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The degree of ionization (also known as ''ionization yield'' in the literature) refers to the proportion of neutral particles, such as those in a
gas Gas is one of the four fundamental states of matter (the others being solid, liquid, and plasma). A pure gas may be made up of individual atoms (e.g. a noble gas like neon), elemental molecules made from one type of atom (e.g. oxygen), or ...
or aqueous solution, that are
ionized Ionization, or Ionisation is the process by which an atom or a molecule acquires a negative or positive charge by gaining or losing electrons, often in conjunction with other chemical changes. The resulting electrically charged atom or molecule ...
. For
electrolyte An electrolyte is a medium containing ions that is electrically conducting through the movement of those ions, but not conducting electrons. This includes most soluble salts, acids, and bases dissolved in a polar solvent, such as water. Upon dis ...
s, it could be understood as a capacity of acid/base to ionize itself. A low degree of ionization is sometimes called ''partially ionized'' (also ''weakly ionized''), and a high degree of ionization as ''fully ionized''. However, fully ionized can also mean that an ion has no electrons left. Ionization refers to the process whereby an
atom Every atom is composed of a nucleus and one or more electrons bound to the nucleus. The nucleus is made of one or more protons and a number of neutrons. Only the most common variety of hydrogen has no neutrons. Every solid, liquid, gas, and ...
or
molecule A molecule is a group of two or more atoms held together by attractive forces known as chemical bonds; depending on context, the term may or may not include ions which satisfy this criterion. In quantum physics, organic chemistry, and bioch ...
loses one or several
electron The electron ( or ) is a subatomic particle with a negative one elementary electric charge. Electrons belong to the first generation of the lepton particle family, and are generally thought to be elementary particles because they have no kn ...
s from its
atomic orbital In atomic theory and quantum mechanics, an atomic orbital is a function describing the location and wave-like behavior of an electron in an atom. This function can be used to calculate the probability of finding any electron of an atom in any spe ...
, or conversely gains an additional one, from an incoming free
electron The electron ( or ) is a subatomic particle with a negative one elementary electric charge. Electrons belong to the first generation of the lepton particle family, and are generally thought to be elementary particles because they have no kn ...
(electron attachment). In both cases, the atom or molecule ceases to be a
neutral particle In physics, a neutral particle is a particle with no electric charge, such as a neutron. The term ''neutral particles'' should not be confused with ''truly neutral particles'', the subclass of neutral particles that are also identical to their ow ...
and becomes a
charge carrier In physics, a charge carrier is a particle or quasiparticle that is free to move, carrying an electric charge, especially the particles that carry electric charges in electrical conductors. Examples are electrons, ions and holes. The term is used ...
. If the species has lost one or several electrons, it becomes positively charged and is called a positive
ion An ion () is an atom or molecule with a net electrical charge. The charge of an electron is considered to be negative by convention and this charge is equal and opposite to the charge of a proton, which is considered to be positive by conve ...
, or
cation An ion () is an atom or molecule with a net electrical charge. The charge of an electron is considered to be negative by convention and this charge is equal and opposite to the charge of a proton, which is considered to be positive by convent ...
. On the contrary, if the species has gained one or several additional electrons, it becomes negatively charged and is called a negative ion, or
anion An ion () is an atom or molecule with a net electrical charge. The charge of an electron is considered to be negative by convention and this charge is equal and opposite to the charge of a proton, which is considered to be positive by convent ...
. Individual free electrons and ions in a plasma have very short lives typically inferior to the
microsecond A microsecond is a unit of time in the International System of Units (SI) equal to one millionth (0.000001 or 10−6 or ) of a second. Its symbol is μs, sometimes simplified to us when Unicode is not available. A microsecond is equal to 1000 n ...
, as ionization and recombination,
excitation Excitation, excite, exciting, or excitement may refer to: * Excitation (magnetic), provided with an electrical generator or alternator * Excite Ballpark, located in San Jose, California * Excite (web portal), web portal owned by IAC * Electron exc ...
and relaxation are collective continuous processes.


Chemistry usage

The degree of dissociation ''α'' (also known as degree of ionization), is a way of representing the strength of an acid. It is defined as the ratio of the number of ionized molecules and the number of molecules dissolved in water. It can be represented as a decimal number or as a percentage. One can classify strong acids as those having ionization degrees above 30%, weak acids as those with ''α'' below 30%, and the rest as moderate acids, at a specified molar concentration.


