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In
nuclear physics Nuclear physics is the field of physics that studies atomic nuclei and their constituents and interactions, in addition to the study of other forms of nuclear matter. Nuclear physics should not be confused with atomic physics, which studies th ...
, a magic number is a number of nucleons (either
proton A proton is a stable subatomic particle, symbol , Hydron (chemistry), H+, or 1H+ with a positive electric charge of +1 ''e'' (elementary charge). Its mass is slightly less than the mass of a neutron and approximately times the mass of an e ...
s or
neutron The neutron is a subatomic particle, symbol or , that has no electric charge, and a mass slightly greater than that of a proton. The Discovery of the neutron, neutron was discovered by James Chadwick in 1932, leading to the discovery of nucle ...
s, separately) such that they are arranged into complete shells within the
atomic nucleus The atomic nucleus is the small, dense region consisting of protons and neutrons at the center of an atom, discovered in 1911 by Ernest Rutherford at the Department_of_Physics_and_Astronomy,_University_of_Manchester , University of Manchester ...
. As a result, atomic nuclei with a "magic" number of protons or neutrons are much more stable than other nuclei. The seven most widely recognized magic numbers as of 2019 are 2, 8, 20, 28, 50, 82, and 126. For protons, this corresponds to the elements
helium Helium (from ) is a chemical element; it has chemical symbol, symbol He and atomic number 2. It is a colorless, odorless, non-toxic, inert gas, inert, monatomic gas and the first in the noble gas group in the periodic table. Its boiling point is ...
,
oxygen Oxygen is a chemical element; it has chemical symbol, symbol O and atomic number 8. It is a member of the chalcogen group (periodic table), group in the periodic table, a highly reactivity (chemistry), reactive nonmetal (chemistry), non ...
, calcium, nickel, tin,
lead Lead () is a chemical element; it has Chemical symbol, symbol Pb (from Latin ) and atomic number 82. It is a Heavy metal (elements), heavy metal that is density, denser than most common materials. Lead is Mohs scale, soft and Ductility, malleabl ...
, and the hypothetical unbihexium, although 126 is so far only known to be a magic number for neutrons. Atomic nuclei consisting of such a magic number of nucleons have a higher average
binding energy In physics and chemistry, binding energy is the smallest amount of energy required to remove a particle from a system of particles or to disassemble a system of particles into individual parts. In the former meaning the term is predominantly use ...
per nucleon than one would expect based upon predictions such as the semi-empirical mass formula and are hence more stable against nuclear decay. The unusual stability of
isotope Isotopes are distinct nuclear species (or ''nuclides'') of the same chemical element. They have the same atomic number (number of protons in their Atomic nucleus, nuclei) and position in the periodic table (and hence belong to the same chemica ...
s having magic numbers means that transuranium elements could theoretically be created with extremely large nuclei and yet not be subject to the extremely rapid radioactive decay normally associated with high
atomic number The atomic number or nuclear charge number (symbol ''Z'') of a chemical element is the charge number of its atomic nucleus. For ordinary nuclei composed of protons and neutrons, this is equal to the proton number (''n''p) or the number of pro ...
s. Large isotopes with magic numbers of nucleons are said to exist in an island of stability. Unlike the magic numbers 2–126, which are realized in spherical nuclei, theoretical calculations predict that nuclei in the island of stability are deformed. Before this was realized, higher magic numbers, such as 184, 258, 350, and 462, were predicted based on simple calculations that assumed spherical shapes: these are generated by the formula 2(\tbinom n1+ \tbinom n2+\tbinom n3) . It is now believed that the sequence of spherical magic numbers cannot be extended in this way. Further predicted magic numbers are 114, 122, 124, and 164 for protons as well as 184, 196, 236, and 318 for neutrons. However, more modern calculations predict 228 and 308 for neutrons, along with 184 and 196.


History and etymology

While working on the Manhattan Project, the German physicist Maria Goeppert Mayer became interested in the properties of nuclear fission products, such as decay energies and half-lives. In 1948, she published a body of experimental evidence for the occurrence of closed nuclear shells for nuclei with 50 or 82 protons or 50, 82, and 126 neutrons. It had already been known that nuclei with 20 protons or neutrons were stable: that was evidenced by calculations by Hungarian-American physicist Eugene Wigner, one of her colleagues in the Manhattan Project. Two years later, in 1950, a new publication followed in which she attributed the shell closures at the magic numbers to spin-orbit coupling. According to Steven Moszkowski, a student of Goeppert Mayer, the term "magic number" was coined by Wigner: "Wigner too believed in the liquid drop model, but he recognized, from the work of Maria Mayer, the very strong evidence for the closed shells. It seemed a little like magic to him, and that is how the words 'Magic Numbers' were coined." These magic numbers were the bedrock of the nuclear shell model, which Mayer developed in the following years together with Hans Jensen and culminated in their shared 1963 Nobel Prize in Physics.


