Neopentyl Alcohol
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Neopentyl alcohol is a
compound Compound may refer to: Architecture and built environments * Compound (enclosure), a cluster of buildings having a shared purpose, usually inside a fence or wall ** Compound (fortification), a version of the above fortified with defensive struct ...
with formula (CH3)3CCH2OH. It is a colorless solid. The compound is one of the eight isomers of
pentyl alcohol An amyl alcohol is any of eight alcohols with the formula C5H12O. A mixture of amyl alcohols (also called amyl alcohol) can be obtained from fusel alcohol. Amyl alcohol is used as a solvent and in esterification, by which is produced amyl acetate ...
.


Preparation and reactions

Neopentyl alcohol can be prepared from the hydroperoxide of diisobutylene. It can also be prepared by the reduction of trimethylacetic acid with
lithium aluminum hydride Lithium aluminium hydride, commonly abbreviated to LAH, is an inorganic compound with the chemical formula Li Al H4. It is a white solid, discovered by Finholt, Bond and Schlesinger in 1947. This compound is used as a reducing agent in organic sy ...
. Neopentyl alcohol was the first described in 1891 by L. Tissier, who prepared it by reduction of a mixture of trimethyl acetic acid and trimethylacetyl chloride with sodium amalgam. Neopentyl alcohol can be converted to neopentyl iodide by treatment with
triphenylphosphite Triphenyl phosphite is the organophosphorus compound with the formula P(OC6H5)3. It is a colourless viscous liquid. Preparation Triphenylphosphite is prepared from phosphorus trichloride and phenol in the presence of a catalytic amount of base: ...
/
methyl iodide Iodomethane, also called methyl iodide, and commonly abbreviated "MeI", is the chemical compound with the formula CH3I. It is a dense, colorless, volatile liquid. In terms of chemical structure, it is related to methane by replacement of one h ...
: :(CH3)3CCH2OH + H3(C6H5O)3Psup>+I → (CH3)3CCH2I + H3(C6H5O)2PO + C6H5OH


See also

* Pentaerythritol
* Neopentyl glycol * Trimethylolethane * Trimethylolpropane


References

Alcohol solvents Primary alcohols Alkanols Tert-butyl compounds {{alcohol-stub