Quantum Superposition
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Quantum superposition is a fundamental principle of
quantum mechanics Quantum mechanics is a fundamental theory in physics that provides a description of the physical properties of nature at the scale of atoms and subatomic particles. It is the foundation of all quantum physics including quantum chemistry, ...
. In classical mechanics, things like position or momentum are always well defined. We may not know what they are at any given time, but that is an issue of our understanding, and not the physical system. In quantum mechanics, a particle can be in a superposition of different states. It can be in two places at once (see
double-slit experiment In modern physics, the double-slit experiment is a demonstration that light and matter can display characteristics of both classically defined waves and particles; moreover, it displays the fundamentally probabilistic nature of quantum mechanics ...
). A measurement always finds it in one state, but before and after the measurement, it interacts in ways that can only be explained by having a superpositions of different states. Mathematically, much like
wave In physics, mathematics, and related fields, a wave is a propagating dynamic disturbance (change from equilibrium) of one or more quantities. Waves can be periodic, in which case those quantities oscillate repeatedly about an equilibrium (res ...
s in
classical physics Classical physics is a group of physics theories that predate modern, more complete, or more widely applicable theories. If a currently accepted theory is considered to be modern, and its introduction represented a major paradigm shift, then the ...
, any two (or more)
quantum state In quantum physics, a quantum state is a mathematical entity that provides a probability distribution for the outcomes of each possible measurement on a system. Knowledge of the quantum state together with the rules for the system's evolution in ...
s can be added together ("superposed") and the result will be another valid quantum state; and conversely, that every quantum state can be represented as a sum of two or more other distinct states. Mathematically, it refers to a property of
solutions Solution may refer to: * Solution (chemistry), a mixture where one substance is dissolved in another * Solution (equation), in mathematics ** Numerical solution, in numerical analysis, approximate solutions within specified error bounds * Solutio ...
to the
Schrödinger equation The Schrödinger equation is a linear partial differential equation that governs the wave function of a quantum-mechanical system. It is a key result in quantum mechanics, and its discovery was a significant landmark in the development of the ...
; since the Schrödinger equation is
linear Linearity is the property of a mathematical relationship (''function'') that can be graphically represented as a straight line. Linearity is closely related to '' proportionality''. Examples in physics include rectilinear motion, the linear r ...
, any linear combination of solutions will also be a solution(s) . An example of a physically observable manifestation of the wave nature of quantum systems is the
interference Interference is the act of interfering, invading, or poaching. Interference may also refer to: Communications * Interference (communication), anything which alters, modifies, or disrupts a message * Adjacent-channel interference, caused by extr ...
peaks from an
electron The electron ( or ) is a subatomic particle with a negative one elementary electric charge. Electrons belong to the first generation of the lepton particle family, and are generally thought to be elementary particles because they have no kn ...
beam in a
double-slit experiment In modern physics, the double-slit experiment is a demonstration that light and matter can display characteristics of both classically defined waves and particles; moreover, it displays the fundamentally probabilistic nature of quantum mechanics ...
. The pattern is very similar to the one obtained by
diffraction Diffraction is defined as the interference or bending of waves around the corners of an obstacle or through an aperture into the region of geometrical shadow of the obstacle/aperture. The diffracting object or aperture effectively becomes a s ...
of classical waves. Another example is a quantum logical qubit state, as used in
quantum information processing Quantum information science is an interdisciplinary field that seeks to understand the analysis, processing, and transmission of information using quantum mechanics principles. It combines the study of Information science with quantum effects in p ...
, which is a quantum superposition of the "basis states" , 0 \rangle and , 1 \rangle . Here , 0 \rangle is the
Dirac notation Distributed Research using Advanced Computing (DiRAC) is an integrated supercomputing facility used for research in particle physics, astronomy and cosmology in the United Kingdom. DiRAC makes use of multi-core processors and provides a variety o ...
for the quantum state that will always give the result 0 when converted to classical logic by a measurement. Likewise , 1 \rangle is the state that will always convert to 1. Contrary to a classical
bit The bit is the most basic unit of information in computing and digital communications. The name is a portmanteau of binary digit. The bit represents a logical state with one of two possible values. These values are most commonly represente ...
that can only be in the state corresponding to 0 or the state corresponding to 1, a qubit may be in a superposition of both states. This means that the probabilities of measuring 0 or 1 for a qubit are in general neither 0.0 nor 1.0, and multiple measurements made on qubits in identical states will not always give the same result.