Doubly magic

Nuclei which have neutron numbers and proton ( atomic) numbers both equal to one of the magic numbers are called "doubly magic", and are generally very stable against decay. The known doubly magic isotopes are
helium-4 Helium-4 () is a stable isotope of the element helium. It is by far the more abundant of the two naturally occurring isotopes of helium, making up about 99.99986% of the helium on Earth. Its nucleus is identical to an alpha particle, and consi ...
,
helium Helium (from ) is a chemical element; it has chemical symbol, symbol He and atomic number 2. It is a colorless, odorless, non-toxic, inert gas, inert, monatomic gas and the first in the noble gas group in the periodic table. Its boiling point is ...
-10, oxygen-16, calcium-40, calcium-48, nickel-48, nickel-56, nickel-78, tin-100, tin-132, and
lead Lead () is a chemical element; it has Chemical symbol, symbol Pb (from Latin ) and atomic number 82. It is a Heavy metal (elements), heavy metal that is density, denser than most common materials. Lead is Mohs scale, soft and Ductility, malleabl ...
-208. While only helium-4, oxygen-16, calcium-40, and lead-208 are completely stable, calcium-48 is extremely long-lived and therefore found naturally, disintegrating only by a very inefficient double beta minus decay process. Double beta decay in general is so rare that several nuclides exist which are predicted to decay by this mechanism but in which no such decay has yet been observed. Even in nuclides whose double beta decay has been confirmed through observations, half lives usually exceed the age of the universe by orders of magnitude, and emitted beta or gamma radiation is for virtually all practical purposes irrelevant. On the other hand, helium-10 is extremely unstable, and has a
half-life Half-life is a mathematical and scientific description of exponential or gradual decay. Half-life, half life or halflife may also refer to: Film * Half-Life (film), ''Half-Life'' (film), a 2008 independent film by Jennifer Phang * ''Half Life: ...
of just (). Doubly magic effects may allow the existence of stable isotopes which otherwise would not have been expected. An example is calcium-40, with 20 neutrons and 20 protons, which is the heaviest stable isotope made of the same number of protons and neutrons. Both calcium-48 and nickel-48 are doubly magic because calcium-48 has 20 protons and 28 neutrons while nickel-48 has 28 protons and 20 neutrons. Calcium-48 is very neutron-rich for such a relatively light element, but like calcium-40, it is stabilized by being doubly magic. As an exception, although oxygen-28 has 8 protons and 20 neutrons, it is unbound with respect to four-neutron decay and appears to lack closed neutron shells, so it is not regarded as doubly magic. Magic number shell effects are seen in ordinary abundances of elements: helium-4 is among the most abundant (and stable) nuclei in the universe and lead-208 is the heaviest stable nuclide ( at least by known experimental observations).
Alpha decay Alpha decay or α-decay is a type of radioactive decay in which an atomic nucleus emits an alpha particle (helium nucleus). The parent nucleus transforms or "decays" into a daughter product, with a mass number that is reduced by four and an a ...
(the emission of a 4He nucleus – also known as an alpha particle – by a heavy element undergoing radioactive decay) is common in part due to the extraordinary stability of helium-4, which makes this type of decay energetically favored in most heavy nuclei over neutron emission, proton emission or any other type of cluster decay. The stability of 4He also leads to the absence of stable isobars of mass number 5 and 8; indeed, all nuclides of those mass numbers decay within fractions of a second to produce alpha particles. Magic effects can keep unstable nuclides from decaying as rapidly as would otherwise be expected. For example, the nuclides tin-100 and tin-132 are examples of doubly magic isotopes of tin that are unstable, and represent endpoints beyond which stability drops off rapidly. Nickel-48, discovered in 1999, is the most proton-rich doubly magic nuclide known. At the other extreme, nickel-78 is also doubly magic, with 28 protons and 50 neutrons, a ratio observed only in much heavier elements, apart from tritium with one proton and two neutrons (78Ni: 28/50 = 0.56; 238U: 92/146 = 0.63). In December 2006, hassium-270, with 108 protons and 162 neutrons, was discovered by an international team of scientists led by the Technical University of Munich, having a
half-life Half-life is a mathematical and scientific description of exponential or gradual decay. Half-life, half life or halflife may also refer to: Film * Half-Life (film), ''Half-Life'' (film), a 2008 independent film by Jennifer Phang * ''Half Life: ...
of 9 seconds. Hassium-270 evidently forms part of an island of stability, and may even be doubly magic due to the deformed (
American football American football, referred to simply as football in the United States and Canada and also known as gridiron football, is a team sport played by two teams of eleven players on a rectangular American football field, field with goalposts at e ...
- or rugby ball-like) shape of this nucleus. Although ''Z'' = 92 and ''N'' = 164 are not magic numbers, the undiscovered neutron-rich nucleus uranium-256 may be doubly magic and spherical due to the difference in size between low- and high-
angular momentum Angular momentum (sometimes called moment of momentum or rotational momentum) is the rotational analog of Momentum, linear momentum. It is an important physical quantity because it is a Conservation law, conserved quantity – the total ang ...
orbitals, which alters the shape of the nuclear potential.


