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In
quantum mechanics Quantum mechanics is a fundamental theory in physics that provides a description of the physical properties of nature at the scale of atoms and subatomic particles. It is the foundation of all quantum physics including quantum chemistry, q ...
, a quantum Markov semigroup describes the dynamics in a Markovian
open quantum system In physics, an open quantum system is a quantum-mechanical system that interacts with an external quantum system, which is known as the ''environment'' or a ''bath''. In general, these interactions significantly change the dynamics of the system an ...
. The axiomatic definition of the prototype of quantum Markov semigroups was first introduced by A. M. Kossakowski in 1972, and then developed by V. Gorini, A. M. Kossakowski,
E. C. G. Sudarshan Ennackal Chandy George Sudarshan (also known as E. C. G. Sudarshan; 16 September 1931 – 13 May 2018) was an Indian American theoretical physicist and a professor at the University of Texas. Sudarshan has been credited with numerous contrib ...
and
Göran Lindblad Göran Lindblad may refer to: * Göran Lindblad (politician) (born 1950), Swedish politician * Göran Lindblad (physicist) Göran Lindblad (9 July 1940 - 30 November 2022) was a Swedish theoretical physicist and a professor at the KTH Royal Ins ...
in 1976.


Motivation

An ideal
quantum system Quantum mechanics is a fundamental Scientific theory, theory in physics that provides a description of the physical properties of nature at the scale of atoms and subatomic particles. It is the foundation of all quantum physics including qua ...
is not realistic because it should be completely isolated while, in practice, it is influenced by the
coupling A coupling is a device used to connect two shafts together at their ends for the purpose of transmitting power. The primary purpose of couplings is to join two pieces of rotating equipment while permitting some degree of misalignment or end mov ...
to an environment, which typically has a large number of degrees of freedom (for example an
atom Every atom is composed of a nucleus and one or more electrons bound to the nucleus. The nucleus is made of one or more protons and a number of neutrons. Only the most common variety of hydrogen has no neutrons. Every solid, liquid, gas ...
interacting with the surrounding radiation field). A complete microscopic description of the degrees of freedom of the environment is typically too complicated. Hence, one looks for simpler descriptions of the dynamics of the open system. In principle, one should investigate the
unitary Unitary may refer to: Mathematics * Unitary divisor * Unitary element * Unitary group * Unitary matrix * Unitary morphism * Unitary operator * Unitary transformation * Unitary representation * Unitarity (physics) * ''E''-unitary inverse semigroup ...
dynamics of the total system, i.e. the system and the environment, to obtain information about the reduced system of interest by averaging the appropriate observables over the degrees of freedom of the environment. To model the dissipative effects due to the interaction with the environment, the
Schrödinger equation The Schrödinger equation is a linear partial differential equation that governs the wave function of a quantum-mechanical system. It is a key result in quantum mechanics, and its discovery was a significant landmark in the development of th ...
is replaced by a suitable
master equation In physics, chemistry and related fields, master equations are used to describe the time evolution of a system that can be modelled as being in a probabilistic combination of states at any given time and the switching between states is determine ...
, such as a
Lindblad equation In quantum mechanics, the Gorini–Kossakowski–Sudarshan–Lindblad equation (GKSL equation, named after Vittorio Gorini, Andrzej Kossakowski, George Sudarshan and Göran Lindblad), master equation in Lindblad form, quantum Liouvillian, or Lind ...
or a stochastic Schrödinger equation in which the infinite degrees of freedom of the environment are "synthesized" as a few
quantum noise Quantum noise is noise arising from the indeterminate state of matter in accordance with fundamental principles of quantum mechanics, specifically the uncertainty principle and via zero-point energy fluctuations. Quantum noise is due to the appa ...
s. Mathematically, time evolution in a Markovian open quantum system is no longer described by means of
one-parameter group In mathematics, a one-parameter group or one-parameter subgroup usually means a continuous group homomorphism :\varphi : \mathbb \rightarrow G from the real line \mathbb (as an additive group) to some other topological group G. If \varphi is i ...
s of unitary maps, but one needs to introduce quantum Markov semigroups.


Definitions


Quantum dynamical semigroup (QDS)

