Pyraclostrobin is a quinone outside inhibitor (
QI)-type
fungicide
Fungicides are pesticides used to kill parasitic fungi or their spores. Fungi can cause serious damage in agriculture, resulting in losses of yield and quality. Fungicides are used both in agriculture and to fight fungal infections in animals, ...
used in
agriculture
Agriculture encompasses crop and livestock production, aquaculture, and forestry for food and non-food products. Agriculture was a key factor in the rise of sedentary human civilization, whereby farming of domesticated species created ...
.
Among the QIs, it lies within the
strobilurin chemical class.
Use
Pyraclostrobin is used to protect ''
Fragaria
''Fragaria'' () is a genus of flowering plants in the rose family, Rosaceae, commonly known as strawberries for their edible fruits. There are more than 20 described species and many Hybrid plant, hybrids and cultivars. The most common strawberr ...
'',
''
Rubus idaeus
''Rubus idaeus'' (raspberry, also called red raspberry or occasionally European red raspberry to distinguish it from other raspberry species) is a red-fruited species of ''Rubus'' native to Europe and northern Asia and commonly cultivated in oth ...
'',
''
Vaccinium corymbosum
''Vaccinium corymbosum'', the northern highbush blueberry, is a North American species of blueberry. Other common names include blue huckleberry, tall huckleberry, swamp huckleberry, high blueberry, and swamp blueberry.
Description
''Vaccinium ...
'',
''
Ribes rubrum
The redcurrant or red currant (''Ribes rubrum'') is a member of the genus ''Ribes'' in the gooseberry family. It is native to western Europe. The species is widely cultivated and has escaped into the wild in many regions.
Description
''Ribes ...
'',
''
Ribes uva-crispa'',
blackberry
BlackBerry is a discontinued brand of handheld devices and related mobile services, originally developed and maintained by the Canadian company Research In Motion (RIM, later known as BlackBerry Limited) until 2016. The first BlackBerry device ...
(various ''
Rubus
''Rubus'' is a large and diverse genus of flowering plants in the rose family, Rosaceae, subfamily Rosoideae, most commonly known as brambles. Fruits of various species are known as raspberries, blackberries, dewberries, and bristleberries. ...
'' spp.),
and ''
Pistachio vera''.
Target pathogens
Pyraclostrobin is used against ''
Botrytis cinerea
''Botrytis cinerea'' is a necrotrophic fungus that affects many plant species, although its most notable hosts may be wine grapes. In viticulture, it is commonly known as "botrytis bunch rot"; in horticulture, it is usually called "grey mould" ...
''
and ''
Alternaria alternata
''Alternaria alternata'' is a fungus causing leaf spots, rots, and blights on many plant parts, and other diseases. It is an opportunistic pathogen on over 380 host species of plant.
It can also cause upper respiratory tract infections and a ...
''.
Resistance
Resistant populations have been identified in:
*''
Botrytis cinerea
''Botrytis cinerea'' is a necrotrophic fungus that affects many plant species, although its most notable hosts may be wine grapes. In viticulture, it is commonly known as "botrytis bunch rot"; in horticulture, it is usually called "grey mould" ...
'' on ''
Fragaria
''Fragaria'' () is a genus of flowering plants in the rose family, Rosaceae, commonly known as strawberries for their edible fruits. There are more than 20 described species and many Hybrid plant, hybrids and cultivars. The most common strawberr ...
'' in the
Carolinas
The Carolinas, also known simply as Carolina, are the U.S. states of North Carolina and South Carolina considered collectively. They are bordered by Virginia to the north, Tennessee to the west, and Georgia (U.S. state), Georgia to the southwes ...
, conferred by the G143A mutation in the partial
cytochrome b
Cytochrome b is a protein found in the membranes of aerobic cells. In eukaryotic mitochondria (inner membrane) and in aerobic prokaryotes, cytochrome b is a component of respiratory chain complex III () — also known as the bc1 complex or ubiq ...
(CYTB) gene.
*''
Botrytis cinerea
''Botrytis cinerea'' is a necrotrophic fungus that affects many plant species, although its most notable hosts may be wine grapes. In viticulture, it is commonly known as "botrytis bunch rot"; in horticulture, it is usually called "grey mould" ...
'' on ''Fragaria'', ''
Rubus idaeus
''Rubus idaeus'' (raspberry, also called red raspberry or occasionally European red raspberry to distinguish it from other raspberry species) is a red-fruited species of ''Rubus'' native to Europe and northern Asia and commonly cultivated in oth ...
