Mercury's Atmosphere
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Mercury, being the closest to the
Sun The Sun is the star at the centre of the Solar System. It is a massive, nearly perfect sphere of hot plasma, heated to incandescence by nuclear fusion reactions in its core, radiating the energy from its surface mainly as visible light a ...
, with a weak magnetic field and the smallest mass of the recognized terrestrial planets, has a very tenuous and highly variable
atmosphere An atmosphere () is a layer of gases that envelop an astronomical object, held in place by the gravity of the object. A planet retains an atmosphere when the gravity is great and the temperature of the atmosphere is low. A stellar atmosph ...
(surface-bound
exosphere The exosphere is a thin, atmosphere-like volume surrounding a planet or natural satellite where molecules are gravitationally bound to that body, but where the density is so low that the molecules are essentially collision-less. In the case of ...
) containing
hydrogen Hydrogen is a chemical element; it has chemical symbol, symbol H and atomic number 1. It is the lightest and abundance of the chemical elements, most abundant chemical element in the universe, constituting about 75% of all baryon, normal matter ...
,
helium Helium (from ) is a chemical element; it has chemical symbol, symbol He and atomic number 2. It is a colorless, odorless, non-toxic, inert gas, inert, monatomic gas and the first in the noble gas group in the periodic table. Its boiling point is ...
,
oxygen Oxygen is a chemical element; it has chemical symbol, symbol O and atomic number 8. It is a member of the chalcogen group (periodic table), group in the periodic table, a highly reactivity (chemistry), reactive nonmetal (chemistry), non ...
,
sodium Sodium is a chemical element; it has Symbol (chemistry), symbol Na (from Neo-Latin ) and atomic number 11. It is a soft, silvery-white, highly reactive metal. Sodium is an alkali metal, being in group 1 element, group 1 of the peri ...
,
calcium Calcium is a chemical element; it has symbol Ca and atomic number 20. As an alkaline earth metal, calcium is a reactive metal that forms a dark oxide-nitride layer when exposed to air. Its physical and chemical properties are most similar to it ...
,
potassium Potassium is a chemical element; it has Symbol (chemistry), symbol K (from Neo-Latin ) and atomic number19. It is a silvery white metal that is soft enough to easily cut with a knife. Potassium metal reacts rapidly with atmospheric oxygen to ...
and
water vapor Water vapor, water vapour, or aqueous vapor is the gaseous phase of Properties of water, water. It is one Phase (matter), state of water within the hydrosphere. Water vapor can be produced from the evaporation or boiling of liquid water or from th ...
, with a combined pressure level of about 10−14
bar Bar or BAR may refer to: Food and drink * Bar (establishment), selling alcoholic beverages * Candy bar ** Chocolate bar * Protein bar Science and technology * Bar (river morphology), a deposit of sediment * Bar (tropical cyclone), a laye ...
(1 nPa). The exospheric species originate either from the
Solar wind The solar wind is a stream of charged particles released from the Sun's outermost atmospheric layer, the Stellar corona, corona. This Plasma (physics), plasma mostly consists of electrons, protons and alpha particles with kinetic energy betwee ...
or from the planetary crust. Solar light pushes the atmospheric gases away from the Sun, creating a comet-like tail behind the planet. The existence of a Mercurian atmosphere was contentious until 1974, although by that time a consensus had formed that Mercury, like the
Moon The Moon is Earth's only natural satellite. It Orbit of the Moon, orbits around Earth at Lunar distance, an average distance of (; about 30 times Earth diameter, Earth's diameter). The Moon rotation, rotates, with a rotation period (lunar ...
, lacked any substantial atmosphere. This conclusion was confirmed in 1974 when the unmanned ''
Mariner 10 ''Mariner 10'' was an American Robotic spacecraft, robotic space probe launched by NASA on 3 November 1973, to fly by the planets Mercury (planet), Mercury and Venus. It was the first spacecraft to perform flybys of multiple planets. ''Marin ...
'' spaceprobe discovered only a tenuous exosphere. Later, in 2008, improved measurements were obtained by the ''
MESSENGER Messenger, Messengers, The Messenger or The Messengers may refer to: People * Courier, a person or company that delivers messages, packages, or mail * Messenger (surname) * Bicycle messenger, a bicyclist who transports packages through cities * M ...
'' spacecraft, which discovered
magnesium Magnesium is a chemical element; it has Symbol (chemistry), symbol Mg and atomic number 12. It is a shiny gray metal having a low density, low melting point and high chemical reactivity. Like the other alkaline earth metals (group 2 ...
in the Mercurian exosphere.