Concept

The principle of quantum superposition states that if a physical system may be in one of many configurations—arrangements of particles or fields—then the most general state is a combination of all of these possibilities, where the amount in each configuration is specified by a
complex number In mathematics, a complex number is an element of a number system that extends the real numbers with a specific element denoted , called the imaginary unit and satisfying the equation i^= -1; every complex number can be expressed in the form ...
. For example, if there are two configurations labelled by 0 and 1, the most general state would be :c_0 0 \rangle + c_1 1 \rangle where the coefficients are complex numbers describing how much goes into each configuration. The principle was described by
Paul Dirac Paul Adrien Maurice Dirac (; 8 August 1902 – 20 October 1984) was an English theoretical physicist who is regarded as one of the most significant physicists of the 20th century. He was the Lucasian Professor of Mathematics at the Univer ...
as follows:
The general principle of superposition of quantum mechanics applies to the states hat are theoretically possible without mutual interference or contradiction... of any one dynamical system. It requires us to assume that between these states there exist peculiar relationships such that whenever the system is definitely in one state we can consider it as being partly in each of two or more other states. The original state must be regarded as the result of a kind of superposition of the two or more new states, in a way that cannot be conceived on classical ideas. Any state may be considered as the result of a superposition of two or more other states, and indeed in an infinite number of ways. Conversely, any two or more states may be superposed to give a new state...
The non-classical nature of the superposition process is brought out clearly if we consider the superposition of two states, ''A'' and ''B'', such that there exists an observation which, when made on the system in state ''A'', is certain to lead to one particular result, ''a'' say, and when made on the system in state ''B'' is certain to lead to some different result, ''b'' say. What will be the result of the observation when made on the system in the superposed state? The answer is that the result will be sometimes ''a'' and sometimes ''b'', according to a probability law depending on the relative weights of ''A'' and ''B'' in the superposition process. It will never be different from both ''a'' and ''b'' .e., either ''a'' or ''b'' ''The intermediate character of the state formed by superposition thus expresses itself through the probability of a particular result for an observation being intermediate between the corresponding probabilities for the original states, not through the result itself being intermediate between the corresponding results for the original states.''
Anton Zeilinger Anton Zeilinger (; born 20 May 1945) is an Austrian quantum physicist and Nobel laureate in physics of 2022. Zeilinger is professor of physics emeritus at the University of Vienna and senior scientist at the Institute for Quantum Optics and Qua ...
, referring to the prototypical example of the
double-slit experiment In modern physics, the double-slit experiment is a demonstration that light and matter can display characteristics of both classically defined waves and particles; moreover, it displays the fundamentally probabilistic nature of quantum mechanics ...
, has elaborated regarding the creation and destruction of quantum superposition:
" e superposition of amplitudes ... is only valid if there is no way to know, even in principle, which path the particle took. It is important to realize that this does not imply that an observer actually takes note of what happens. It is sufficient to destroy the interference pattern, if the path information is accessible in principle from the experiment or even if it is dispersed in the environment and beyond any technical possibility to be recovered, but in principle still ‘‘out there.’’ The absence of any such information is ''the essential criterion'' for quantum interference to appear.