'', ''
Vaccinium corymbosum
''Vaccinium corymbosum'', the northern highbush blueberry, is a North American species of blueberry. Other common names include blue huckleberry, tall huckleberry, swamp huckleberry, high blueberry, and swamp blueberry.
Description
''Vaccinium ...
'', ''
Ribes rubrum
The redcurrant or red currant (''Ribes rubrum'') is a member of the genus ''Ribes'' in the gooseberry family. It is native to western Europe. The species is widely cultivated and has escaped into the wild in many regions.
Description
''Ribes ...
'', ''
Ribes uva-crispa'', and
blackberry
BlackBerry is a discontinued brand of handheld devices and related mobile services, originally developed and maintained by the Canadian company Research In Motion (RIM, later known as BlackBerry Limited) until 2016. The first BlackBerry device ...
(various ''
Rubus
''Rubus'' is a large and diverse genus of flowering plants in the rose family, Rosaceae, subfamily Rosoideae, most commonly known as brambles. Fruits of various species are known as raspberries, blackberries, dewberries, and bristleberries. ...
'' spp.) in
Northern Germany
Northern Germany (, ) is a linguistic, geographic, socio-cultural and historic region in the northern part of Germany which includes the coastal states of Schleswig-Holstein, Mecklenburg-Vorpommern and Lower Saxony and the two city-states Hambur ...
.
*''
Botrytis cinerea
''Botrytis cinerea'' is a necrotrophic fungus that affects many plant species, although its most notable hosts may be wine grapes. In viticulture, it is commonly known as "botrytis bunch rot"; in horticulture, it is usually called "grey mould" ...
'' on ''Fragaria'' in
Florida
Florida ( ; ) is a U.S. state, state in the Southeastern United States, Southeastern region of the United States. It borders the Gulf of Mexico to the west, Alabama to the northwest, Georgia (U.S. state), Georgia to the north, the Atlantic ...
.
*''
Alternaria alternata
''Alternaria alternata'' is a fungus causing leaf spots, rots, and blights on many plant parts, and other diseases. It is an opportunistic pathogen on over 380 host species of plant.
It can also cause upper respiratory tract infections and a ...
'' on ''
Pistachio vera'' in
California
California () is a U.S. state, state in the Western United States that lies on the West Coast of the United States, Pacific Coast. It borders Oregon to the north, Nevada and Arizona to the east, and shares Mexico–United States border, an ...
.
Geography of use
United States
Pyraclostrobin was widely used throughout the
United States
The United States of America (USA), also known as the United States (U.S.) or America, is a country primarily located in North America. It is a federal republic of 50 U.S. state, states and a federal capital district, Washington, D.C. The 48 ...
, but especially in the
Upper Midwest
The Upper Midwest is a northern subregion of the U.S. Census Bureau's Midwestern United States. Although the exact boundaries are not uniformly agreed upon, the region is usually defined to include the states of Iowa, Michigan, Minnesota and Wi ...
.
Off-target toxicity
Although toxic, and recommended to be avoided by humans, pyraclostrobin is of temporary and low toxicity, that is to say it is merely an irritant
of eyes and skin.
It does cause some degree of reproductive and developmental failure in mammals
but does not absorb well through the skin.
It is likely to
bioaccumulate
Bioaccumulation is the gradual accumulation of substances, such as pesticides or other chemicals, in an organism. Bioaccumulation occurs when an organism absorbs a substance faster than it can be lost or eliminated by catabolism and excretion. Th ...
in
aquatic organisms.
Residues in diet
Pyraclostrobin does not accumulate in foods to a significant degree.
Biodegradability
Pyraclostrobin is described by one source as not very
biodegradable
Biodegradation is the breakdown of organic matter by microorganisms, such as bacteria and fungi. It is generally assumed to be a natural process, which differentiates it from composting. Composting is a human-driven process in which biodegrada ...
,
and by another as possibly significantly biodegradable.
References
Further reading
*
*{{cite web , title=Pyraclostrobine , website=NIST WebBook , publisher=
National Institute of Standards and Technology
The National Institute of Standards and Technology (NIST) is an agency of the United States Department of Commerce whose mission is to promote American innovation and industrial competitiveness. NIST's activities are organized into Outline of p ...
, url=http://webbook.nist.gov/cgi/inchi/InChI%3D1S/C19H18ClN3O4/c1-25-19(24)23(26-2)17-6-4-3-5-14(17)13-27-18-11-12-22(21-18)16-9-7-15(20)8-10-16/h3-12H%2C13H2%2C1-2H3 , access-date=2021-03-02
Fungicides
Carbamates
Pyrazoles
Anilines
4-Chlorophenyl compounds
Strobilurins
Methoxy compounds