Silver telluride (Ag₂Te) is a chemical compound, a telluride of

silver Silver is a chemical element; it has Symbol (chemistry), symbol Ag () and atomic number 47. A soft, whitish-gray, lustrous transition metal, it exhibits the highest electrical conductivity, thermal conductivity, and reflectivity of any metal. ...

, also known as disilver telluride or silver(I) telluride. It forms a

monoclinic In crystallography, the monoclinic crystal system is one of the seven crystal systems. A crystal system is described by three Vector (geometric), vectors. In the monoclinic system, the crystal is described by vectors of unequal lengths, as in t ...

crystal. In a wider sense, ''silver telluride'' can be used to denote AgTe (silver(II) telluride, a

metastable In chemistry and physics, metastability is an intermediate energetic state within a dynamical system other than the system's state of least energy. A ball resting in a hollow on a slope is a simple example of metastability. If the ball is onl ...

compound) or Ag₅Te₃. Silver(I) telluride occurs naturally as the mineral

hessite Hessite is a mineral form of silver telluride, disilver telluride (Ag2Te). It is a soft, dark grey telluride mineral which forms monoclinic crystals. It is named after Germain Henri Hess (1802–1850). Hessite is found in the US in Eagle County ...

, whereas silver(II) telluride is known as empressite. Silver telluride is a

semiconductor A semiconductor is a material with electrical conductivity between that of a conductor and an insulator. Its conductivity can be modified by adding impurities (" doping") to its crystal structure. When two regions with different doping level ...

which can be doped both n-type and p-type. Stoichiometric Ag₂Te has n-type conductivity. On heating silver is lost from the material.

Non-stoichiometric Non-stoichiometric compounds are chemical compounds, almost always solid inorganic compounds, having chemical element, elemental composition whose proportions cannot be represented by a ratio of small natural numbers (i.e. an empirical formula); ...

silver telluride has shown extraordinary magnetoresistance.

Synthesis

Porous silver telluride (AgTe) is synthesized by an electrochemical deposition method. The experiment can be performed using a potentiostat and a three-electrode cell with 200 mL of 0.5 M sulfuric acid electrolyte solution containing Ag nanoparticles at room temperature. Then a silver paste used in the tungsten ditelluride (WTe₂) attachment leach into the electrolyte which causes small amounts of Ag to dissolve in the electrolyte. The electrolyte was stirred by a magnetic bar to remove hydrogen bubbles. A silver- silver chloride electrode and a platinum wire can be used as reference and counter electrodes. All the potentials can be measured against the reference electrode, and it was calibrated using the equation ERHE = EAg/AgCl + .059 pH + .197. In order to grow the porous AgTe, the WTe₂ was treated using multiple cyclic voltammetry between -1.2 and 0 volts with a scan rate of 100 mV/s. Glutathione coated Ag₂Te Nanoparticles can be synthesized by preparing a 9 mL solution containing 10 mM AgNO₃, 5mM Na₂TeO₃, and 30 mM glutathione. Place that solution in an ice bath. N₂H₄ was added to the solution and the reaction is allowed to proceed for 5 min under constant stirring. Then the nanoparticles are washed three times by a way of centrifugation, after the three washes the nanoparticles are suspended in PBS and washed again with that same method.

References

* * * *Hagyeong Kwon, Dongyeon Bae, Dongyeun Won, Heeju Kim, Gunn Kim, Jiung Cho, Hee Jung Park, Hionsuck Baik, Ah Reum Jeong, Chia-Hsien Lin, Ching-Yu Chiang, Ching-Shun Ku, Heejun Yang, and Suyeon Cho "Nanoporous Silver Telluride for active hydrogen evolution." (n.d.) https://pubs.acs.org/doi/10.1021/acsnano.0c09517

Synthesis

References

See also

Related materials