Derivation

Magic numbers are typically obtained by
empirical Empirical evidence is evidence obtained through sense experience or experimental procedure. It is of central importance to the sciences and plays a role in various other fields, like epistemology and law. There is no general agreement on how t ...
studies; if the form of the nuclear potential is known, then the Schrödinger equation can be solved for the motion of nucleons and energy levels determined. Nuclear shells are said to occur when the separation between energy levels is significantly greater than the local mean separation. In the shell model for the nucleus, magic numbers are the numbers of nucleons at which a shell is filled. For instance, the magic number 8 occurs when the 1s1/2, 1p3/2, 1p1/2 energy levels are filled, as there is a large energy gap between the 1p1/2 and the next highest 1d5/2 energy levels. The atomic analog to nuclear magic numbers are those numbers of
electron The electron (, or in nuclear reactions) is a subatomic particle with a negative one elementary charge, elementary electric charge. It is a fundamental particle that comprises the ordinary matter that makes up the universe, along with up qua ...
s leading to discontinuities in the
ionization energy In physics and chemistry, ionization energy (IE) is the minimum energy required to remove the most loosely bound electron of an isolated gaseous atom, Ion, positive ion, or molecule. The first ionization energy is quantitatively expressed as : ...
. These occur for the
noble gas The noble gases (historically the inert gases, sometimes referred to as aerogens) are the members of Group (periodic table), group 18 of the periodic table: helium (He), neon (Ne), argon (Ar), krypton (Kr), xenon (Xe), radon (Rn) and, in some ...
es
helium Helium (from ) is a chemical element; it has chemical symbol, symbol He and atomic number 2. It is a colorless, odorless, non-toxic, inert gas, inert, monatomic gas and the first in the noble gas group in the periodic table. Its boiling point is ...
,
neon Neon is a chemical element; it has symbol Ne and atomic number 10. It is the second noble gas in the periodic table. Neon is a colorless, odorless, inert monatomic gas under standard conditions, with approximately two-thirds the density of ...
,
argon Argon is a chemical element; it has symbol Ar and atomic number 18. It is in group 18 of the periodic table and is a noble gas. Argon is the third most abundant gas in Earth's atmosphere, at 0.934% (9340 ppmv). It is more than twice as abu ...
,
krypton Krypton (from 'the hidden one') is a chemical element; it has symbol (chemistry), symbol Kr and atomic number 36. It is a colorless, odorless noble gas that occurs in trace element, trace amounts in the Earth's atmosphere, atmosphere and is of ...
,
xenon Xenon is a chemical element; it has symbol Xe and atomic number 54. It is a dense, colorless, odorless noble gas found in Earth's atmosphere in trace amounts. Although generally unreactive, it can undergo a few chemical reactions such as the ...
, radon and
oganesson Oganesson is a synthetic element, synthetic chemical element; it has Chemical symbol, symbol Og and atomic number 118. It was first synthesized in 2002 at the Joint Institute for Nuclear Research (JINR) in Dubna, near Moscow, Russia, by a joint ...
. Hence, the "atomic magic numbers" are 2, 10, 18, 36, 54, 86 and 118. As with the nuclear magic numbers, these are expected to be changed in the superheavy region due to spin/orbit-coupling effects affecting subshell energy levels. Hence copernicium (112) and flerovium (114) are expected to be more inert than oganesson (118), and the next noble gas after these is expected to occur at element 172 rather than 168 (which would continue the pattern). In 2010, an alternative explanation of magic numbers was given in terms of symmetry considerations. Based on the fractional extension of the standard rotation group, the ground state properties (including the magic numbers) for metallic clusters and nuclei were simultaneously determined analytically. A specific potential term is not necessary in this model.


See also

* Magic number (chemistry) * Superatom * Superdeformation


References


External links

* * see chapter 10 especially. * * {{DEFAULTSORT:Physics - Magic Number Isotopes Periodic table Radioactivity Integer sequences