Composition

The Mercurian exosphere consists of a variety of species originating either from the
Solar wind The solar wind is a stream of charged particles released from the Sun's outermost atmospheric layer, the Stellar corona, corona. This Plasma (physics), plasma mostly consists of electrons, protons and alpha particles with kinetic energy betwee ...
or from the planetary crust. Killen, 2007, pp. 433–434 The first constituents discovered were
atomic hydrogen A hydrogen atom is an atom of the chemical element hydrogen. The electrically neutral hydrogen atom contains a single positively charged proton in the nucleus, and a single negatively charged electron bound to the nucleus by the Coulomb for ...
(H),
helium Helium (from ) is a chemical element; it has chemical symbol, symbol He and atomic number 2. It is a colorless, odorless, non-toxic, inert gas, inert, monatomic gas and the first in the noble gas group in the periodic table. Its boiling point is ...
(He) and
atomic oxygen There are several known allotropes of oxygen. The most familiar is molecular oxygen (), present at significant levels in Earth's atmosphere and also known as dioxygen or triplet oxygen. Another is the highly reactive ozone (). Others are: * Atomic ...
(O), which were observed by the ultraviolet radiation
photometer A photometer is an instrument that measures the strength of electromagnetic radiation in the range from ultraviolet to infrared and including the visible spectrum. Most photometers convert light into an electric current using a photoresistor, ...
of the ''
Mariner 10 ''Mariner 10'' was an American Robotic spacecraft, robotic space probe launched by NASA on 3 November 1973, to fly by the planets Mercury (planet), Mercury and Venus. It was the first spacecraft to perform flybys of multiple planets. ''Marin ...
'' spaceprobe in 1974. The near-surface concentrations of these elements were estimated to vary from 230 cm−3 for hydrogen to 44,000 cm−3 for oxygen, with an intermediate concentration of helium. In 2008 the ''
MESSENGER Messenger, Messengers, The Messenger or The Messengers may refer to: People * Courier, a person or company that delivers messages, packages, or mail * Messenger (surname) * Bicycle messenger, a bicyclist who transports packages through cities * M ...
'' probe confirmed the presence of atomic hydrogen, although its concentration appeared higher than the 1974 estimate. McClintock 2008, p. 93 Mercury's exospheric hydrogen and helium are believed to come from the Solar wind, while the oxygen is likely to be of crustal origin. The fourth species detected in Mercury's exosphere was
sodium Sodium is a chemical element; it has Symbol (chemistry), symbol Na (from Neo-Latin ) and atomic number 11. It is a soft, silvery-white, highly reactive metal. Sodium is an alkali metal, being in group 1 element, group 1 of the peri ...
(Na). It was discovered in 1985 by Drew Potter and Tom Morgan, who observed its Fraunhofer emission lines at 589 and 589.6 nm. Killen, 2007, pp. 434–436 The average
column density The area density (also known as areal density, surface density, superficial density, areic density, column density, or density thickness) of a two-dimensional object is calculated as the mass per unit area. The SI derived unit is the "kilogram p ...
of this element is about 1 cm−2. Sodium is observed to concentrate near the poles, forming bright spots. Killen, 2007, pp. 438–442 Its abundance is also enhanced near the dawn terminator as compared to the dusk terminator. Killen, 2007, pp. 442–444 Some research has claimed a correlation of the sodium abundance with certain surface features such as Caloris or radio bright spots; however these results remain controversial. A year after the sodium discovery, Potter and Morgan reported that
