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A hydrometer or lactometer is an instrument used for measuring density or
relative density Relative density, also called specific gravity, is a dimensionless quantity defined as the ratio of the density (mass of a unit volume) of a substance to the density of a given reference material. Specific gravity for solids and liquids is nea ...
of
liquids Liquid is a state of matter with a definite volume but no fixed shape. Liquids adapt to the shape of their container and are nearly incompressible, maintaining their volume even under pressure. The density of a liquid is usually close to th ...
based on the concept of
buoyancy Buoyancy (), or upthrust, is the force exerted by a fluid opposing the weight of a partially or fully immersed object (which may be also be a parcel of fluid). In a column of fluid, pressure increases with depth as a result of the weight of t ...
. They are typically
calibrated In measurement technology and metrology, calibration is the comparison of measurement values delivered by a device under test with those of a calibration standard of known accuracy. Such a standard could be another measurement device of known ...
and graduated with one or more scales such as
specific gravity Relative density, also called specific gravity, is a dimensionless quantity defined as the ratio of the density (mass of a unit volume) of a substance to the density of a given reference material. Specific gravity for solids and liquids is nea ...
. A hydrometer usually consists of a sealed hollow glass tube with a wider bottom portion for
buoyancy Buoyancy (), or upthrust, is the force exerted by a fluid opposing the weight of a partially or fully immersed object (which may be also be a parcel of fluid). In a column of fluid, pressure increases with depth as a result of the weight of t ...
, a
ballast Ballast is dense material used as a weight to provide stability to a vehicle or structure. Ballast, other than cargo, may be placed in a vehicle, often a ship or the gondola of a balloon or airship, to provide stability. A compartment within ...
such as
lead Lead () is a chemical element; it has Chemical symbol, symbol Pb (from Latin ) and atomic number 82. It is a Heavy metal (elements), heavy metal that is density, denser than most common materials. Lead is Mohs scale, soft and Ductility, malleabl ...
or mercury for stability, and a narrow stem with graduations for measuring. The liquid to test is poured into a tall container, often a
graduated cylinder A graduated cylinder, also known as a measuring cylinder or mixing cylinder, is a common piece of laboratory equipment used to measure the volume of a liquid. It has a narrow cylindrical shape. Each marked line on the graduated cylinder represent ...
, and the hydrometer is gently lowered into the liquid until it floats freely. The point at which the surface of the liquid touches the stem of the hydrometer correlates to relative density. Hydrometers can contain any number of scales along the stem corresponding to properties correlating to the density. Hydrometers are calibrated for different uses, such as a lactometer for measuring the density (creaminess) of milk, a saccharometer for measuring the density of sugar in a liquid, or an alcoholometer for measuring higher levels of alcohol in spirits. The hydrometer makes use of
Archimedes' principle Archimedes' principle states that the upward buoyant force that is exerted on a body immersed in a fluid, whether fully or partially, is equal to the weight of the fluid that the body displaces. Archimedes' principle is a law of physics fun ...
: a solid suspended in a fluid is buoyed by a force equal to the weight of the fluid displaced by the submerged part of the suspended solid. The lower the density of the fluid, the deeper a hydrometer of a given weight sinks; the stem is calibrated to give a numerical reading.


