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The Planck relationFrench & Taylor (1978), pp. 24, 55.Cohen-Tannoudji, Diu & Laloë (1973/1977), pp. 10–11. (referred to as Planck's energy–frequency relation,Schwinger (2001), p. 203. the Planck–Einstein relation, Planck equation, and Planck formula, though the latter might also refer to
Planck's law In physics, Planck's law (also Planck radiation law) describes the spectral density of electromagnetic radiation emitted by a black body in thermal equilibrium at a given temperature , when there is no net flow of matter or energy between the ...
) is a fundamental equation in
quantum mechanics Quantum mechanics is the fundamental physical Scientific theory, theory that describes the behavior of matter and of light; its unusual characteristics typically occur at and below the scale of atoms. Reprinted, Addison-Wesley, 1989, It is ...
which states that the
energy Energy () is the physical quantity, quantitative physical property, property that is transferred to a physical body, body or to a physical system, recognizable in the performance of Work (thermodynamics), work and in the form of heat and l ...
of a
photon A photon () is an elementary particle that is a quantum of the electromagnetic field, including electromagnetic radiation such as light and radio waves, and the force carrier for the electromagnetic force. Photons are massless particles that can ...
, known as
photon energy Photon energy is the energy carried by a single photon. The amount of energy is directly proportional to the photon's electromagnetic frequency and thus, equivalently, is inversely proportional to the wavelength. The higher the photon's frequenc ...
, is proportional to its
frequency Frequency is the number of occurrences of a repeating event per unit of time. Frequency is an important parameter used in science and engineering to specify the rate of oscillatory and vibratory phenomena, such as mechanical vibrations, audio ...
: E = h \nu. The constant of proportionality, , is known as the
Planck constant The Planck constant, or Planck's constant, denoted by h, is a fundamental physical constant of foundational importance in quantum mechanics: a photon's energy is equal to its frequency multiplied by the Planck constant, and the wavelength of a ...
. Several equivalent forms of the relation exist, including in terms of
angular frequency In physics, angular frequency (symbol ''ω''), also called angular speed and angular rate, is a scalar measure of the angle rate (the angle per unit time) or the temporal rate of change of the phase argument of a sinusoidal waveform or sine ...
: E = \hbar \omega, where \hbar = h / 2 \pi. Written using the symbol for frequency, the relation is E = h f. The relation accounts for the quantized nature of light and plays a key role in understanding phenomena such as the
photoelectric effect The photoelectric effect is the emission of electrons from a material caused by electromagnetic radiation such as ultraviolet light. Electrons emitted in this manner are called photoelectrons. The phenomenon is studied in condensed matter physi ...
and
black-body radiation Black-body radiation is the thermal radiation, thermal electromagnetic radiation within, or surrounding, a body in thermodynamic equilibrium with its environment, emitted by a black body (an idealized opaque, non-reflective body). It has a specific ...
(where the related Planck postulate can be used to derive
Planck's law In physics, Planck's law (also Planck radiation law) describes the spectral density of electromagnetic radiation emitted by a black body in thermal equilibrium at a given temperature , when there is no net flow of matter or energy between the ...
).


Spectral forms

Light can be characterized using several spectral quantities, such as
frequency Frequency is the number of occurrences of a repeating event per unit of time. Frequency is an important parameter used in science and engineering to specify the rate of oscillatory and vibratory phenomena, such as mechanical vibrations, audio ...
,
wavelength In physics and mathematics, wavelength or spatial period of a wave or periodic function is the distance over which the wave's shape repeats. In other words, it is the distance between consecutive corresponding points of the same ''phase (waves ...
,
wavenumber In the physical sciences, the wavenumber (or wave number), also known as repetency, is the spatial frequency of a wave. Ordinary wavenumber is defined as the number of wave cycles divided by length; it is a physical quantity with dimension of ...
\tilde, and their angular equivalents (
angular frequency In physics, angular frequency (symbol ''ω''), also called angular speed and angular rate, is a scalar measure of the angle rate (the angle per unit time) or the temporal rate of change of the phase argument of a sinusoidal waveform or sine ...
,
angular wavelength In physics and mathematics, wavelength or spatial period of a wave or periodic function is the distance over which the wave's shape repeats. In other words, it is the distance between consecutive corresponding points of the same '' phase'' on ...
, and
angular wavenumber In the physical sciences, the wavenumber (or wave number), also known as repetency, is the spatial frequency of a wave. Ordinary wavenumber is defined as the number of wave cycles divided by length; it is a physical quantity with dimension of r ...
). These quantities are related through \nu = \frac = c \tilde \nu = \frac = \frac = \frac, so the Planck relation can take the following "standard" forms: E = h \nu = \frac = h c \tilde \nu, as well as the following "angular" forms: E = \hbar \omega = \frac = \hbar c k. The standard forms make use of the
Planck constant The Planck constant, or Planck's constant, denoted by h, is a fundamental physical constant of foundational importance in quantum mechanics: a photon's energy is equal to its frequency multiplied by the Planck constant, and the wavelength of a ...
. The angular forms make use of the
reduced Planck constant The Planck constant, or Planck's constant, denoted by h, is a fundamental physical constant of foundational importance in quantum mechanics: a photon's energy is equal to its frequency multiplied by the Planck constant, and the wavelength of a ...
. Here is the
speed of light The speed of light in vacuum, commonly denoted , is a universal physical constant exactly equal to ). It is exact because, by international agreement, a metre is defined as the length of the path travelled by light in vacuum during a time i ...
.