potassium Potassium is a chemical element; it has Symbol (chemistry), symbol K (from Neo-Latin ) and atomic number19. It is a silvery white metal that is soft enough to easily cut with a knife. Potassium metal reacts rapidly with atmospheric oxygen to ...
(K) is also present in the exosphere of Mercury, though with a column density two orders of magnitude lower than that of sodium. The properties and spatial distribution of these two elements are otherwise very similar. Killen, 2007, pp. 449–452 In 1998 another element,
calcium Calcium is a chemical element; it has symbol Ca and atomic number 20. As an alkaline earth metal, calcium is a reactive metal that forms a dark oxide-nitride layer when exposed to air. Its physical and chemical properties are most similar to it ...
(Ca), was detected with column density three orders of magnitude below that of sodium. Killen, 2007, pp. 452–453 Observations by the ''MESSENGER'' probe in 2009 showed that calcium is concentrated mainly near the equator—opposite to what is observed for sodium and potassium. McClintock 2009, p. 612–613 Further observations by Messenger reported in 2014 note the atmosphere is supplemented by materials vaporized off the surface by meteors both sporadic and in a
meteor shower A meteor shower is a celestial event in which a number of meteors are observed to radiate, or originate, from one point in the night sky. These meteors are caused by streams of cosmic debris called meteoroids entering Earth's atmosphere at ext ...
associated with
Comet Encke Comet Encke , or Encke's Comet (official designation: 2P/Encke), is a periodic comet that completes an orbit of the Sun once every 3.3 years. (This is the shortest period of a reasonably bright comet; the faint main-belt comet 311P/PanSTARRS has ...
. In 2008 the ''
MESSENGER Messenger, Messengers, The Messenger or The Messengers may refer to: People * Courier, a person or company that delivers messages, packages, or mail * Messenger (surname) * Bicycle messenger, a bicyclist who transports packages through cities * M ...
'' probe's Fast Imaging Plasma Spectrometer (FIPS) discovered several molecular and different ions in the vicinity of Mercury, including H2O+ (ionized
water vapor Water vapor, water vapour, or aqueous vapor is the gaseous phase of Properties of water, water. It is one Phase (matter), state of water within the hydrosphere. Water vapor can be produced from the evaporation or boiling of liquid water or from th ...
) and H2S+ (ionized
hydrogen sulfide Hydrogen sulfide is a chemical compound with the formula . It is a colorless chalcogen-hydride gas, and is toxic, corrosive, and flammable. Trace amounts in ambient atmosphere have a characteristic foul odor of rotten eggs. Swedish chemist ...
). Their abundances relative to sodium are about 0.2 and 0.7, respectively. Other ions such as H3O+ (
hydronium In chemistry, hydronium (hydroxonium in traditional British English) is the cation , also written as , the type of oxonium ion produced by protonation of water. It is often viewed as the positive ion present when an Arrhenius acid is dissolved ...
), OH (
hydroxyl In chemistry, a hydroxy or hydroxyl group is a functional group with the chemical formula and composed of one oxygen atom covalently bonded to one hydrogen atom. In organic chemistry, alcohols and carboxylic acids contain one or more hydroxy ...
), O2+ and Si+ are present as well. Zurbuchen 2008, p. 91, Table 1 During its 2009 flyby, the Ultraviolet and Visible Spectrometer (UVVS) channel of the Mercury Atmospheric and Surface Composition Spectrometer (MASCS) on board the ''MESSENGER'' spacecraft first revealed the presence of
magnesium Magnesium is a chemical element; it has Symbol (chemistry), symbol Mg and atomic number 12. It is a shiny gray metal having a low density, low melting point and high chemical reactivity. Like the other alkaline earth metals (group 2 ...
in the Mercurian exosphere. The near-surface abundance of this newly detected constituent is roughly comparable to that of sodium.