History

upright=0.6, Hydrometer from ''Practical Physics'' The hydrometer probably dates back to the Greek philosopher
Archimedes Archimedes of Syracuse ( ; ) was an Ancient Greece, Ancient Greek Greek mathematics, mathematician, physicist, engineer, astronomer, and Invention, inventor from the ancient city of Syracuse, Sicily, Syracuse in History of Greek and Hellenis ...
(3rd century BC) who used its principles to find the density of various liquids. An early description of a hydrometer comes from a Latin poem, written in the 2nd century AD by Remnius, who compared the use of a hydrometer to the method of fluid displacement used by Archimedes to determine the gold content of Hiero II's crown.
Hypatia of Alexandria Hypatia (born 350–370 – March 415 AD) was a Neoplatonist philosopher, astronomer, and mathematician who lived in Alexandria, Egypt: at that time a major city of the Eastern Roman Empire. In Alexandria, Hypatia was a prominent thinker who ...
370; d.415 CE), an important female Greek mathematician, is the first person traditionally associated with the hydrometer. In a letter, Synesius of Cyrene asks Hypatia, his teacher, to make a hydrometer for him:
The instrument in question is a cylindrical tube, which has the shape of a flute and is about the same size. It has notches in a perpendicular line, by means of which we are able to test the weight of the waters. A cone forms a lid at one of the extremities, closely fitted to the tube. The cone and the tube have one base only. This is called the baryllium. Whenever you place the tube in water, it remains erect. You can then count the notches at your ease, and in this way ascertain the weight of the water.
According to the ''Encyclopedia of the History of Arabic Science'', it was used by
Abū Rayhān al-Bīrūnī Abu Rayhan Muhammad ibn Ahmad al-Biruni (; ; 973after 1050), known as al-Biruni, was a Khwarazmian Iranian scholar and polymath during the Islamic Golden Age. He has been called variously "Father of Comparative Religion", "Father of modern ...
in the 11th century and described by
Al-Khazini Abū al-Fath Abd al-Rahman Mansūr al-Khāzini or simply al-Khāzini (, flourished 1115–1130) was an Iranian astronomer, mechanician and physicist of Byzantine Greek origin who lived during the Seljuk Empire. His astronomical tables, written ...
in the 12th century. It was rediscovered in 1612 by Galileo and his circle of friends, and used in experiments especially at the Accademia del Cimento. It appeared again in the 1675 work of Robert Boyle (who coined the name ''"hydrometer"''), with types devised by
Antoine Baumé Antoine Baumé (26 February 172815 October 1804) was a French people, French chemist. Life He was born at Senlis, Oise, Senlis. He was apprenticed to the chemist Claude Joseph Geoffroy, and in 1752 was admitted a member of the École de Pharmaci ...
(the
Baumé scale The Baumé scale is a pair of hydrometer scales developed by French pharmacist Antoine Baumé in 1768 to measure density of various liquids. The unit of the Baumé scale has been notated variously as ''degrees Baumé'', ''B°'', ''Bé°'' and simp ...
), William Nicholson, and Jacques Alexandre César Charles in the late 18th century, more or less contemporarily with
Benjamin Sikes Bartholomew Sikes (died 1803) was an officer in the employ of HM Excise who in the late 18th century perfected a device by which the alcoholic content of a liquid can be measured. In 1802 he presented his invention to a board of inquiry toget ...
' discovery of the device by which the alcoholic content of a liquid can be automatically determined. The use of the Sikes device was made obligatory by British law in 1818.


Ranges

The hydrometer sinks deeper in low-density liquids such as
kerosene Kerosene, or paraffin, is a combustibility, combustible hydrocarbon liquid which is derived from petroleum. It is widely used as a fuel in Aviation fuel, aviation as well as households. Its name derives from the Greek (''kērós'') meaning " ...
,
gasoline Gasoline ( North American English) or petrol ( Commonwealth English) is a petrochemical product characterized as a transparent, yellowish, and flammable liquid normally used as a fuel for spark-ignited internal combustion engines. When for ...
, and
alcohol Alcohol may refer to: Common uses * Alcohol (chemistry), a class of compounds * Ethanol, one of several alcohols, commonly known as alcohol in everyday life ** Alcohol (drug), intoxicant found in alcoholic beverages ** Alcoholic beverage, an alco ...
, and less deep in high-density liquids such as
brine Brine (or briny water) is a high-concentration solution of salt (typically sodium chloride or calcium chloride) in water. In diverse contexts, ''brine'' may refer to the salt solutions ranging from about 3.5% (a typical concentration of seawat ...
,
milk Milk is a white liquid food produced by the mammary glands of lactating mammals. It is the primary source of nutrition for young mammals (including breastfeeding, breastfed human infants) before they are able to digestion, digest solid food. ...
, and
acid An acid is a molecule or ion capable of either donating a proton (i.e. Hydron, hydrogen cation, H+), known as a Brønsted–Lowry acid–base theory, Brønsted–Lowry acid, or forming a covalent bond with an electron pair, known as a Lewis ...
s. It is usual for hydrometers to be used with dense liquids to have the mark 1.000 (for water) near the top of the stem, and those for use with lighter liquids to have 1.000 near the bottom. In many industries a set of hydrometers is used (1.0–0.95, 0.95–.) to have instruments covering the range of specific gravities that may be encountered.


