Molybdenum(II) iodide is an
iodide
An iodide ion is I−. Compounds with iodine in formal oxidation state −1 are called iodides. In everyday life, iodide is most commonly encountered as a component of iodized salt, which many governments mandate. Worldwide, iodine deficiency ...
of
molybdenum
Molybdenum is a chemical element; it has Symbol (chemistry), symbol Mo (from Neo-Latin ''molybdaenum'') and atomic number 42. The name derived from Ancient Greek ', meaning lead, since its ores were confused with lead ores. Molybdenum minerals hav ...
with the
chemical formula
A chemical formula is a way of presenting information about the chemical proportions of atoms that constitute a particular chemical compound or molecule, using chemical element symbols, numbers, and sometimes also other symbols, such as pare ...
MoI
2.
Preparation
Molybdenum(II) iodide can be produced by the reaction of
molybdenum(II) bromide
Molybdenum(II) bromide is an inorganic compound
An inorganic compound is typically a chemical compound that lacks carbon–hydrogen bondsthat is, a compound that is not an organic compound. The study of inorganic compounds is a subfield of ch ...
and
lithium iodide
Lithium iodide, or LiI, is a compound of lithium and iodine. When exposed to air, it becomes yellow in color, due to the oxidation of iodide to iodine. It crystallizes in the NaCl motif. It can participate in various hydrates.Wietelmann, Ulrich a ...
:
Georg Brauer
Georg Karl Brauer (11 April 1908 in Bochum – 26 February 2001 in Freiburg im Breisgau
Freiburg im Breisgau or simply Freiburg is the List of cities in Baden-Württemberg by population, fourth-largest city of the German state of Baden-Wü ...
(Hrsg.) u. a.: ''Handbuch der Präparativen Anorganischen Chemie.'' 3., umgearbeitete Auflage. Band III, Ferdinand Enke, Stuttgart 1981, ISBN 3-432-87823-0, S. 1539.
:
It can also be produced by the decomposition of
molybdenum(III) iodide
Molybdenum(III) iodide is the inorganic compound with the formula MoI3.
Preparation
Molybdenum(III) iodide is created by the reaction of molybdenum hexacarbonyl with iodine gas at .
:2 Mo(CO)6 + 3 I2 → 2 MoI3 + 12 CO
It can also be made from ...
in a vacuum at 100 °C:
:
Properties
Molybdenum(II) iodide is a black solid that is stable in air. It is insoluble in polar and non-polar
solvent
A solvent (from the Latin language, Latin ''wikt:solvo#Latin, solvō'', "loosen, untie, solve") is a substance that dissolves a solute, resulting in a Solution (chemistry), solution. A solvent is usually a liquid but can also be a solid, a gas ...
s.
References
{{Iodides
Molybdenum(II) compounds
Iodides