is a country in Central Europe. It lies between the Baltic Sea and the North Sea to the north and the Alps to the south. Its sixteen States of Germany, constituent states have a total popu ...

Norway Norway, officially the Kingdom of Norway, is a Nordic countries, Nordic country located on the Scandinavian Peninsula in Northern Europe. The remote Arctic island of Jan Mayen and the archipelago of Svalbard also form part of the Kingdom of ...

Portugal Portugal, officially the Portuguese Republic, is a country on the Iberian Peninsula in Southwestern Europe. Featuring Cabo da Roca, the westernmost point in continental Europe, Portugal borders Spain to its north and east, with which it share ...

Sweden Sweden, formally the Kingdom of Sweden, is a Nordic countries, Nordic country located on the Scandinavian Peninsula in Northern Europe. It borders Norway to the west and north, and Finland to the east. At , Sweden is the largest Nordic count ...

Scotland Scotland is a Countries of the United Kingdom, country that is part of the United Kingdom. It contains nearly one-third of the United Kingdom's land area, consisting of the northern part of the island of Great Britain and more than 790 adjac ...

, in

Plovdiv Plovdiv (, ) is the List of cities and towns in Bulgaria, second-largest city in Bulgaria, 144 km (93 miles) southeast of the capital Sofia. It had a population of 490,983 and 675,000 in the greater metropolitan area. Plovdiv is a cultural hub ...

, Bulgaria and in Ditrău, Romania. *In Africa there are syenite formations in Aswan, Egypt, and in

Malawi Malawi, officially the Republic of Malawi, is a landlocked country in Southeastern Africa. It is bordered by Zambia to the west, Tanzania to the north and northeast, and Mozambique to the east, south, and southwest. Malawi spans over and ...

in the

Mulanje Mountain Forest Reserve Mulanje Mountain Forest Reserve is a nature reserve founded in 1927 in Malawi. The reserve covers 56,317 hectares. It is operated by the Mulanje Mountain Conservation Trust. The reserve was designated a biosphere reserve by UNESCO in 2000. __TOC_ ...

. Syenite rock was used to make the Quay with Sphinxes. *In Australia syenite occurs as small intrusive bodies in nearly every state. In

New South Wales New South Wales (commonly abbreviated as NSW) is a States and territories of Australia, state on the Eastern states of Australia, east coast of :Australia. It borders Queensland to the north, Victoria (state), Victoria to the south, and South ...

, a large syenite intruded during the breakup of

Gondwana Gondwana ( ; ) was a large landmass, sometimes referred to as a supercontinent. The remnants of Gondwana make up around two-thirds of today's continental area, including South America, Africa, Antarctica, Australia (continent), Australia, Zea ...

in the

Cretaceous The Cretaceous ( ) is a geological period that lasted from about 143.1 to 66 mya (unit), million years ago (Mya). It is the third and final period of the Mesozoic Era (geology), Era, as well as the longest. At around 77.1 million years, it is the ...

. * Paatusoq and Kangerluluk fjords in southeastern

Greenland Greenland is an autonomous territory in the Danish Realm, Kingdom of Denmark. It is by far the largest geographically of three constituent parts of the kingdom; the other two are metropolitan Denmark and the Faroe Islands. Citizens of Greenlan ...

, where a bay within the latter ''(Syenitbugt)'' and a headland ''(Syenitnæs)'' are named after the rock.

Etymology

The term ''syenite'' was originally applied to hornblende granite like that of Syene (now Aswan) in

Egypt Egypt ( , ), officially the Arab Republic of Egypt, is a country spanning the Northeast Africa, northeast corner of Africa and Western Asia, southwest corner of Asia via the Sinai Peninsula. It is bordered by the Mediterranean Sea to northe ...

, from which the name is derived.

Episyenite

Episyenite (or ''epi-syenite'') is a term used in

petrology Petrology () is the branch of geology that studies rocks, their mineralogy, composition, texture, structure and the conditions under which they form. Petrology has three subdivisions: igneous, metamorphic, and sedimentary petrology. Igneous ...

to describe veins, pods, or lenses of rock originally rich in

silicon dioxide Silicon dioxide, also known as silica, is an oxide of silicon with the chemical formula , commonly found in nature as quartz. In many parts of the world, silica is the major constituent of sand. Silica is one of the most complex and abundan ...

(SiO₂) from which quartz has been severely depleted. This is often accompanied by strong enrichment in potassium and rare earth elements, leaving the altered rock a distinctive brick red color, or by albitization (enrichment in sodium), leaving the altered rock a conspicuous white color. Episyenites are heterogenous in their properties, but all have experienced nearly complete disappearance of quartz at sub- solidus temperatures; that is, at temperatures below the melting point of the host rock. The formation of episyenites (''episyenitization'') typically takes place through leaching of quartz by mildly saline hydrothermal fluids, typically near a cooling

intrusion In geology, an igneous intrusion (or intrusive body or simply intrusion) is a body of intrusive igneous rock that forms by crystallization of magma slowly cooling below the surface of the Earth. Intrusions have a wide variety of forms and com ...

. Because episyenitization usually takes place in granitoid rock and usually involves alkaline

metasomatism Metasomatism (from the Greek μετά ''metá'' "change" and σῶμα ''sôma'' "body") is the chemical alteration of a rock by hydrothermal and other fluids. It is traditionally defined as metamorphism which involves a change in the chemical com ...

(addition of alkali metal oxides to the rock) the result is a rock that has the mineral composition of an igneous syenite. In addition to rare earth elements, episyenites may be important sources of

uranium Uranium is a chemical element; it has chemical symbol, symbol U and atomic number 92. It is a silvery-grey metal in the actinide series of the periodic table. A uranium atom has 92 protons and 92 electrons, of which 6 are valence electrons. Ura ...

and other valuable metals. Notable occurrences of episyenite are found in the Central Iberian Massif of Spain, in

Cambrian The Cambrian ( ) is the first geological period of the Paleozoic Era, and the Phanerozoic Eon. The Cambrian lasted 51.95 million years from the end of the preceding Ediacaran period 538.8 Ma (million years ago) to the beginning of the Ordov ...

Ordovician The Ordovician ( ) is a geologic period and System (geology), system, the second of six periods of the Paleozoic Era (geology), Era, and the second of twelve periods of the Phanerozoic Eon (geology), Eon. The Ordovician spans 41.6 million years f ...

beds of New Mexico and Colorado, Scandinavia, Brazil, and Ukraine.

References

* E. Wm. Heinrich. Microscopic Petrography, McGraw-Hill, 1956 {{Authority control Granitic rocks Industrial minerals