In general, quantum dynamical semigroups can be defined on
von Neumann algebra In mathematics, a von Neumann algebra or W*-algebra is a *-algebra of bounded operators on a Hilbert space that is closed in the weak operator topology and contains the identity operator. It is a special type of C*-algebra. Von Neumann a ...
s, so the dimensionality of the system could be infinite. Let \mathcal be a von Neumann algebra acting on
Hilbert space In mathematics, Hilbert spaces (named after David Hilbert) allow generalizing the methods of linear algebra and calculus from (finite-dimensional) Euclidean vector spaces to spaces that may be infinite-dimensional. Hilbert spaces arise natu ...
\mathcal , a quantum dynamical semigroup on \mathcal is a collection of bounded operators on \mathcal , denoted by \mathcal := \left( \mathcal_t \right)_ , with the following properties: # \mathcal_0 \left( a \right) = a , \forall a \in \mathcal , # \mathcal_ \left( a \right) = \mathcal_t \left( \mathcal_s \left( a \right) \right) , \forall s, t \ge 0 , \forall a \in \mathcal , # \mathcal_t is
completely positive In mathematics a positive map is a map between C*-algebras that sends positive elements to positive elements. A completely positive map is one which satisfies a stronger, more robust condition. Definition Let A and B be C*-algebras. A linear ...
for all t \ge 0 , # \mathcal_t is a \sigma -weakly continuous operator in \mathcal for all t \ge 0 , # For all a \in \mathcal , the map t \mapsto \mathcal_t \left( a \right) is continuous with respect to the \sigma -weak topology on \mathcal . It is worth mentioning that, under the condition of complete positivity, the operators \mathcal_t are \sigma -weakly continuous if and only if \mathcal_t are normal. Recall that, letting \mathcal_+ denote the
convex cone In linear algebra, a ''cone''—sometimes called a linear cone for distinguishing it from other sorts of cones—is a subset of a vector space that is closed under scalar multiplication; that is, is a cone if x\in C implies sx\in C for every . ...
of positive elements in \mathcal , a positive operator T : \mathcal \rightarrow \mathcal is said to be normal if for every increasing
net Net or net may refer to: Mathematics and physics * Net (mathematics), a filter-like topological generalization of a sequence * Net, a linear system of divisors of dimension 2 * Net (polyhedron), an arrangement of polygons that can be folded u ...
\left( x_\alpha \right)_\alpha in \mathcal_+ with
least upper bound In mathematics, the infimum (abbreviated inf; plural infima) of a subset S of a partially ordered set P is a greatest element in P that is less than or equal to each element of S, if such an element exists. Consequently, the term ''greatest lo ...
x in \mathcal_+ one has : \lim_ \langle u, (T x_\alpha) u \rangle = \sup_ \langle u, (T x_\alpha) u \rangle = \langle u, (T x) u \rangle for each u in a norm-dense linear sub-manifold of \mathcal .


Quantum Markov semigroup (QMS)

A quantum dynamical semigroup \mathcal is said to be identity-preserving (or conservative, or Markovian) if where \boldsymbol \in \mathcal is the identity element. For simplicity, \mathcal is called quantum Markov semigroup. Notice that, the identity-preserving property and positivity of \mathcal_t imply \left\, \mathcal_t \right\, = 1 for all t \ge 0 and then \mathcal is a
contraction semigroup In mathematical analysis, a ''C''0-semigroup Γ(''t''), ''t'' ≥ 0, is called a quasicontraction semigroup if there is a constant ''ω'' such that , , Γ(''t''), ,  ≤ exp(''ωt'') for all ''t'' ≥ 0. Γ(''t'') is c ...
. The Condition () plays an important role not only in the proof of uniqueness and unitarity of solution of a Hudson-
Parthasarathy Krishna (; Sanskrit: , ' in IAST, pronounced (Classical Sanskrit) and in ''Vedic Sanskrit'' is a Hindu deity worshipped across many traditions of Hinduism in a variety of different perspectives. In Hinduism, Krishna is recognized as the comple ...
quantum stochastic differential equation, but also in deducing regularity conditions for paths of classical Markov processes in view of
operator theory In mathematics, operator theory is the study of linear operators on function spaces, beginning with differential operators and integral operators. The operators may be presented abstractly by their characteristics, such as bounded linear oper ...
.


Infinitesimal generator of QDS

The infinitesimal generator of a quantum dynamical semigroup \mathcal is the operator \mathcal with domain \operatorname (\mathcal) , where : \operatorname \left( \mathcal \right) := \left\ and \mathcal(a) := b .


Characterization of generators of uniformly continuous QMSs

If the quantum Markov semigroup \mathcal is uniformly continuous in addition, which means \lim_ \left\, \mathcal_t - \mathcal_0 \right\, = 0 , then * the infinitesimal generator \mathcal will be a
bounded operator In functional analysis and operator theory, a bounded linear operator is a linear transformation L : X \to Y between topological vector spaces (TVSs) X and Y that maps bounded subsets of X to bounded subsets of Y. If X and Y are normed vecto ...
on von Neumann algebra \mathcal with domain \mathrm (\mathcal) = \mathcal , * the map t \mapsto \mathcal_t a will automatically be continuous for every a \in \mathcal , * the infinitesimal generator \mathcal will be also \sigma -weakly continuous. Under such assumption, the infinitesimal generator \mathcal has the characterization : \mathcal \left( a \right) = i \left H, a \right+ \sum_ \left( V_j^\dagger a V_j - \frac \left\ \right) where a \in \mathcal , V_j \in \mathcal (\mathcal) , \sum_ V_j^\dagger V_j \in \mathcal (\mathcal) , and H \in \mathcal (\mathcal) is
self-adjoint In mathematics, and more specifically in abstract algebra, an element ''x'' of a *-algebra is self-adjoint if x^*=x. A self-adjoint element is also Hermitian, though the reverse doesn't necessarily hold. A collection ''C'' of elements of a sta ...
. Moreover, above \left \cdot, \cdot \right denotes the
commutator In mathematics, the commutator gives an indication of the extent to which a certain binary operation fails to be commutative. There are different definitions used in group theory and ring theory. Group theory The commutator of two elements, ...
, and \left\ the anti-commutator.


Selected recent publications

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See also

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References

{{reflist Quantum mechanics Semigroup theory