Theory


Examples

For an equation describing a physical phenomenon, the superposition principle states that a combination of solutions to a linear equation is also a solution of it. When this is true the equation is said to obey the superposition principle. Thus, if state vectors , and each solve the
linear equation In mathematics, a linear equation is an equation that may be put in the form a_1x_1+\ldots+a_nx_n+b=0, where x_1,\ldots,x_n are the variables (or unknowns), and b,a_1,\ldots,a_n are the coefficients, which are often real numbers. The coefficien ...
on ψ, then would also be a solution, in which each is a coefficient. The
Schrödinger equation The Schrödinger equation is a linear partial differential equation that governs the wave function of a quantum-mechanical system. It is a key result in quantum mechanics, and its discovery was a significant landmark in the development of the ...
is linear, so quantum mechanics follows this. For example, consider an
electron The electron ( or ) is a subatomic particle with a negative one elementary electric charge. Electrons belong to the first generation of the lepton particle family, and are generally thought to be elementary particles because they have no kn ...
with two possible configurations: up and down. This describes the physical system of a
qubit In quantum computing, a qubit () or quantum bit is a basic unit of quantum information—the quantum version of the classic binary bit physically realized with a two-state device. A qubit is a two-state (or two-level) quantum-mechanical system, ...
. :c_1 \rangle + c_2 \rangle is the most general state. But these coefficients dictate probabilities for the system to be in either configuration. The probability for a specified configuration is given by the square of the absolute value of the coefficient. The probabilities must add to 1, since the electron must be in one of those two states. : p_\text = c_1 ^2 : p_\text = c_2 \mid^2 : p_\text = p_\text + p_\text = 1 Continuing with this example, if a particle can be in state  up and  down, it can also be in a state where it is an amount up and an amount down. :, \psi\rangle = i \rangle + \rangle. In this, the probability for up is \left, \frac\^2=\frac. The probability for down is \left, \frac\^2=\frac. Note that \frac+\frac=1. In the description, only the relative size of the different components matter, and their angle to each other on the complex plane. This is usually stated by declaring that two states which are a multiple of one another are the same as far as the description of the situation is concerned. Either of these describe the same state for any nonzero \alpha : , \psi \rangle \approx \alpha , \psi \rangle The fundamental law of quantum mechanics is that the evolution is
linear Linearity is the property of a mathematical relationship (''function'') that can be graphically represented as a straight line. Linearity is closely related to '' proportionality''. Examples in physics include rectilinear motion, the linear r ...
, meaning that if state A turns into A′ and B turns into B′ after 10 seconds, then after 10 seconds the superposition \psi turns into a mixture of A′ and B′ with the same
coefficients In mathematics, a coefficient is a multiplicative factor in some term of a polynomial, a series, or an expression; it is usually a number, but may be any expression (including variables such as , and ). When the coefficients are themselves var ...
as A and B. For example, if we have the following : \rangle \to \rangle : \rangle \to \frac \rangle + \frac \rangle Then after those 10 seconds our state will change to :c_1 \rangle + c_2 \rangle \to c_1 \left( \rangle\right) + c_2 \left(\frac \rangle + \frac \rangle \right) So far there have just been 2 configurations, but there can be infinitely many. In illustration, a particle can have any position, so that there are different configurations which have any value of the position . These are written: : , x\rangle The principle of superposition guarantees that there are states which are arbitrary superpositions of all the positions with complex coefficients: : \sum_x \psi(x) , x\rangle This sum is defined only if the index  is discrete. If the index is over \reals, then the sum is replaced by an integral. The quantity \psi(x) is called the
wavefunction A wave function in quantum physics is a mathematical description of the quantum state of an isolated quantum system. The wave function is a complex-valued probability amplitude, and the probabilities for the possible results of measurements mad ...
of the particle. If we consider a qubit with both position and spin, the state is a superposition of all possibilities for both: : \sum_x \psi_+(x), x,\rangle + \psi_-(x), x,\rangle \, The configuration space of a quantum mechanical system cannot be worked out without some physical knowledge. The input is usually the allowed different classical configurations, but without the duplication of including both position and momentum. A pair of particles can be in any combination of pairs of positions. A state where one particle is at position x and the other is at position y is written , x,y\rangle. The most general state is a superposition of the possibilities: : \sum_ A(x,y) , x,y\rangle \, The description of the two particles is much larger than the description of one particle—it is a function in twice the number of dimensions. This is also true in probability, when the statistics of two random variables are
correlated In statistics, correlation or dependence is any statistical relationship, whether causal or not, between two random variables or bivariate data. Although in the broadest sense, "correlation" may indicate any type of association, in statistics ...
. If two particles are uncorrelated, the
probability distribution In probability theory and statistics, a probability distribution is the mathematical function that gives the probabilities of occurrence of different possible outcomes for an experiment. It is a mathematical description of a random phenomenon i ...
for their joint position is a product of the probability of finding one at one position and the other at the other position: : P(x,y) = P_x (x) P_y(y) \, This means that the wave function A(x,y) of the system can be represented as a product of the wave functions \psi_x(x) and \psi_y(y) of its parts: : A(x,y) = \psi_x(x)\psi_y(y) \,. In 1927, Heitler and London, attempted to quantitatively mechanically calculate the ground steady state of the H2 molecule. The calculations were based on the quantum superposition of the two hydrogen atoms that make up the system - H2 molecule. The success of this attempt became the basis for all further development of
covalent bond A covalent bond is a chemical bond that involves the sharing of electrons to form electron pairs between atoms. These electron pairs are known as shared pairs or bonding pairs. The stable balance of attractive and repulsive forces between atoms ...
.


Analogy with probability

In
probability theory Probability theory is the branch of mathematics concerned with probability. Although there are several different probability interpretations, probability theory treats the concept in a rigorous mathematical manner by expressing it through a set o ...
there is a similar principle. If a system has a probabilistic description, this description gives the probability of any configuration, and given any two different configurations, there is a state which is partly this and partly that, with positive real number coefficients, the probabilities, which say how much of each there is. For example, if we have a
probability distribution In probability theory and statistics, a probability distribution is the mathematical function that gives the probabilities of occurrence of different possible outcomes for an experiment. It is a mathematical description of a random phenomenon i ...
for where a particle is, it is described by the "state" : \sum_x \rho(x) , x\rangle Where \rho is the
probability density function In probability theory, a probability density function (PDF), or density of a continuous random variable, is a function whose value at any given sample (or point) in the sample space (the set of possible values taken by the random variable) can ...
, a positive number that measures the probability that the particle will be found at a certain location. The evolution equation is also linear in probability, for fundamental reasons. If the particle has some probability for going from position ''x'' to ''y'', and from ''z'' to ''y'', the probability of going to ''y'' starting from a state which is half-''x'' and half-''z'' is a half-and-half mixture of the probability of going to ''y'' from each of the options. This is the principle of linear superposition in probability. Quantum mechanics is different, because the numbers can be positive or negative. While the complex nature of the numbers is just a doubling, if you consider the real and imaginary parts separately, the sign of the coefficients is important. In probability, two different possible outcomes always add together, so that if there are more options to get to a point ''z'', the probability always goes up. In quantum mechanics, different possibilities can cancel. In probability theory with a finite number of states, the probabilities can always be multiplied by a positive number to make their sum equal to one. For example, if there is a three state probability system: : x , 1\rangle + y , 2\rangle + z , 3\rangle \, where the probabilities x,y,z are positive numbers. Rescaling ''x'',''y'',''z'' so that : x+y+z=1 \, The geometry of the state space is a revealed to be a triangle. In general it is a
simplex In geometry, a simplex (plural: simplexes or simplices) is a generalization of the notion of a triangle or tetrahedron to arbitrary dimensions. The simplex is so-named because it represents the simplest possible polytope in any given dimension. ...
. There are special points in a triangle or simplex corresponding to the corners, and these points are those where one of the probabilities is equal to 1 and the others are zero. These are the unique locations where the position is known with certainty. In a quantum mechanical system with three states, the quantum mechanical wavefunction is a superposition of states again, but this time twice as many quantities with no restriction on the sign: : A, 1\rangle + B, 2\rangle + C, 3\rangle = (A_r + iA_i) , 1\rangle + (B_r + i B_i) , 2\rangle + (C_r + iC_i) , 3\rangle \, rescaling the variables so that the sum of the squares is 1, the geometry of the space is revealed to be a high-dimensional sphere : A_r^2 + A_i^2 + B_r^2 + B_i^2 + C_r^2 + C_i^2 = 1 \,. A sphere has a large amount of symmetry, it can be viewed in different coordinate systems or bases. So unlike a probability theory, a quantum theory has a large number of different bases in which it can be equally well described. The geometry of the phase space can be viewed as a hint that the quantity in quantum mechanics which corresponds to the probability is the ''absolute square'' of the coefficient of the superposition.


