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Pyroxferroite (Fe2+,Ca)SiO3 is a single chain
inosilicate Silicate minerals are rock-forming minerals made up of silicate groups. They are the largest and most important class of minerals and make up approximately 90 percent of Earth's crust. In mineralogy, the crystalline forms of silica (silicon dio ...
. It is mostly composed of
iron Iron is a chemical element; it has symbol Fe () and atomic number 26. It is a metal that belongs to the first transition series and group 8 of the periodic table. It is, by mass, the most common element on Earth, forming much of Earth's o ...
,
silicon Silicon is a chemical element; it has symbol Si and atomic number 14. It is a hard, brittle crystalline solid with a blue-grey metallic lustre, and is a tetravalent metalloid (sometimes considered a non-metal) and semiconductor. It is a membe ...
and
oxygen Oxygen is a chemical element; it has chemical symbol, symbol O and atomic number 8. It is a member of the chalcogen group (periodic table), group in the periodic table, a highly reactivity (chemistry), reactive nonmetal (chemistry), non ...
, with smaller fractions of
calcium Calcium is a chemical element; it has symbol Ca and atomic number 20. As an alkaline earth metal, calcium is a reactive metal that forms a dark oxide-nitride layer when exposed to air. Its physical and chemical properties are most similar to it ...
and several other metals. Together with armalcolite and tranquillityite, it is one of the three minerals which were discovered on the Moon during the 1969
Apollo 11 Apollo 11 was a spaceflight conducted from July 16 to 24, 1969, by the United States and launched by NASA. It marked the first time that humans Moon landing, landed on the Moon. Commander Neil Armstrong and Lunar Module pilot Buzz Aldrin l ...
mission. It was then found in Lunar and
Martian meteorite A Martian meteorite is a rock that formed on Mars, was ejected from the planet by an impact event, and traversed interplanetary space before landing on Earth as a meteorite. , 277 meteorites had been classified as Martian, less than half a perce ...
s as well as a mineral in the Earth's crust. Pyroxferroite can also be produced by annealing synthetic clinopyroxene at high pressures and temperatures. The mineral is metastable and gradually decomposes at ambient conditions, but this process can take billions of years.


Etymology

Pyroxferroite is named from ''pyroxene'' and ''ferrum'' (Latin for iron), as the iron-rich analogue of pyroxmangite. The word pyroxene, in turn comes from the Greek words for ''fire'' (πυρ) and ''stranger'' (ξένος). Pyroxenes were named this way because of their presence in volcanic lavas, where they are sometimes seen as crystals embedded in volcanic
glass Glass is an amorphous (non-crystalline solid, non-crystalline) solid. Because it is often transparency and translucency, transparent and chemically inert, glass has found widespread practical, technological, and decorative use in window pane ...
; it was assumed they were impurities in the glass, hence the name "fire strangers". However, they are simply early-forming minerals that crystallized before the lava erupted.