Scales

Modern hydrometers usually measure
specific gravity Relative density, also called specific gravity, is a dimensionless quantity defined as the ratio of the density (mass of a unit volume) of a substance to the density of a given reference material. Specific gravity for solids and liquids is nea ...
but different scales were (and sometimes still are) used in certain industries. Examples include: *
API gravity The American Petroleum Institute gravity, or API gravity, is a measure of how heavy or light a petroleum liquid is compared to water: if its API gravity is greater than 10, it is lighter and floats on water; if less than 10, it is heavier and sinks ...
, universally used worldwide by the petroleum industry. *
Baumé scale The Baumé scale is a pair of hydrometer scales developed by French pharmacist Antoine Baumé in 1768 to measure density of various liquids. The unit of the Baumé scale has been notated variously as ''degrees Baumé'', ''B°'', ''Bé°'' and simp ...
, formerly used in industrial chemistry and
pharmacology Pharmacology is the science of drugs and medications, including a substance's origin, composition, pharmacokinetics, pharmacodynamics, therapeutic use, and toxicology. More specifically, it is the study of the interactions that occur betwee ...
*
Brix Degrees Brix (symbol °Bx) is a measure of the dissolved solids in a liquid, based on its specific gravity, and is commonly used to measure dissolved sugar content of a solution. One degree Brix is 1 gram of sucrose solute dissolved in 100 grams ...
scale, primarily used in fruit juice, wine making and the sugar industry * Oechsle scale, used for measuring the density of
grape must Must is freshly crushed fruit juice (usually grape juice) that contains the skins, seeds, and stems of the fruit. The solid portion of the must is called pomace and typically makes up 7–23% of the total weight of the must. Making must is the ...
*
Plato scale The principal factors that characterize beer are bitterness, the variety of flavours present in the beverage and their intensity, alcohol content, and colour. Standards for those characteristics allow a more objective and uniform determination t ...
, primarily used in
brewing Brewing is the production of beer by steeping a starch source (commonly cereal grains, the most popular of which is barley) in water and #Fermenting, fermenting the resulting sweet liquid with Yeast#Beer, yeast. It may be done in a brewery ...
* Twaddell scale, formerly used in the bleaching and dyeing industries


Specialized hydrometers

Specialized hydrometers are frequently named for their use: a lactometer, for example, is a hydrometer designed especially for use with dairy products. They are sometimes referred to by this specific name, sometimes as hydrometers.


Alcoholometer

An alcoholmeter is a hydrometer that indicates the alcoholic strength of liquids which are essentially a mixture of alcohol and water. It is also known as a ''proof and Tralles hydrometer'' (after Johann Georg Tralles, but commonly misspelled as traille and tralle). It measures the density of the fluid. Where no sugar or other dissolved substances are present, the specific gravity of a solution of ethanol in water can be directly correlated to the concentration of alcohol. Saccharometers for measuring sugar-water mixtures measure densities greater than water. Many have scales marked with volume percents of "potential alcohol", based on a pre-calculated specific gravity. A higher "potential alcohol" reading on this scale is caused by a greater specific gravity, assumed to be caused by the introduction of dissolved sugars or carbohydrate based material. A reading is taken before and after fermentation and approximate alcohol content is determined by subtracting the post fermentation reading from the pre-fermentation reading. These were important instruments for determining tax, and specific maker's instruments could be specified.
Bartholomew Sikes Bartholomew Sikes (died 1803) was an officer in the employ of HM Excise who in the late 18th century perfected a device by which the alcoholic content of a liquid can be measured. In 1802 he presented his invention to a board of inquiry togeth ...
had a monopoly in the UK and
Mary Dicas Mary Dicas became Mary Arstall (fl. 1800–1818) was a scientific instrument maker in Liverpool. Her company created thousands of hydrometers that were exported to America where ''Dicas & Co'' enjoyed a monopoly as the agreed instrument for calcul ...
and her family enjoyed a similar monopoly in the US.


Lactometer

A lactometer is used to check purity of cow's milk. The specific gravity of milk does not give a conclusive indication of its composition since milk contains a variety of substances that are either heavier or lighter than water. Additional tests for fat content are necessary to determine overall composition. The instrument is graduated into a hundred parts. Milk is poured in and allowed to stand until the cream has formed, then the depth of the cream deposit in degrees determines the quality of the milk. If the milk sample is pure, the lactometer floats higher than if it is adulterated or impure.