Hamiltonian evolution

The numbers that describe the amplitudes for different possibilities define the
kinematics Kinematics is a subfield of physics, developed in classical mechanics, that describes the Motion (physics), motion of points, Physical object, bodies (objects), and systems of bodies (groups of objects) without considering the forces that cause ...
, the space of different states. The dynamics describes how these numbers change with time. For a particle that can be in any one of infinitely many discrete positions, a particle on a lattice, the superposition principle tells you how to make a state: : \sum_n \psi_n , n\rangle \, So that the infinite list of amplitudes (\ldots, \psi_, \psi_, \psi_0, \psi_1, \psi_2, \ldots) completely describes the quantum state of the particle. This list is called the state vector, and formally it is an element of a
Hilbert space In mathematics, Hilbert spaces (named after David Hilbert) allow generalizing the methods of linear algebra and calculus from (finite-dimensional) Euclidean vector spaces to spaces that may be infinite-dimensional. Hilbert spaces arise natural ...
, an infinite-dimensional complex
vector space In mathematics and physics, a vector space (also called a linear space) is a set whose elements, often called ''vectors'', may be added together and multiplied ("scaled") by numbers called '' scalars''. Scalars are often real numbers, but can ...
. It is usual to represent the state so that the sum of the
absolute square In mathematics, a square is the result of multiplying a number by itself. The verb "to square" is used to denote this operation. Squaring is the same as raising to the power  2, and is denoted by a superscript 2; for instance, the square ...
s of the amplitudes is one: : \sum \psi_n^*\psi_n = 1 For a particle described by probability theory random walking on a line, the analogous thing is the list of probabilities (\ldots,P_,P_,P_0,P_1,P_2,\ldots), which give the probability of any position. The quantities that describe how they change in time are the transition probabilities \scriptstyle K_(t), which gives the probability that, starting at x, the particle ends up at y time t later. The total probability of ending up at y is given by the sum over all the possibilities : P_y(t_0+t) = \sum_x P_x(t_0) K_(t) \, The condition of conservation of probability states that starting at any x, the total probability to end up ''somewhere'' must add up to 1: : \sum_y K_ = 1 \, So that the total probability will be preserved, K is what is called a
stochastic matrix In mathematics, a stochastic matrix is a square matrix used to describe the transitions of a Markov chain. Each of its entries is a nonnegative real number representing a probability. It is also called a probability matrix, transition matrix, ...
. When no time passes, nothing changes: for 0 elapsed time \scriptstyle K(0) = \delta_ , the K matrix is zero except from a state to itself. So in the case that the time is short, it is better to talk about the rate of change of the probability instead of the absolute change in the probability. : P_y(t+dt) = P_y(t) + dt \, \sum_x P_x R_ \, where \scriptstyle R_ is the time derivative of the K matrix: : R_ = . \, The equation for the probabilities is a differential equation that is sometimes called the master equation: : = \sum_x P_x R_ \, The R matrix is the probability per unit time for the particle to make a transition from x to y. The condition that the K matrix elements add up to one becomes the condition that the R matrix elements add up to zero: : \sum_y R_ = 0 \, One simple case to study is when the R matrix has an equal probability to go one unit to the left or to the right, describing a particle that has a constant rate of random walking. In this case \scriptstyle R_ is zero unless y is either ''x'' + 1, ''x'', or ''x'' − 1, when ''y'' is ''x'' + 1 or ''x'' − 1, the ''R'' matrix has value ''c'', and in order for the sum of the ''R'' matrix coefficients to equal zero, the value of R_ must be −2''c''. So the probabilities obey the discretized diffusion equation: : = c(P_ - 2P_x + P_) \, which, when c is scaled appropriately and the P distribution is smooth enough to think of the system in a
continuum limit In mathematical physics and mathematics, the continuum limit or scaling limit of a lattice model (physics), lattice model refers to its behaviour in the limit as the lattice spacing goes to zero. It is often useful to use lattice models to approxi ...
becomes: : = c \, Which is the
diffusion equation The diffusion equation is a parabolic partial differential equation. In physics, it describes the macroscopic behavior of many micro-particles in Brownian motion, resulting from the random movements and collisions of the particles (see Fick's la ...
. Quantum amplitudes give the rate at which amplitudes change in time, and they are mathematically exactly the same except that they are complex numbers. The analog of the finite time K matrix is called the U matrix: : \psi_n(t) = \sum_m U_(t) \psi_m \, Since the sum of the absolute squares of the amplitudes must be constant, U must be
unitary Unitary may refer to: Mathematics * Unitary divisor * Unitary element * Unitary group * Unitary matrix * Unitary morphism * Unitary operator * Unitary transformation * Unitary representation * Unitarity (physics) * ''E''-unitary inverse semigroup ...
: : \sum_n U^*_ U_ = \delta_ \, or, in matrix notation, : U^\dagger U = I \, The rate of change of ''U'' is called the
Hamiltonian Hamiltonian may refer to: * Hamiltonian mechanics, a function that represents the total energy of a system * Hamiltonian (quantum mechanics), an operator corresponding to the total energy of that system ** Dyall Hamiltonian, a modified Hamiltonian ...
''H'', up to a traditional factor of ''i'': : H_ = i U_ The Hamiltonian gives the rate at which the particle has an amplitude to go from m to n. The reason it is multiplied by i is that the condition that U is unitary translates to the condition: : (I + i H^\dagger \, dt )(I - i H \, dt ) = I : H^\dagger - H = 0 \, which says that H is
Hermitian {{Short description, none Numerous things are named after the French mathematician Charles Hermite (1822–1901): Hermite * Cubic Hermite spline, a type of third-degree spline * Gauss–Hermite quadrature, an extension of Gaussian quadrature meth ...
. The eigenvalues of the Hermitian matrix ''H'' are real quantities, which have a physical interpretation as energy levels. If the factor ''i'' were absent, the H matrix would be antihermitian and would have purely imaginary eigenvalues, which is not the traditional way quantum mechanics represents observable quantities like the energy. For a particle that has equal amplitude to move left and right, the Hermitian matrix H is zero except for nearest neighbors, where it has the value ''c''. If the coefficient is everywhere constant, the condition that ''H'' is Hermitian demands that the amplitude to move to the left is the complex conjugate of the amplitude to move to the right. The equation of motion for \psi is the time differential equation: : i = c^* \psi_ + c \psi_ In the case in which left and right are symmetric, ''c'' is real. By redefining the phase of the wavefunction in time, \psi\rightarrow \psi e^, the amplitudes for being at different locations are only rescaled, so that the physical situation is unchanged. But this phase rotation introduces a linear term. : i = c \psi_ - 2c\psi_n + c\psi_, which is the right choice of phase to take the continuum limit. When c is very large and \psi is slowly varying so that the lattice can be thought of as a line, this becomes the free
Schrödinger equation The Schrödinger equation is a linear partial differential equation that governs the wave function of a quantum-mechanical system. It is a key result in quantum mechanics, and its discovery was a significant landmark in the development of the ...
: : i = - If there is an additional term in the H matrix that is an extra phase rotation that varies from point to point, the continuum limit is the Schrödinger equation with a potential energy: : i = - + V(x) \psi These equations describe the motion of a single particle in non-relativistic quantum mechanics.


