A Hofmann voltameter is an apparatus for electrolysing water, invented by

August Wilhelm von Hofmann August Wilhelm von Hofmann (8 April 18185 May 1892) was a German chemist who made considerable contributions to organic chemistry. His research on aniline helped lay the basis of the aniline-dye industry, and his research on coal tar laid the g ...

(1818–1892) in 1866. It consists of three joined upright cylinders, usually glass. The inner cylinder is open at the top to allow addition of

water Water is an inorganic compound with the chemical formula . It is a transparent, tasteless, odorless, and Color of water, nearly colorless chemical substance. It is the main constituent of Earth's hydrosphere and the fluids of all known liv ...

which contains a low concentration of a compound such as

sulfuric acid Sulfuric acid (American spelling and the preferred IUPAC name) or sulphuric acid (English in the Commonwealth of Nations, Commonwealth spelling), known in antiquity as oil of vitriol, is a mineral acid composed of the elements sulfur, oxygen, ...

to improve conductivity and complete the circuit. A

platinum Platinum is a chemical element; it has Symbol (chemistry), symbol Pt and atomic number 78. It is a density, dense, malleable, ductility, ductile, highly unreactive, precious metal, precious, silverish-white transition metal. Its name origina ...

electrode is placed inside the bottom of each of the two side cylinders, connected to the positive and negative terminals of a source of

electricity Electricity is the set of physical phenomena associated with the presence and motion of matter possessing an electric charge. Electricity is related to magnetism, both being part of the phenomenon of electromagnetism, as described by Maxwel ...

. When current is run through Hofmann's voltameter, gaseous

oxygen Oxygen is a chemical element; it has chemical symbol, symbol O and atomic number 8. It is a member of the chalcogen group (periodic table), group in the periodic table, a highly reactivity (chemistry), reactive nonmetal (chemistry), non ...

forms at the

anode An anode usually is an electrode of a polarized electrical device through which conventional current enters the device. This contrasts with a cathode, which is usually an electrode of the device through which conventional current leaves the devic ...

and gaseous

hydrogen Hydrogen is a chemical element; it has chemical symbol, symbol H and atomic number 1. It is the lightest and abundance of the chemical elements, most abundant chemical element in the universe, constituting about 75% of all baryon, normal matter ...

at the

cathode A cathode is the electrode from which a conventional current leaves a polarized electrical device such as a lead-acid battery. This definition can be recalled by using the mnemonic ''CCD'' for ''Cathode Current Departs''. Conventional curren ...

. Each gas displaces water and collects at the top of the two outer tubes. The tubes which collect the product gases are usually graduated, so that the volume of gas can be measured.

Name

The name ' voltameter' was coined by

Daniell Daniell is a surname. Notable people with the surname include: * Alexander Daniell (1599–1668), Cornish landowner * Alfred Daniell (1853–1937) * Ave Daniell (1914–1999), American (gridiron) footballer * Charles Daniell (1827–1889), Majo ...

, who shortened

Faraday Michael Faraday (; 22 September 1791 – 25 August 1867) was an English chemist and physicist who contributed to the study of electrochemistry and electromagnetism. His main discoveries include the principles underlying electromagnetic inducti ...

's original name of "volta-electrometer". Hofmann voltameters are no longer used as electrical measuring devices. However, before the invention of the

ammeter An ammeter (abbreviation of ''ampere meter'') is an measuring instrument, instrument used to measure the electric current, current in a Electrical circuit, circuit. Electric currents are measured in amperes (A), hence the name. For direct measure ...

, voltameters were often used to measure

direct current Direct current (DC) is one-directional electric current, flow of electric charge. An electrochemical cell is a prime example of DC power. Direct current may flow through a conductor (material), conductor such as a wire, but can also flow throug ...

, since current through a voltameter with

iron Iron is a chemical element; it has symbol Fe () and atomic number 26. It is a metal that belongs to the first transition series and group 8 of the periodic table. It is, by mass, the most common element on Earth, forming much of Earth's o ...

copper Copper is a chemical element; it has symbol Cu (from Latin ) and atomic number 29. It is a soft, malleable, and ductile metal with very high thermal and electrical conductivity. A freshly exposed surface of pure copper has a pinkish-orang ...

electrodes electroplates the cathode with an amount of metal from the anode directly proportional to the total coulombs of charge transferred ( Faraday's law of electrolysis). The modern name is "electrochemical

coulometer A voltameter or coulometer is a scientific instrument used for measuring instrument, measuring electric charge (quantity of electricity) through electrolytic action. The International System of Units, SI unit of electric charge is the coulomb. T ...

". Although the correct spelling of Hofmann contains only one 'f', it is often incorrectly depicted as Hoffmann.

Uses

The amount of electricity that has passed through the system can then be determined from the volume of gas.

Thomas Edison Thomas Alva Edison (February11, 1847October18, 1931) was an American inventor and businessman. He developed many devices in fields such as electric power generation, mass communication, sound recording, and motion pictures. These inventions, ...

used voltameters as electricity meters. A Hofmann voltameter is often used as a demonstration of

stoichiometric Stoichiometry () is the relationships between the masses of reactants and products before, during, and following chemical reactions. Stoichiometry is based on the law of conservation of mass; the total mass of reactants must equal the total m ...

principles, as the two-to-one ratio of the volumes of

and

gas produced by the apparatus illustrates the chemical formula of water, H₂O. However, this is only true if oxygen and hydrogen gases are assumed to be diatomic. If hydrogen gas were monatomic and oxygen diatomic, the gas volume ratio would be 4:1. The volumetric composition of water is the ratio by volume of hydrogen to oxygen present. This value is 2:1 experimentally; this value is determined using Hofmann's water voltameter.

References

{{DEFAULTSORT:Hofmann Voltameter Electrolytic cells Hydrogen technologies Hydrogen production

Name

Uses

See also

References