Occurrence

Pyroxferroite was first discovered in 1969 in
lunar rock Moon rock or lunar rock is rock originating from Earth's Moon. This includes lunar material collected during the course of human exploration of the Moon, and rock that has been ejected naturally from the Moon's surface and landed on Earth a ...
samples from
Tranquility Base Tranquility Base () is the site on the Moon where, in July 1969, humans landed and walked on a celestial body other than Earth for the first time. On July 20, 1969, Apollo 11 crewmembers Neil Armstrong and Buzz Aldrin landed their Apollo Lunar Mo ...
, the
Sea of Tranquility Mare Tranquillitatis (Latin for Sea of Tranquillity or Sea of Tranquility) is a lunar mare that sits within the Tranquillitatis basin on the Moon. It contains Tranquility Base, the first location on another celestial body to be visited by hu ...
landing site of
Apollo Apollo is one of the Twelve Olympians, Olympian deities in Ancient Greek religion, ancient Greek and Ancient Roman religion, Roman religion and Greek mythology, Greek and Roman mythology. Apollo has been recognized as a god of archery, mu ...
11. Together with armalcolite and tranquillityite, it is one of the three minerals which were first found on the Moon. Later, pyroxferroite was detected in Lunar and
Martian meteorite A Martian meteorite is a rock that formed on Mars, was ejected from the planet by an impact event, and traversed interplanetary space before landing on Earth as a meteorite. , 277 meteorites had been classified as Martian, less than half a perce ...
s recovered in
Oman Oman, officially the Sultanate of Oman, is a country located on the southeastern coast of the Arabian Peninsula in West Asia and the Middle East. It shares land borders with Saudi Arabia, the United Arab Emirates, and Yemen. Oman’s coastline ...
. It also occurs in the Earth's crust, in association with
clinopyroxene The pyroxenes (commonly abbreviated Px) are a group of important rock-forming inosilicate minerals found in many igneous and metamorphic rocks. Pyroxenes have the general formula , where X represents ions of calcium (Ca), sodium (Na), iron (Fe ...
,
plagioclase Plagioclase ( ) is a series of Silicate minerals#Tectosilicates, tectosilicate (framework silicate) minerals within the feldspar group. Rather than referring to a particular mineral with a specific chemical composition, plagioclase is a continu ...
,
ilmenite Ilmenite is a titanium-iron oxide mineral with the idealized formula . It is a weakly magnetic black or steel-gray solid. Ilmenite is the most important ore of titanium and the main source of titanium dioxide, which is used in paints, printi ...
,
cristobalite Cristobalite ( ) is a mineral polymorph of silica that is formed at very high temperatures. It has the same chemical formula as quartz, Si O2, but a distinct crystal structure. Both quartz and cristobalite are polymorphs with all the members o ...
,
tridymite Tridymite is a high-temperature polymorphism (materials science), polymorph of silica and usually occurs as minute tabular white or colorless pseudo-hexagonal crystals, or scales, in cavities in felsic volcanic rocks. Its chemical formula is sili ...
,
fayalite Fayalite (, commonly abbreviated to Fa) is the iron-rich endmember, end-member of the olivine solid solution, solid-solution series. In common with all minerals in the olivine, olivine group, fayalite crystallizes in the orthorhombic system (spac ...
,
fluorapatite Fluorapatite, often with the alternate spelling of fluoroapatite, is a phosphate mineral with the formula Ca5(PO4)3F (calcium fluorophosphate). Fluorapatite is a hard crystalline solid. Although samples can have various color (green, brown, blu ...
and potassic
feldspar Feldspar ( ; sometimes spelled felspar) is a group of rock-forming aluminium tectosilicate minerals, also containing other cations such as sodium, calcium, potassium, or barium. The most common members of the feldspar group are the ''plagiocl ...
, and forms series with pyroxmangite. Pyroxferroite has been found in the Isanago mine, in
Kyoto Prefecture is a Prefectures of Japan, prefecture of Japan located in the Kansai region of Honshu. Kyoto Prefecture has a population of 2,561,358 () and has a geographic area of . Kyoto Prefecture borders Fukui Prefecture to the northeast, Shiga Prefecture ...
,
Japan Japan is an island country in East Asia. Located in the Pacific Ocean off the northeast coast of the Asia, Asian mainland, it is bordered on the west by the Sea of Japan and extends from the Sea of Okhotsk in the north to the East China Sea ...
; near Iva,
Anderson County, South Carolina Anderson County is a county located in the U.S. state of South Carolina. As of the 2020 census, its population was 203,718. Its county seat is Anderson. Named for Revolutionary War leader Robert Anderson, the county is located in northwest ...
, US; from Väster Silfberg,
Värmland Värmland () is a ''Provinces of Sweden, landskap'' (historical province) in west-central Sweden. It borders Västergötland, Dalsland, Dalarna, Västmanland, and Närke, and is bounded by Norway in the west. Name Several Latinized version ...
,
Sweden Sweden, formally the Kingdom of Sweden, is a Nordic countries, Nordic country located on the Scandinavian Peninsula in Northern Europe. It borders Norway to the west and north, and Finland to the east. At , Sweden is the largest Nordic count ...
; and
Lapua Lapua (; ) is a List of cities and towns in Finland, town and municipalities of Finland, municipality in Finland's South Ostrobothnia regions of Finland, region. It is located next to the Lapua River. The town has a population of () and cov ...
,
Finland Finland, officially the Republic of Finland, is a Nordic country in Northern Europe. It borders Sweden to the northwest, Norway to the north, and Russia to the east, with the Gulf of Bothnia to the west and the Gulf of Finland to the south, ...
. In the original lunar samples, pyroxferroite was associated with similar minerals, but also with
troilite Troilite () is a rare iron sulfide mineral with the simple formula of FeS. It is the iron-rich endmember of the pyrrhotite group. Pyrrhotite has the formula Fe(1−x)S (x = 0 to 0.2) which is iron deficient. As troilite lacks the iron deficiency ...
which is rare on Earth, but is common on the Moon and Mars.


