was a type of
explosive
An explosive (or explosive material) is a reactive substance that contains a great amount of potential energy that can produce an explosion if released suddenly, usually accompanied by the production of light, heat, sound, and pressure. An ex ...
shell-filling developed by the
Japanese naval engineer (1860–1911).
Shimose, born in
Hiroshima Prefecture, graduated from
Tokyo Imperial University
The University of Tokyo (, abbreviated as in Japanese and UTokyo in English) is a public university, public research university in Bunkyō, Tokyo, Japan. Founded in 1877 as the nation's first modern university by the merger of several Edo peri ...
and became one of Japan's earliest holders of a doctorate in engineering. In 1887, the
Imperial Japanese Navy
The Imperial Japanese Navy (IJN; Kyūjitai: Shinjitai: ' 'Navy of the Greater Japanese Empire', or ''Nippon Kaigun'', 'Japanese Navy') was the navy of the Empire of Japan from 1868 to 1945, Potsdam Declaration, when it was dissolved followin ...
hired him as a
chemical engineer
A chemical engineer is a professional equipped with the knowledge of chemistry and other basic sciences who works principally in the chemical industry to convert basic raw materials into a variety of Product (chemistry), products and deals with ...
, and from 1899 he headed a research unit tasked with developing a more powerful type of shell-filling for use by
naval artillery
Naval artillery is artillery mounted on a warship, originally used only for naval warfare and then subsequently used for more specialized roles in surface warfare such as naval gunfire support (NGFS) and anti-aircraft warfare (AAW) engagements. ...
.
Shimose developed a new explosive based on
picric acid
Picric acid is an organic compound with the formula (O2N)3C6H2OH. Its IUPAC name is 2,4,6-trinitrophenol (TNP). The name "picric" comes from (''pikros''), meaning "bitter", due to its bitter taste. It is one of the most acidic phenols. Like ot ...
– already used by France in the form of Melinite and by Britain in the form of
Lyddite. Picric acid has an instability problem when in contact with
iron
Iron is a chemical element; it has symbol Fe () and atomic number 26. It is a metal that belongs to the first transition series and group 8 of the periodic table. It is, by mass, the most common element on Earth, forming much of Earth's o ...
or other
heavy metals
upright=1.2, Crystals of lead.html" ;"title="osmium, a heavy metal nearly twice as dense as lead">osmium, a heavy metal nearly twice as dense as lead
Heavy metals is a controversial and ambiguous term for metallic elements with relatively h ...
, so the French mixed it with
collodion
Collodion is a flammable, syrupy solution of nitrocellulose in Diethyl ether, ether and Alcohol (chemistry), alcohol. There are two basic types: flexible and non-flexible. The flexible type is often used as a surgical dressing or to hold dressings ...
and the British mixed it with
dinitrobenzene Dinitrobenzenes are nitrobenzenes composed of a benzene ring and two nitro group (-NO2) substituents. The three possible arrangements of the nitro groups afford three isomers, 1,2-dinitrobenzene, 1,3-dinitrobenzene, and 1,4-dinitrobenzene. Each iso ...
and
vaseline
Vaseline ()Also pronounced with the main stress on the last syllable . is an American brand of petroleum jelly-based products owned by British multinational company Unilever. Products include plain petroleum jelly and a selection of skin creams, ...
to form compounds for stability within gun shells. On the other hand, Shimose coated the inside of a shell with unpigmented
Japanese lacquer and further sealed it with wax to prevent his powder from coming into contact with the metal shell. Because it was undiluted, the explosive generated more heat and blast speed than any other
high explosive
An explosive (or explosive material) is a reactive substance that contains a great amount of potential energy that can produce an explosion if released suddenly, usually accompanied by the production of light, heat, sound, and pressure. An exp ...
available at the time. The Imperial Japanese Navy adopted Shimose powder, with its composition treated as top secret, from 1893 – not only for naval artillery but also for
naval mine
A naval mine is a self-contained explosive weapon placed in water to damage or destroy surface ships or submarines. Similar to anti-personnel mine, anti-personnel and other land mines, and unlike purpose launched naval depth charges, they are ...
s,
depth charge
A depth charge is an anti-submarine warfare (ASW) weapon designed to destroy submarine
A submarine (often shortened to sub) is a watercraft capable of independent operation underwater. (It differs from a submersible, which has more limited ...
s and
torpedo
A modern torpedo is an underwater ranged weapon launched above or below the water surface, self-propelled towards a target, with an explosive warhead designed to detonate either on contact with or in proximity to the target. Historically, such ...
warheads. It played an important role in the Japanese victory in the
Russo-Japanese War
The Russo-Japanese War (8 February 1904 – 5 September 1905) was fought between the Russian Empire and the Empire of Japan over rival imperial ambitions in Manchuria and the Korean Empire. The major land battles of the war were fought on the ...
of 1904 to 1905.
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See also
*
Armstrong's mixture
References
{{wiktionary
Explosives
Powders