The Kozeny–Carman equation (or Carman–Kozeny equation or Kozeny equation) is a relation used in the field of
fluid dynamics
In physics and engineering, fluid dynamics is a subdiscipline of fluid mechanics that describes the flow of fluids—liquids and gases. It has several subdisciplines, including '' aerodynamics'' (the study of air and other gases in motion) ...
to calculate the
pressure drop
Pressure drop is defined as the difference in total pressure between two points of a fluid carrying network. A pressure drop occurs when frictional forces, caused by the resistance to flow, act on a fluid as it flows through the tube. The main d ...
of a
fluid
In physics, a fluid is a liquid, gas, or other material that continuously deforms (''flows'') under an applied shear stress, or external force. They have zero shear modulus, or, in simpler terms, are substances which cannot resist any shea ...
flowing through a
packed bed
In chemical processing, a packed bed is a hollow tube, pipe, or other vessel that is filled with a packing material. The packing can be randomly filled with small objects like Raschig rings or else it can be a specifically designed structure ...
of solids. It is named after
Josef Kozeny and Philip C. Carman. The equation is only valid for
creeping flow, i.e. in the slowest limit of
laminar flow. The equation was derived by Kozeny (1927)
and Carman (1937, 1956)
[
] from a starting point of (a) modelling fluid flow in a
packed bed
In chemical processing, a packed bed is a hollow tube, pipe, or other vessel that is filled with a packing material. The packing can be randomly filled with small objects like Raschig rings or else it can be a specifically designed structure ...
as laminar fluid flow in a collection of curving passages/tubes crossing the
packed bed
In chemical processing, a packed bed is a hollow tube, pipe, or other vessel that is filled with a packing material. The packing can be randomly filled with small objects like Raschig rings or else it can be a specifically designed structure ...
and (b)
Poiseuille's law describing laminar fluid flow in straight, circular section pipes.
Equation
The equation is given as:
[
]
:
where:
*
is the pressure drop;
*
is the total height of the bed;
*
is the
superficial or "empty-tower" velocity;
*
is the
viscosity
The viscosity of a fluid is a measure of its resistance to deformation at a given rate. For liquids, it corresponds to the informal concept of "thickness": for example, syrup has a higher viscosity than water.
Viscosity quantifies the inte ...
of the fluid;
*
is the
porosity
Porosity or void fraction is a measure of the void (i.e. "empty") spaces in a material, and is a fraction of the volume of voids over the total volume, between 0 and 1, or as a percentage between 0% and 100%. Strictly speaking, some tests measure ...
of the bed;
*
is the
sphericity
Sphericity is a measure of how closely the shape of an object resembles that of a perfect sphere. For example, the sphericity of the balls inside a ball bearing determines the quality of the bearing, such as the load it can bear or the speed a ...
of the particles in the packed bed;
*
is the diameter of the volume equivalent spherical particle.
[
]
This equation holds for flow through packed beds with particle
Reynolds numbers up to approximately 1.0, after which point frequent shifting of flow channels in the bed causes considerable
kinetic energy
In physics, the kinetic energy of an object is the energy that it possesses due to its motion.
It is defined as the work needed to accelerate a body of a given mass from rest to its stated velocity. Having gained this energy during its a ...
losses.
This equation is a partial case of the
Darcy's law
Darcy's law is an equation that describes the flow of a fluid through a porous medium. The law was formulated by Henry Darcy based on results of experiments on the flow of water through beds of sand, forming the basis of hydrogeology, a branch of ...
stating that "''flow is proportional to the pressure drop and inversely proportional to the fluid viscosity''".
:
Combining these equations gives the final Kozeny equation for absolute (single phase) permeability
:
*
is the
porosity
Porosity or void fraction is a measure of the void (i.e. "empty") spaces in a material, and is a fraction of the volume of voids over the total volume, between 0 and 1, or as a percentage between 0% and 100%. Strictly speaking, some tests measure ...
of the bed (or core plug)
raction*
is average diameter of sand grains
*
is absolute (i.e. single phase) permeability
^2*
is the
phericityof the particles in the packed bed = 1 for spherical particles
The combined proportionality and unity factor
has typically average value of 0.8E6 /1.0135 from measuring many naturally occurring core plug samples, ranging from high to low clay content, but it may reach a value of 3.2E6 /1.0135 for clean sand. The denominator is included explicitly to remind us that permeability is defined using
tmas pressure unit while reservoir engineering calculations and reservoir simulations typically use
aras pressure unit.
History
The equation was first
[Robert P. Chapuis and Michel Aubertin, "PREDICTING THE COEFFICIENT OF PERMEABILITY OF SOILS USING THE KOZENY-CARMAN EQUATION", Report EPM–RT–2003-03, Département des génies civil, géologique et des mines; École Polytechnique de Montréal, January 2003 https://publications.polymtl.ca/2605/1/EPM-RT-2003-03_Chapuis.pdf (accessed 2011-02-05)] proposed by Kozeny (1927)
[J. Kozeny,]
Ueber kapillare Leitung des Wassers im Boden
" Sitzungsber Akad. Wiss., Wien, 136(2a): 271-306, 1927. and later modified by Carman (1937, 1956).
[P.C. Carman, "Fluid flow through granular beds." Transactions, Institution of Chemical Engineers, London, 15: 150-166, 1937.][P.C. Carman, "Flow of gases through porous media." Butterworths, London, 1956.] A similar equation was derived independently by Fair and Hatch in 1933.
[ G.M. Fair, L.P. Hatch, Fundamental factors governing the streamline flow of water through sand, J. AWWA 25 (1933) 1551–1565.] A comprehensive review of other equations has been published
[ E. Erdim, Ö. Akgiray and İ. Demir, A revisit of pressure drop-flow rate correlations for packed beds of spheres, Powder Technology Volume 283, October 2015, Pages 488-504 ]
See also
*
Fractionating column
A fractionating column or fractional column is an essential item used in the distillation of liquid mixtures to separate the mixture into its component parts, or fractions, based on the differences in volatilities. Fractionating columns are used in ...
*
Random close pack
*
Raschig ring
*
Ergun equation
References
{{DEFAULTSORT:Kozeny-Carman equation
Equations of fluid dynamics
Unit operations
Porous media