The Rose–Vinet equation of state is a set of equations used to describe the
equation of state
In physics and chemistry, an equation of state is a thermodynamic equation relating state variables, which describe the state of matter under a given set of physical conditions, such as pressure, volume, temperature, or internal energy. Most mo ...
of solid objects. It is a modification of the
Birch–Murnaghan equation of state
The Birch–Murnaghan isothermal equation of state, published in 1947 by Albert Francis Birch of Harvard, is a relationship between the volume of a body and the pressure to which it is subjected. Birch proposed this equation based on the work of ...
.
The initial paper discusses how the equation only depends on four inputs: the isothermal
bulk modulus
The bulk modulus (K or B or k) of a substance is a measure of the resistance of a substance to bulk compression. It is defined as the ratio of the infinitesimal pressure increase to the resulting ''relative'' decrease of the volume.
Other mo ...
, the derivative of bulk modulus with respect to pressure
, the volume
, and the thermal expansion; all evaluated at zero pressure (
) and at a single (reference) temperature. The same equation holds for all classes of solids and a wide range of temperatures.
Let the cube root of the specific volume be
:
then the equation of state is:
:
A similar equation was published by Stacey et al. in 1981.
References
Solid mechanics
Equations of state
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