Properties

''Mariner 10''
ultraviolet Ultraviolet radiation, also known as simply UV, is electromagnetic radiation of wavelengths of 10–400 nanometers, shorter than that of visible light, but longer than X-rays. UV radiation is present in sunlight and constitutes about 10% of ...
observations have established an upper bound on the exospheric surface density at about 105 particles per cubic centimeter. This corresponds to a surface pressure of less than 10−12 
bar Bar or BAR may refer to: Food and drink * Bar (establishment), selling alcoholic beverages * Candy bar ** Chocolate bar * Protein bar Science and technology * Bar (river morphology), a deposit of sediment * Bar (tropical cyclone), a laye ...
(1  nPa). Domingue, 2007, pp. 162–163 The temperature of Mercury's exosphere depends on species as well as geographical location. For exospheric atomic hydrogen, the temperature appears to be about 420 K, a value obtained by both ''Mariner 10'' and ''MESSENGER''. The temperature for sodium is much higher, reaching 750–1,500 K on the equator and 1,500–3,500 K at the poles. Killen, 2007, pp. 436–438 Some observations show that Mercury is surrounded by a hot corona of calcium atoms with temperature between 12,000 and 20,000 K. In the early 2000s, a simulation of Mercury's Na exosphere and its temporal variation was conducted to identify the source process that supplied crustal species to the exosphere. Processes like; evaporation, diffusion from the interior, sputtering by photons and energetic ions, chemical sputtering by photons, and meteoritic vaporization were tested. However, evaporation provides the strongest match when comparing the changes in the sodium exosphere with solar distance and time of day to the 2001 observations of Mercury's sodium tail.


Tails

Because of Mercury's proximity to the Sun, the pressure of solar light is much stronger than near Earth. Solar radiation pushes neutral atoms away from Mercury, creating a comet-like tail behind it. McClintock 2009, p. 610–611 The main component in the tail is sodium, which has been detected beyond 24 million km (1000 RM) from the planet.
Schmidt Schmidt may refer to: * Schmidt (surname), including list of people and fictional characters with the surname * Schmidt (singer) (born 1990), German pop and jazz singer * Schmidt (lunar crater), a small lunar impact crater * Schmidt (Martian c ...
2010, p. 9–16
This sodium tail expands rapidly to a diameter of about 20,000 km at a distance of 17,500 km. Killen, 2007, p. 448 In 2009, ''MESSENGER'' also detected calcium and magnesium in the tail, although these elements were only observed at distances less than 8 RM.


Observation difficulties

Mercury is the least explored planet of the
inner Solar System The Solar SystemCapitalization of the name varies. The International Astronomical Union, the authoritative body regarding astronomical nomenclature, specifies capitalizing the names of all individual astronomical objects but uses mixed "Sol ...
due to the many difficulties of observation. The position of Mercury as seen from Earth is always very close to the Sun, which causes challenges when trying to observe it. The
Hubble Space Telescope The Hubble Space Telescope (HST or Hubble) is a space telescope that was launched into low Earth orbit in 1990 and remains in operation. It was not the Orbiting Solar Observatory, first space telescope, but it is one of the largest and most ...
and other Earth-based space imaging systems have highly sensitive sensors so they can observe deep space objects. They must not be directed toward the Sun, lest its powerful radiation destroy the sensors. Instead, flyby and orbital missions to Mercury can study the planet and receive accurate data. Even though Mercury is closer to Earth than Pluto is, the
transfer orbit Orbits Astrodynamics In orbital mechanics, a transfer orbit is an intermediate elliptical orbit that is used to move a spacecraft in an orbital maneuver from one circular, or largely circular, orbit to another. There are several types of tran ...
from Earth to Mercury requires more energy. Mercury being so close to the Sun, space probes going there are accelerating as they approach, due to the Sun's gravitational pull. This requires the use of
retrorocket A retrorocket (short for ''retrograde rocket'') is a rocket engine providing thrust opposing the motion of a vehicle, thereby causing it to decelerate. They have mostly been used in spacecraft, with more limited use in short-runway aircraft land ...
s, which use fuel that the probe must carry instead of better instruments.


See also

*
Orders of magnitude (pressure) This is a tabulated listing of the orders of magnitude in relation to pressure expressed in pascals. psi values, prefixed with + and -, denote values relative to Earth's sea level standard atmospheric pressure (psig); otherwise, psia is assumed. ...
* Magnetosphere of Mercury


References


Notes


Bibliography

* * * * * * * * * {{Authority control Mercury Mercury (planet)