Quantum mechanics in imaginary time

The analogy between quantum mechanics and probability is very strong, so that there are many mathematical links between them. In a statistical system in discrete time, t=1,2,3, described by a transition matrix for one time step \scriptstyle K_, the probability to go between two points after a finite number of time steps can be represented as a sum over all paths of the probability of taking each path: : K_(T) = \sum_ \prod_t K_ \, where the sum extends over all paths x(t) with the property that x(0)=0 and x(T)=y. The analogous expression in quantum mechanics is the path integral. A generic transition matrix in probability has a stationary distribution, which is the eventual probability to be found at any point no matter what the starting point. If there is a nonzero probability for any two paths to reach the same point at the same time, this stationary distribution does not depend on the initial conditions. In probability theory, the probability m for the stochastic matrix obeys
detailed balance The principle of detailed balance can be used in kinetic systems which are decomposed into elementary processes (collisions, or steps, or elementary reactions). It states that at equilibrium, each elementary process is in equilibrium with its reve ...
when the stationary distribution \rho_n has the property: : \rho_n K_ = \rho_m K_ \, Detailed balance says that the total probability of going from m to n in the stationary distribution, which is the probability of starting at m \rho_m times the probability of hopping from m to n, is equal to the probability of going from n to m, so that the total back-and-forth flow of probability in equilibrium is zero along any hop. The condition is automatically satisfied when n=m, so it has the same form when written as a condition for the transition-probability R matrix. : \rho_n R_ = \rho_m R_ \, When the R matrix obeys detailed balance, the scale of the probabilities can be redefined using the stationary distribution so that they no longer sum to 1: : p'_n = \sqrt\;p_n \, In the new coordinates, the R matrix is rescaled as follows: : \sqrt R_ = H_ \, and H is symmetric : H_ = H_ \, This matrix H defines a quantum mechanical system: : i \psi_n = \sum H_ \psi_m \, whose Hamiltonian has the same eigenvalues as those of the R matrix of the statistical system. The
eigenvectors In linear algebra, an eigenvector () or characteristic vector of a linear transformation is a nonzero vector that changes at most by a scalar factor when that linear transformation is applied to it. The corresponding eigenvalue, often denoted b ...
are the same too, except expressed in the rescaled basis. The stationary distribution of the statistical system is the ''ground state'' of the Hamiltonian and it has energy exactly zero, while all the other energies are positive. If H is exponentiated to find the U matrix: : U(t) = e^ \, and t is allowed to take on complex values, the K' matrix is found by taking time imaginary. : K'(t) = e^ \, For quantum systems which are invariant under time reversal the Hamiltonian can be made real and symmetric, so that the action of time-reversal on the wave-function is just complex conjugation. If such a Hamiltonian has a unique lowest energy state with a positive real wave-function, as it often does for physical reasons, it is connected to a stochastic system in imaginary time. This relationship between stochastic systems and quantum systems sheds much light on
supersymmetry In a supersymmetric theory the equations for force and the equations for matter are identical. In theoretical and mathematical physics, any theory with this property has the principle of supersymmetry (SUSY). Dozens of supersymmetric theories e ...
.