Physics usage

In
plasma Plasma or plasm may refer to: Science * Plasma (physics), one of the four fundamental states of matter * Plasma (mineral), a green translucent silica mineral * Quark–gluon plasma, a state of matter in quantum chromodynamics Biology * Blood pla ...
, the degree of ionization \alpha refers to the proportion of neutral particles that are ionized: : \alpha = \frac where n_i is the ion density and n_n the neutral density (in particles per cubic meter). It is a dimensionless number, sometimes expressed as a percentage. When referred to an atom, "fully ionized" means that there are no bound electrons left, resulting in a bare
nucleus Nucleus ( : nuclei) is a Latin word for the seed inside a fruit. It most often refers to: *Atomic nucleus, the very dense central region of an atom *Cell nucleus, a central organelle of a eukaryotic cell, containing most of the cell's DNA Nucle ...
. A particular case of fully ionized gases are very hot thermonuclear plasmas, such as plasmas artificially produced in
nuclear explosion A nuclear explosion is an explosion that occurs as a result of the rapid release of energy from a high-speed nuclear reaction. The driving reaction may be nuclear fission or nuclear fusion or a multi-stage cascading combination of the two, t ...
s or naturally formed in our
Sun The Sun is the star at the center of the Solar System. It is a nearly perfect ball of hot plasma, heated to incandescence by nuclear fusion reactions in its core. The Sun radiates this energy mainly as light, ultraviolet, and infrared radi ...
and all
stars A star is an astronomical object comprising a luminous spheroid of plasma held together by its gravity. The nearest star to Earth is the Sun. Many other stars are visible to the naked eye at night, but their immense distances from Earth ma ...
in the universe. Regular stars largely contain
hydrogen Hydrogen is the chemical element with the symbol H and atomic number 1. Hydrogen is the lightest element. At standard conditions hydrogen is a gas of diatomic molecules having the formula . It is colorless, odorless, tasteless, non-toxic, an ...
and
helium Helium (from el, ἥλιος, helios, lit=sun) is a chemical element with the symbol He and atomic number 2. It is a colorless, odorless, tasteless, non-toxic, inert, monatomic gas and the first in the noble gas group in the periodic table. ...
that are fully ionized into
protons A proton is a stable subatomic particle, symbol , H+, or 1H+ with a positive electric charge of +1 ''e'' elementary charge. Its mass is slightly less than that of a neutron and 1,836 times the mass of an electron (the proton–electron mass ...
(H+) and alpha-particles (He2+).


History

Ionized matter was first identified in a discharge tube (or
Crookes tube A Crookes tube (also Crookes–Hittorf tube) is an early experimental electrical discharge tube, with partial vacuum, invented by English physicist William Crookes and others around 1869-1875, in which cathode rays, streams of electrons, were dis ...
), and so described by
Sir William Crookes Sir William Crookes (; 17 June 1832 – 4 April 1919) was a British chemist and physicist who attended the Royal College of Chemistry, now part of Imperial College London, and worked on spectroscopy. He was a pioneer of vacuum tubes, inventing t ...
in 1879 (he called it "radiant matter"). The nature of the
Crookes tube A Crookes tube (also Crookes–Hittorf tube) is an early experimental electrical discharge tube, with partial vacuum, invented by English physicist William Crookes and others around 1869-1875, in which cathode rays, streams of electrons, were dis ...
"
cathode ray Cathode rays or electron beam (e-beam) are streams of electrons observed in discharge tubes. If an evacuated glass tube is equipped with two electrodes and a voltage is applied, glass behind the positive electrode is observed to glow, due to ele ...
" matter was subsequently identified by English physicist Sir J.J. Thomson in 1897, and dubbed "plasma" by
Irving Langmuir Irving Langmuir (; January 31, 1881 – August 16, 1957) was an American chemist, physicist, and engineer. He was awarded the Nobel Prize in Chemistry in 1932 for his work in surface chemistry. Langmuir's most famous publication is the 1919 art ...
in 1928,I. Langmuir,
Oscillations in ionized gases
" ''Proc. Natl. Acad. Sci. U.S.'', vol. 14, p. 628, 1928
perhaps because it reminded him of a
blood plasma Blood plasma is a light amber-colored liquid component of blood in which blood cells are absent, but contains proteins and other constituents of whole blood in suspension. It makes up about 55% of the body's total blood volume. It is the intra ...
.G. L. Rogoff, Ed., ''IEEE Transactions on Plasma Science'', vol. 19, p. 989, Dec. 1991. See extract at {{cite web , url=http://www.plasmacoalition.org/what.htm , title=Coalition for Plasma Science - What is a plasma? , accessdate=2006-05-24 , url-status=dead , archiveurl=https://web.archive.org/web/20060420130322/http://www.plasmacoalition.org/what.htm , archivedate=20 April 2006


See also

*
List of plasma physics articles This is a list of plasma physics topics. A * Ablation * Abradable coating * Abraham–Lorentz force * Absorption band * Accretion disk * Active galactic nucleus * Adiabatic invariant * ADITYA (tokamak) * Aeronomy * Afterglow plasma * Air ...


Footnotes

Plasma physics Ions Physical chemistry