Saccharometer

A saccharometer is a type of hydrometer used for determining the amount of sugar in a solution, invented by Thomas Thomson. It is used primarily by
winemaker A winemaker or vintner is a person engaged in winemaking. They are generally employed by wineries or wine companies, where their work includes: *Cooperating with viticulturists *Monitoring the maturity of grapes to ensure their quality and to de ...
s and brewers, and it can also be used in making
sorbet Sorbet (, ) is a frozen dessert made using ice combined with fruit juice, fruit purée, or other ingredients, such as wine, liqueur, or honey. Sorbet does not contain dairy products. Sherbet is similar to sorbet, but contains dairy. Etymolog ...
s and ice-creams. The first brewers' saccharometer was constructed by Benjamin Martin (with distillation in mind), and initially used for brewing by James Baverstock Sr in 1770. Henry Thrale adopted its use and it was later popularized by John Richardson in 1784. It consists of a large weighted glass bulb with a thin stem rising from the top with calibrated markings. The sugar level can be determined by reading the value where the surface of the liquid crosses the scale. The higher the sugar content, the denser the solution, and thus the higher the bulb will float.


Thermohydrometer

A thermohydrometer is a hydrometer that has a
thermometer A thermometer is a device that measures temperature (the hotness or coldness of an object) or temperature gradient (the rates of change of temperature in space). A thermometer has two important elements: (1) a temperature sensor (e.g. the bulb ...
enclosed in the float section. For measuring the density of petroleum products, such as fuel oils, the specimen is usually heated in a temperature jacket with a thermometer placed behind it since density is dependent on temperature. Light oils are placed in cooling jackets, typically at 15 °C. Very light oils with many volatile components are measured in a variable volume container using a floating
piston A piston is a component of reciprocating engines, reciprocating pumps, gas compressors, hydraulic cylinders and pneumatic cylinders, among other similar mechanisms. It is the moving component that is contained by a cylinder (engine), cylinder a ...
sampling device to minimize light end losses.


Battery hydrometer

The state of charge of a lead-acid battery can be estimated from the density of the
sulfuric acid Sulfuric acid (American spelling and the preferred IUPAC name) or sulphuric acid (English in the Commonwealth of Nations, Commonwealth spelling), known in antiquity as oil of vitriol, is a mineral acid composed of the elements sulfur, oxygen, ...
solution used as
electrolyte An electrolyte is a substance that conducts electricity through the movement of ions, but not through the movement of electrons. This includes most soluble Salt (chemistry), salts, acids, and Base (chemistry), bases, dissolved in a polar solven ...
. A hydrometer calibrated to read specific gravity relative to water at is a standard tool for servicing automobile batteries. Tables are used to correct the reading to the standard temperature. Hydrometers are also used for maintenance of wet-cell nickel-cadmium batteries to ensure the electrolyte is of the proper strength for the application; for this battery chemistry the specific gravity of the electrolyte is not related to the state of charge of the battery. A battery hydrometer with thermometer (thermohydrometer) measures the temperature-compensated specific gravity and electrolyte temperature.


Antifreeze tester

Another automotive use of hydrometers is testing the quality of the
antifreeze An antifreeze is an additive which lowers the freezing point of a water-based liquid. An antifreeze mixture is used to achieve freezing-point depression for cold environments. Common antifreezes also increase the boiling point of the liquid, allow ...
solution used for engine cooling. The degree of freeze protection can be related to the density (and so concentration) of the antifreeze; different types of antifreeze have different relations between measured density and freezing point.


Acidometer

An acidometer, or acidimeter, is a hydrometer used to measure the specific gravity of an
acid An acid is a molecule or ion capable of either donating a proton (i.e. Hydron, hydrogen cation, H+), known as a Brønsted–Lowry acid–base theory, Brønsted–Lowry acid, or forming a covalent bond with an electron pair, known as a Lewis ...
.


Barkometer

A barkometer is calibrated to test the strength of tanning liquors used in tanning
leather Leather is a strong, flexible and durable material obtained from the tanning (leather), tanning, or chemical treatment, of animal skins and hides to prevent decay. The most common leathers come from cattle, sheep, goats, equine animals, buffal ...
.


Salinometer

A salinometer is a hydrometer used to measure the salt content of the feed water to a marine steam boiler.


Urinometer

A
urinometer An Urinometer is a simple piece of equipment for determining urine specific gravity. Description A typical urinometer is composed of a float, a weight, and a stem. The float is an air-filled glass tube, ending in the weight on the left and the s ...
is a medical hydrometer designed for
urinalysis Urinalysis, a portmanteau of the words ''urine'' and ''analysis'', is a Test panel, panel of medical tests that includes physical (macroscopic) examination of the urine, chemical evaluation using urine test strips, and #Microscopic examination, m ...
. As urine's specific gravity is dictated by its ratio of solutes (wastes) to water, a urinometer makes it possible to quickly assess a patient's overall level of hydration.