Experiments and applications

Successful experiments involving superpositions of relatively large (by the standards of quantum physics) objects have been performed. * A "
cat state In quantum mechanics, the cat state, named after Schrödinger's cat, is a quantum state composed of two diametrically opposed conditions ''at the same time'', such as the possibilities that a cat is alive and dead at the same time. Generalizing Sch ...
" has been achieved with
photon A photon () is an elementary particle that is a quantum of the electromagnetic field, including electromagnetic radiation such as light and radio waves, and the force carrier for the electromagnetic force. Photons are massless, so they always ...
s. * A
beryllium Beryllium is a chemical element with the symbol Be and atomic number 4. It is a steel-gray, strong, lightweight and brittle alkaline earth metal. It is a divalent element that occurs naturally only in combination with other elements to form mi ...
ion An ion () is an atom or molecule with a net electrical charge. The charge of an electron is considered to be negative by convention and this charge is equal and opposite to the charge of a proton, which is considered to be positive by conven ...
has been trapped in a superposed state. * A
double slit experiment In modern physics, the double-slit experiment is a demonstration that light and matter can display characteristics of both classically defined waves and particles; moreover, it displays the fundamentally probabilistic nature of quantum mechanica ...
has been performed with molecules as large as buckyballs and functionalized oligoporphyrins with up to 2000 atoms. * A 2013 experiment superposed molecules containing 15,000 each of protons, neutrons and electrons. The molecules were of compounds selected for their good thermal stability, and were evaporated into a beam at a temperature of 600 K. The beam was prepared from highly purified chemical substances, but still contained a mixture of different molecular species. Each species of molecule interfered only with itself, as verified by mass spectrometry. * An experiment involving a superconducting quantum interference device ("SQUID") has been linked to the theme of the "cat state" thought experiment. :By use of very low temperatures, very fine experimental arrangements were made to protect in near isolation and preserve the coherence of intermediate states, for a duration of time, between preparation and detection, of SQUID currents. Such a SQUID current is a coherent physical assembly of perhaps billions of electrons. Because of its coherence, such an assembly may be regarded as exhibiting "collective states" of a macroscopic quantal entity. For the principle of superposition, after it is prepared but before it is detected, it may be regarded as exhibiting an intermediate state. It is not a single-particle state such as is often considered in discussions of interference, for example by Dirac in his famous dictum stated above. Dirac, P. A. M. (1930/1958), p. 9. Moreover, though the 'intermediate' state may be loosely regarded as such, it has not been produced as an output of a secondary quantum analyser that was fed a pure state from a primary analyser, and so this is not an example of superposition as strictly and narrowly defined. :Nevertheless, after preparation, but before measurement, such a SQUID state may be regarded in a manner of speaking as a "pure" state that is a superposition of a clockwise and an anti-clockwise current state. In a SQUID, collective electron states can be physically prepared in near isolation, at very low temperatures, so as to result in protected coherent intermediate states. What is remarkable here is that there are two well-separated self-coherent collective states that exhibit such
metastability In chemistry and physics, metastability denotes an intermediate Energy level, energetic state within a dynamical system other than the system's ground state, state of least energy. A ball resting in a hollow on a slope is a simple example of me ...
. The crowd of electrons tunnels back and forth between the clockwise and the anti-clockwise states, as opposed to forming a single intermediate state in which there is no definite collective sense of current flow. * An experiment involving a
flu virus ''Orthomyxoviridae'' (from Greek ὀρθός, ''orthós'' 'straight' + μύξα, ''mýxa'' 'mucus') is a family of negative-sense RNA viruses. It includes seven genera: ''Alphainfluenzavirus'', ''Betainfluenzavirus'', '' Gammainfluenzavirus'', '' ...
has been proposed. * A
piezoelectric Piezoelectricity (, ) is the electric charge that accumulates in certain solid materials—such as crystals, certain ceramics, and biological matter such as bone, DNA, and various proteins—in response to applied Stress (mechanics), mechanical s ...
"
tuning fork A tuning fork is an acoustic resonator in the form of a two-pronged fork with the prongs (tines) formed from a U-shaped bar of elastic metal (usually steel). It resonates at a specific constant pitch when set vibrating by striking it against ...
" has been constructed, which can be placed into a superposition of vibrating and non-vibrating states. The resonator comprises about 10 trillion atoms. * Recent research indicates that
chlorophyll Chlorophyll (also chlorophyl) is any of several related green pigments found in cyanobacteria and in the chloroplasts of algae and plants. Its name is derived from the Greek words , ("pale green") and , ("leaf"). Chlorophyll allow plants to a ...
within
plants Plants are predominantly Photosynthesis, photosynthetic eukaryotes of the Kingdom (biology), kingdom Plantae. Historically, the plant kingdom encompassed all living things that were not animals, and included algae and fungi; however, all curr ...
appears to exploit the feature of quantum superposition to achieve greater efficiency in transporting energy, allowing pigment proteins to be spaced further apart than would otherwise be possible. * An experiment has been proposed, with a bacterial cell cooled to 10 mK, using an electromechanical oscillator. At that temperature, all metabolism would be stopped, and the cell might behave virtually as a definite chemical species. For detection of interference, it would be necessary that the cells be supplied in large numbers as pure samples of identical and detectably recognizable virtual chemical species. It is not known whether this requirement can be met by bacterial cells. They would be in a state of suspended animation during the experiment. In
quantum computing Quantum computing is a type of computation whose operations can harness the phenomena of quantum mechanics, such as superposition, interference, and entanglement. Devices that perform quantum computations are known as quantum computers. Though ...
the phrase "cat state" often refers to the
GHZ state The hertz (symbol: Hz) is the unit of frequency in the International System of Units (SI), equivalent to one event (or cycle) per second. The hertz is an SI derived unit whose expression in terms of SI base units is s−1, meaning that on ...
, the special entangled state of
qubit In quantum computing, a qubit () or quantum bit is a basic unit of quantum information—the quantum version of the classic binary bit physically realized with a two-state device. A qubit is a two-state (or two-level) quantum-mechanical system, ...
s wherein the qubits are in an equal superposition of all being 0 and all being 1; i.e., : , \psi \rangle = \frac \bigg( , 00\ldots0 \rangle + , 11\ldots1 \rangle \bigg).


