Linarite is a somewhat rare, crystalline mineral that is known among
mineral collector
Mineral collecting is the hobby of systematically collecting, identifying and displaying mineral specimens. Mineral collecting can also be a part of the profession of mineralogy and allied geologic specialties. Individual collectors often ...
s for its unusually intense, pure blue color. It is formed by the
oxidation
Redox (reduction–oxidation, , ) is a type of chemical reaction in which the oxidation states of substrate change. Oxidation is the loss of electrons or an increase in the oxidation state, while reduction is the gain of electrons or a ...
of
galena
Galena, also called lead glance, is the natural mineral form of lead(II) sulfide (PbS). It is the most important ore of lead and an important source of silver.
Galena is one of the most abundant and widely distributed sulfide minerals. It cry ...
and
chalcopyrite
Chalcopyrite ( ) is a copper iron sulfide mineral and the most abundant copper ore mineral. It has the chemical formula CuFeS2 and crystallizes in the tetragonal system. It has a brassy to golden yellow color and a hardness of 3.5 to 4 on the Mo ...
and other copper sulfides. It is a combined
copper
Copper is a chemical element with the symbol Cu (from la, cuprum) and atomic number 29. It is a soft, malleable, and ductile metal with very high thermal and electrical conductivity. A freshly exposed surface of pure copper has a pinkish ...
lead
Lead is a chemical element with the Symbol (chemistry), symbol Pb (from the Latin ) and atomic number 82. It is a heavy metals, heavy metal that is density, denser than most common materials. Lead is Mohs scale of mineral hardness#Intermediate ...
sulfate
The sulfate or sulphate ion is a polyatomic ion, polyatomic anion with the empirical formula . Salts, acid derivatives, and peroxides of sulfate are widely used in industry. Sulfates occur widely in everyday life. Sulfates are salt (chemistry), ...
hydroxide
Hydroxide is a diatomic anion with chemical formula OH−. It consists of an oxygen and hydrogen atom held together by a single covalent bond, and carries a negative electric charge. It is an important but usually minor constituent of water ...
with formula PbCuSO
4(OH)
2.
Linarite occurs as
monoclinic
In crystallography, the monoclinic crystal system is one of the seven crystal systems. A crystal system is described by three vectors. In the monoclinic system, the crystal is described by vectors of unequal lengths, as in the orthorhombic ...
prismatic to tabular crystals and irregular masses. It is easily confused with
azurite
Azurite is a soft, deep-blue copper mineral produced by weathering of copper ore deposits. During the early 19th century, it was also known as chessylite, after the type locality at Chessy-les-Mines near Lyon, France. The mineral, a basic car ...
, but does not react with dilute
hydrochloric acid
Hydrochloric acid, also known as muriatic acid, is an aqueous solution of hydrogen chloride. It is a colorless solution with a distinctive pungent smell. It is classified as a strong acid. It is a component of the gastric acid in the dig ...
as azurite does. It has a
Mohs hardness
The Mohs scale of mineral hardness () is a qualitative ordinal scale, from 1 to 10, characterizing scratch resistance of various minerals through the ability of harder material to scratch softer material.
The scale was introduced in 1812 by the ...
of 2.5 and a
specific gravity
Relative density, or specific gravity, is the ratio of the density (mass of a unit volume) of a substance to the density of a given reference material. Specific gravity for liquids is nearly always measured with respect to water (molecule), wa ...
of 5.3 - 5.5.
Linarite was first identified in 1822. It is named after the Linares Plateau,
Spain
, image_flag = Bandera de España.svg
, image_coat = Escudo de España (mazonado).svg
, national_motto = '' Plus ultra'' ( Latin)(English: "Further Beyond")
, national_anthem = (English: "Royal March")
, ...
.
[ It occurs in association with ]brochantite
Brochantite is a sulfate mineral, one of a number of cupric sulfates. Its chemical formula is Cu4SO4(OH)6. Formed in arid climates or in rapidly oxidizing copper sulfide deposits, it was named by Armand Lévy for his fellow Frenchman, geologi ...
, anglesite
Anglesite is a lead sulfate mineral with the chemical formula PbSO4. It occurs as an oxidation product of primary lead sulfide ore, galena. Anglesite occurs as prismatic orthorhombic crystals and earthy masses, and is isomorphous with barite and ...
, caledonite, leadhillite
Leadhillite is a lead sulfate carbonate hydroxide mineral, often associated with anglesite. It has the formula Pb4SO4(CO3)2(OH)2. Leadhillite crystallises in the monoclinic system, but develops pseudo-hexagonal forms due to crystal twinning. It f ...
, cerussite
Cerussite (also known as lead carbonate or white lead ore) is a mineral consisting of lead carbonate (PbCO3), and is an important ore of lead. The name is from the Latin ''cerussa'', white lead. ''Cerussa nativa'' was mentioned by Conrad Gess ...
, malachite
Malachite is a copper carbonate hydroxide mineral, with the formula Cu2CO3(OH)2. This opaque, green-banded mineral crystallizes in the monoclinic crystal system, and most often forms botryoidal, fibrous, or stalagmitic masses, in fracture ...
and hemimorphite
Hemimorphite is the chemical compound Zn4( Si2O7)( OH)2 ·H2O, a component of mineral calamine. It is a silicate mineral which, together with smithsonite (ZnCO3), has been historically mined from the upper parts of zinc and lead ores. Both c ...
.[
]
Image gallery
File:Linarite-130099.jpg, A shallow pocket of crystals of an intense cobalt blue, from Darwin, Darwin District, Inyo County, California, USA
File:Linarite-37781.jpg, Linarite with malachite
Malachite is a copper carbonate hydroxide mineral, with the formula Cu2CO3(OH)2. This opaque, green-banded mineral crystallizes in the monoclinic crystal system, and most often forms botryoidal, fibrous, or stalagmitic masses, in fracture ...
, Blanchard Mine, Hansonburg District, Socorro County, New Mexico
Socorro County is a county in the U.S. state of New Mexico. As of the 2010 census, the population was 17,866. The county seat is Socorro. The county was formed in 1852 as one of the original nine counties of New Mexico Territory. Socorro w ...
USA (Size: 1.1 x 0.8 x 0.4 cm)
File:Linarite-Caledonite-53689.jpg, Linarite with caledonite, from Baker, El Dorado County, California
El Dorado County (), officially the County of El Dorado, is a county located in the U.S. state of California. As of the 2020 census, the population was 191,185. The county seat is Placerville. The County is part of the Sacramento-Rosevil ...
USA (Size 5.4 x 5.2 x 3.2 cm)
File:Malachite-Linarite-Cerussite-173905.jpg, Unusual cerussite with a coating ingrained into the surface of microcrystalline malachite and linarite that give it a rich blue-green color
References
Mineral galleries
Lead minerals
Copper(II) minerals
Sulfate minerals
Monoclinic minerals
Minerals in space group 11
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