Synthesis

Synthetic pyroxferroite crystals can be produced by compressing synthetic clinopyroxene (composition Ca0.15Fe0.85SiO3) to a pressure in the range of 10–17.5 kbar and heating it to 1130–1250 °C. It is metastable at low temperatures and pressures: at pressures below 10 kbar pyroxferroite converts to a mixture of
olivine The mineral olivine () is a magnesium iron Silicate minerals, silicate with the chemical formula . It is a type of Nesosilicates, nesosilicate or orthosilicate. The primary component of the Earth's upper mantle (Earth), upper mantle, it is a com ...
,
pyroxene The pyroxenes (commonly abbreviated Px) are a group of important rock-forming inosilicate minerals found in many igneous and metamorphic rocks. Pyroxenes have the general formula , where X represents ions of calcium (Ca), sodium (Na), iron ( ...
and a
silicon dioxide Silicon dioxide, also known as silica, is an oxide of silicon with the chemical formula , commonly found in nature as quartz. In many parts of the world, silica is the major constituent of sand. Silica is one of the most complex and abundan ...
phase, whereas at low temperatures, it transforms to a clinopyroxene. The presence of cristobalite,
vesicular texture Vesicular texture is a volcanic rock texture characterized by a rock being pitted with many cavities (known as vesicles) at its surface and inside. This texture is common in aphanitic, or glassy, igneous rocks that have come to the surface ...
and some other petrographic observations indicate that the lunar pyroxferroite was produced upon rapid cooling from low-pressure and high-temperature (volcanic) conditions, i.e. that the mineral is metastable. However, the conversion rate is very slow and pyroxferroite can exist at low temperatures for periods longer than 3 billion years.


Properties

The crystal structure of pyroxferroite contains silicon-oxygen chains with a repeat period of seven SiO4 tetrahedra. These chains are separated by polyhedra where a central metal atom is surrounded by 6 or 7 oxygen atoms; there are 7 inequivalent metal polyhedra in the unit cell. The resulted layers are parallel to (110) planes in pyroxferroite, whereas they are parallel to (100) planes in pyroxenes. Chemical composition of pyroxferroite can be decomposed into elementary oxides as follows: FeO (concentration 44–48%), SiO2(45–47%), CaO (4.7–6.1%), MnO (0.6–1.3%), MgO (0.3-1%), TiO2 (0.2–0.5%) and Al2O3 (0.2–1.2%). Whereas magnesium is usually present at about 0.8%, in some samples it had an undetectably low concentration.


References

{{Manganese minerals Inosilicates Iron(II) minerals Manganese(II) minerals Calcium minerals Pyroxene group Triclinic minerals Minerals in space group 2 Apollo 11 Minerals described in 1970