Formal interpretation

Applying the
superposition principle The superposition principle, also known as superposition property, states that, for all linear systems, the net response caused by two or more stimuli is the sum of the responses that would have been caused by each stimulus individually. So tha ...
to a quantum mechanical particle, the configurations of the particle are all positions, so the superpositions make a complex wave in space. The coefficients of the linear superposition are a wave which describes the particle as best as is possible, and whose amplitude interferes according to the
Huygens principle Huygens (also Huijgens, Huigens, Huijgen/Huygen, or Huigen) is a Dutch patronymic surname, meaning "son of Hugo". Most references to "Huygens" are to the polymath Christiaan Huygens. Notable people with the surname include: * Jan Huygen (1563–1 ...
. For any physical property in
quantum mechanics Quantum mechanics is a fundamental theory in physics that provides a description of the physical properties of nature at the scale of atoms and subatomic particles. It is the foundation of all quantum physics including quantum chemistry, ...
, there is a list of all the states where that property has some value. These states are necessarily perpendicular to each other using the Euclidean notion of perpendicularity which comes from sums-of-squares length, except that they also must not be i multiples of each other. This list of perpendicular states has an associated value which is the value of the physical property. The superposition principle guarantees that any state can be written as a combination of states of this form with complex coefficients. Write each state with the value q of the physical quantity as a vector in some basis \psi^q_n, a list of numbers at each value of n for the vector which has value q for the physical quantity. Now form the outer product of the vectors by multiplying all the vector components and add them with coefficients to make the matrix : A_ = \sum_q q \psi^_n \psi^q_m where the sum extends over all possible values of q. This matrix is necessarily symmetric because it is formed from the orthogonal states, and has eigenvalues q. The matrix A is called the observable associated to the physical quantity. It has the property that the eigenvalues and eigenvectors determine the physical quantity and the states which have definite values for this quantity. Every physical quantity has a
Hermitian {{Short description, none Numerous things are named after the French mathematician Charles Hermite (1822–1901): Hermite * Cubic Hermite spline, a type of third-degree spline * Gauss–Hermite quadrature, an extension of Gaussian quadrature meth ...
linear operator In mathematics, and more specifically in linear algebra, a linear map (also called a linear mapping, linear transformation, vector space homomorphism, or in some contexts linear function) is a mapping V \to W between two vector spaces that pre ...
associated to it, and the states where the value of this physical quantity is definite are the
eigenstate In quantum physics, a quantum state is a mathematical entity that provides a probability distribution for the outcomes of each possible measurement on a system. Knowledge of the quantum state together with the rules for the system's evolution in t ...
s of this linear operator. The linear combination of two or more eigenstates results in quantum superposition of two or more values of the quantity. If the quantity is measured, the value of the physical quantity will be random, with a probability equal to the square of the coefficient of the superposition in the linear combination. Immediately after the measurement, the state will be given by the eigenvector corresponding to the measured eigenvalue.