Gallery

Hydrometer in a still (cropped).jpg, Alcohol meter to measure ethanol concentration of a water/ethanol mixture, shown in the "parrot head" of a still Densimetro o galattometro con custodia - Musei del cibo - Parmigiano - 314a.jpg, Lactometer to measure the density of milk, indicating its fat content Battery condition indicator.jpg, Battery condition indicator to measure electrolyte density in a lead–acid battery, indicating its state of charge (~1985) Coolant indicator.jpg, Antifreeze tester to measure engine coolant density, indicating its freezing point.


Use in soil analysis

A hydrometer analysis is the process by which fine-grained soils,
silt Silt is granular material of a size between sand and clay and composed mostly of broken grains of quartz. Silt may occur as a soil (often mixed with sand or clay) or as sediment mixed in suspension (chemistry), suspension with water. Silt usually ...
s and
clay Clay is a type of fine-grained natural soil material containing clay minerals (hydrous aluminium phyllosilicates, e.g. kaolinite, ). Most pure clay minerals are white or light-coloured, but natural clays show a variety of colours from impuriti ...
s, are graded. Hydrometer analysis is performed if the grain sizes are too small for
sieve analysis A sieve analysis (or gradation test) is a practice or procedure used in geology, civil engineering, and chemical engineering to assess the particle size distribution (also called ''gradation'') of a granular material by allowing the material to p ...
. The basis for this test is
Stokes' Law In fluid dynamics, Stokes' law gives the frictional force – also called drag force – exerted on spherical objects moving at very small Reynolds numbers in a viscous fluid. It was derived by George Gabriel Stokes in 1851 by solving the S ...
for falling spheres in a viscous fluid in which the terminal velocity of fall depends on the grain diameter and the densities of the grain in suspension and of the fluid. The grain diameter thus can be calculated from a knowledge of the distance and time of fall. The hydrometer also determines the specific gravity (or density) of the suspension, and this enables the fraction of particles of a certain equivalent particle diameter to be calculated.Fakhry A. Assaad, Philip Elmer LaMoreaux, Travis H. Hughes (ed.), '' Field Methods for Geologists and Hydrogeologists'', Springer Science & Business Media, 2004 , p.299


See also

*
Density meter A density meter (densimeter) is a device which measures the density of an object or material. Density is usually abbreviated as either \rho or D . Typically, density either has the units of '' kg/m^3 '' or '' lb/ft^3 ''. The most basic principl ...
*
Densitometer A densitometer is a device that measures the degree of darkness (the optical density) of a photographic or semitransparent material or of a reflecting surface. The densitometer is basically a light source aimed at a photoelectric cell. It deter ...
*
Dasymeter A dasymeter was meant initially as a device to demonstrate the buoyant effect of gases like air (as shown in the adjacent pictures). A dasymeter which allows weighing acts as a densimeter used to measure the density of gases. Principle The ...
* Elevator paradox (physics) * Fahrenheit hydrometer * Gravity (beer) *
Hydrostatic bubbles Hydrostatic bubbles, also known as philosophical bubbles, gravity beads, aerometrical beads and hydrometer beads, are a type of hydrometer invented in 1757 by Alexander Wilson of Glasgow. The design was subsequently improved and patented by the g ...
*
Hygrometer A hair tension dial hygrometer with a nonlinear scale. A hygrometer is an instrument that measures humidity: that is, how much water vapor is present. Humidity measurement instruments usually rely on measurements of some other quantities, such a ...
*
Oscillating U-tube {{no footnotes, date=March 2014 The oscillating U-tube is a technique to determine the density of liquids and gases based on an electronic measurement of the frequency of oscillation, from which the density value is calculated. This measuring p ...
* Pyknometer *
Refractometer A refractometer is a laboratory or field device for the measurement of an Refractive index, index of refraction (refractometry). The index of refraction is calculated from the observed refraction angle using Snell's law. For mixtures, the index ...


References


Sources


Hypatia of AlexandriaHydrometer InformationGuide to Brewing Hydrometers
*Jurjen Draaijer

. ''Milk Producer Group Resource Book'', Food and Agriculture Organization of the United Nations
Using Your Hydrometer
Winemaking Home Page.

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