de Broglie relation

The de Broglie relation,Weinberg (1995), p. 3. also known as de Broglie's momentum–wavelength relation, generalizes the Planck relation to
matter wave Matter waves are a central part of the theory of quantum mechanics, being half of wave–particle duality. At all scales where measurements have been practical, matter exhibits wave-like behavior. For example, a beam of electrons can be diffract ...
s.
Louis de Broglie Louis Victor Pierre Raymond, 7th Duc de Broglie (15 August 1892 – 19 March 1987) was a French theoretical physicist and aristocrat known for his contributions to quantum theory. In his 1924 PhD thesis, he postulated the wave nature of elec ...
argued that if particles had a wave nature, the relation would also apply to them, and postulated that particles would have a wavelength equal to . Combining de Broglie's postulate with the Planck–Einstein relation leads to p = h \tilde \nu or p = \hbar k. The de Broglie relation is also often encountered in
vector Vector most often refers to: * Euclidean vector, a quantity with a magnitude and a direction * Disease vector, an agent that carries and transmits an infectious pathogen into another living organism Vector may also refer to: Mathematics a ...
form \mathbf = \hbar \mathbf, where is the momentum vector, and is the
angular wave vector In physics, a wave vector (or wavevector) is a vector used in describing a wave, with a typical unit being cycle per metre. It has a magnitude and direction. Its magnitude is the wavenumber of the wave (inversely proportional to the wavelength), ...
.


Bohr's frequency condition

Bohr's frequency condition states that the frequency of a photon absorbed or emitted during an
electronic transition In atomic physics and chemistry, an atomic electron transition (also called an atomic transition, quantum jump, or quantum leap) is an electron changing from one energy level to another within an atom or artificial atom. The time scale of a qua ...
is related to the energy difference () between the two
energy level A quantum mechanics, quantum mechanical system or particle that is bound state, bound—that is, confined spatially—can only take on certain discrete values of energy, called energy levels. This contrasts with classical mechanics, classical pa ...
s involved in the transition:van der Waerden (1967), p. 5. \Delta E = h \nu. This is a direct consequence of the Planck–Einstein relation.


See also

*
Compton wavelength The Compton wavelength is a quantum mechanical property of a particle, defined as the wavelength of a photon whose energy is the same as the rest energy of that particle (see mass–energy equivalence). It was introduced by Arthur Compton in 1 ...


References


Cited bibliography

* Cohen-Tannoudji, C., Diu, B., Laloë, F. (1973/1977). ''Quantum Mechanics'', translated from the French by S.R. Hemley, N. Ostrowsky, D. Ostrowsky, second edition, volume 1, Wiley, New York, . * French, A.P., Taylor, E.F. (1978). ''An Introduction to Quantum Physics'', Van Nostrand Reinhold, London, . *Griffiths, D.J. (1995). ''Introduction to Quantum Mechanics'', Prentice Hall, Upper Saddle River NJ, . * Landé, A. (1951). ''Quantum Mechanics'', Sir Isaac Pitman & Sons, London. *Landsberg, P.T. (1978). ''Thermodynamics and Statistical Mechanics'', Oxford University Press, Oxford UK, . * Messiah, A. (1958/1961)
''Quantum Mechanics''
volume 1, translated from the French by G.M. Temmer, North-Holland, Amsterdam. * Schwinger, J. (2001). ''Quantum Mechanics: Symbolism of Atomic Measurements'', edited by B.-G. Englert, Springer, Berlin, . * van der Waerden, B.L. (1967). ''Sources of Quantum Mechanics'', edited with a historical introduction by B.L. van der Waerden, North-Holland Publishing, Amsterdam. * Weinberg, S. (1995). ''The Quantum Theory of Fields'', volume 1, ''Foundations'', Cambridge University Press, Cambridge UK, . * Weinberg, S. (2013). ''Lectures on Quantum Mechanics'', Cambridge University Press, Cambridge UK, . {{DEFAULTSORT:Planck-Einstein relation Foundational quantum physics Max Planck Old quantum theory