Physical interpretation

It is natural to ask why ordinary everyday objects and events do not seem to display quantum mechanical features such as superposition. Indeed, this is sometimes regarded as "mysterious", for instance by Richard Feynman. Feynman, R. P., Leighton, R. B., Sands, M. (1965), § 1-1. In 1935,
Erwin Schrödinger Erwin Rudolf Josef Alexander Schrödinger (, ; ; 12 August 1887 – 4 January 1961), sometimes written as or , was a Nobel Prize-winning Austrian physicist with Irish citizenship who developed a number of fundamental results in quantum theory ...
devised a well-known thought experiment, now known as
Schrödinger's cat In quantum mechanics, Schrödinger's cat is a thought experiment that illustrates a paradox of quantum superposition. In the thought experiment, a hypothetical cat may be considered simultaneously both alive and dead, while it is unobserved in ...
, which highlighted this dissonance between quantum mechanics and classical physics. One modern view is that this mystery is explained by
quantum decoherence Quantum decoherence is the loss of quantum coherence. In quantum mechanics, particles such as electrons are described by a wave function, a mathematical representation of the quantum state of a system; a probabilistic interpretation of the wave ...
. A macroscopic system (such as a cat) may evolve over time into a superposition of classically distinct quantum states (such as "alive" and "dead"). The mechanism that achieves this is a subject of significant research, one mechanism suggests that the state of the cat is entangled with the state of its environment (for instance, the molecules in the atmosphere surrounding it), when averaged over the possible quantum states of the environment (a physically reasonable procedure unless the quantum state of the environment can be controlled or measured precisely) the resulting
mixed quantum state In quantum physics, a quantum state is a mathematical entity that provides a probability distribution for the outcomes of each possible measurement on a system. Knowledge of the quantum state together with the rules for the system's evolution i ...
for the cat is very close to a classical probabilistic state where the cat has some definite probability to be dead or alive, just as a classical observer would expect in this situation. Another proposed class of theories is that the fundamental time evolution equation is incomplete, and requires the addition of some type of fundamental
Lindbladian In quantum mechanics, the Gorini–Kossakowski–Sudarshan–Lindblad equation (GKSL equation, named after Vittorio Gorini, Andrzej Kossakowski, George Sudarshan and Göran Lindblad), master equation in Lindblad form, quantum Liouvillian, or Lind ...
, the reason for this addition and the form of the additional term varies from theory to theory. A popular theory is Continuous spontaneous localization, where the lindblad term is proportional to the spatial separation of the states, this too results in a quasi-classical probabilistic state.


See also

*
Eigenstates In quantum physics, a quantum state is a mathematical entity that provides a probability distribution for the outcomes of each possible measurement on a system. Knowledge of the quantum state together with the rules for the system's evolution i ...
*
Mach–Zehnder interferometer The Mach–Zehnder interferometer is a device used to determine the relative phase shift variations between two collimated beams derived by splitting light from a single source. The interferometer has been used, among other things, to measure pha ...
* Penrose interpretation * Pure qubit state *
Quantum computation Quantum computing is a type of computation whose operations can harness the phenomena of quantum mechanics, such as superposition, interference, and entanglement. Devices that perform quantum computations are known as quantum computers. Though ...
*
Schrödinger's cat In quantum mechanics, Schrödinger's cat is a thought experiment that illustrates a paradox of quantum superposition. In the thought experiment, a hypothetical cat may be considered simultaneously both alive and dead, while it is unobserved in ...
*
Superposition principle The superposition principle, also known as superposition property, states that, for all linear systems, the net response caused by two or more stimuli is the sum of the responses that would have been caused by each stimulus individually. So tha ...
*
Wave packet In physics, a wave packet (or wave train) is a short "burst" or "envelope" of localized wave action that travels as a unit. A wave packet can be analyzed into, or can be synthesized from, an infinite set of component sinusoidal waves of diffe ...


References


Bibliography of cited references

* Bohr, N. (1927/1928). The quantum postulate and the recent development of atomic theory
''Nature'' Supplement 14 April 1928, 121: 580–590
* Cohen-Tannoudji, C., Diu, B., Laloë, F. (1973/1977). ''Quantum Mechanics'', translated from the French by S. R. Hemley, N. Ostrowsky, D. Ostrowsky, second edition, volume 1, Wiley, New York, . * Dirac, P. A. M. (1930/1958). ''The Principles of Quantum Mechanics'', 4th edition, Oxford University Press. * Einstein, A. (1949). Remarks concerning the essays brought together in this co-operative volume, translated from the original German by the editor, pp. 665–688 in Schilpp, P. A. editor (1949)
''Albert Einstein: Philosopher-Scientist''
volume , Open Court, La Salle IL. * Feynman, R. P., Leighton, R.B., Sands, M. (1965). ''The Feynman Lectures on Physics''
volume 3
Addison-Wesley, Reading, MA. * Merzbacher, E. (1961/1970). ''Quantum Mechanics'', second edition, Wiley, New York. * Messiah, A. (1961). ''Quantum Mechanics'', volume 1, translated by G.M. Temmer from the French ''Mécanique Quantique'', North-Holland, Amsterdam. * {{DEFAULTSORT:Quantum Superposition Quantum mechanics Articles containing video clips