High-level waste (HLW) is a type of

nuclear waste Radioactive waste is a type of hazardous waste that contains radioactive material. It is a result of many activities, including nuclear medicine, nuclear research, nuclear power generation, nuclear decommissioning, rare-earth mining, and nuclear ...

created by the reprocessing of spent nuclear fuel. It exists in two main forms: * First and second cycle raffinate and other waste streams created by

nuclear reprocessing Nuclear reprocessing is the chemical separation of fission products and actinides from spent nuclear fuel. Originally, reprocessing was used solely to extract plutonium for producing nuclear weapons. With commercialization of nuclear power, the ...

. * Waste formed by

vitrification Vitrification (, via French ') is the full or partial transformation of a substance into a glass, that is to say, a non- crystalline or amorphous solid. Glasses differ from liquids structurally and glasses possess a higher degree of connectivity ...

of liquid high-level waste. Liquid high-level waste is typically held temporarily in underground tanks pending vitrification. Most of the high-level waste created by the

Manhattan Project The Manhattan Project was a research and development program undertaken during World War II to produce the first nuclear weapons. It was led by the United States in collaboration with the United Kingdom and Canada. From 1942 to 1946, the ...

and the weapons programs of the

Cold War The Cold War was a period of global Geopolitics, geopolitical rivalry between the United States (US) and the Soviet Union (USSR) and their respective allies, the capitalist Western Bloc and communist Eastern Bloc, which lasted from 1947 unt ...

exists in this form because funding for further processing was typically not part of the original weapons programs. Both spent nuclear fuel and vitrified waste are considered as suitable forms for long term disposal, after a period of temporary storage in the case of spent nuclear fuel. HLW contains many of the fission products and transuranic elements generated in the reactor core and is the type of nuclear waste with the highest activity. HLW accounts for over 95% of the total radioactivity produced in the nuclear power process. In other words, while most nuclear waste is low-level and intermediate-level waste, such as protective clothing and equipment that have been contaminated with radiation, the majority of the ''radioactivity'' produced from the nuclear power generation process comes from high-level waste. Some countries, particularly France, reprocess commercial spent fuel. High-level waste is very radioactive and, therefore, requires special shielding during handling and transport. Initially it also needs cooling, because it generates a great deal of heat. Most of the heat, at least after short-lived nuclides have decayed, is from the medium-lived fission products

caesium-137 Caesium-137 (), cesium-137 (US), or radiocaesium, is a radioactive isotope of caesium that is formed as one of the more common fission products by the nuclear fission of uranium-235 and other fissionable isotopes in nuclear reactors and nucle ...

and

strontium-90 Strontium-90 () is a radioactive isotope of strontium produced by nuclear fission, with a half-life of 28.79 years. It undergoes β− decay into yttrium-90, with a decay energy of 0.546 MeV. Strontium-90 has applications in medicine a ...

, which have half-lives on the order of 30 years. A typical large 1000 MWe nuclear reactor produces 25–30 tons of

spent fuel Spent nuclear fuel, occasionally called used nuclear fuel, is nuclear fuel that has been irradiated in a nuclear reactor (usually at a nuclear power plant). It is no longer useful in sustaining a nuclear reaction in an ordinary thermal reactor and ...

per year. If the fuel were reprocessed and

vitrified Vitrification (, via French ') is the full or partial transformation of a substance into a glass, that is to say, a non- crystalline or amorphous solid. Glasses differ from liquids structurally and glasses possess a higher degree of connectivity ...

, the waste volume would be only about three cubic meters per year, but the

decay heat Decay heat is the heat released as a result of radioactive decay. This heat is produced as an effect of radiation on materials: the energy of the alpha particle, alpha, Beta particle, beta or gamma radiation is converted into the thermal movement ...

would be almost the same. It is generally accepted that the final waste will be disposed of in a

deep geological repository A deep geological repository is a way of storing hazardous or radioactive waste within a stable geologic environment, typically 200–1,000 m below the surface of the earth. It entails a combination of waste form, waste package, engineered seals ...

, and many countries have developed plans for such a site, including

Finland Finland, officially the Republic of Finland, is a Nordic country in Northern Europe. It borders Sweden to the northwest, Norway to the north, and Russia to the east, with the Gulf of Bothnia to the west and the Gulf of Finland to the south, ...

France France, officially the French Republic, is a country located primarily in Western Europe. Overseas France, Its overseas regions and territories include French Guiana in South America, Saint Pierre and Miquelon in the Atlantic Ocean#North Atlan ...

Japan Japan is an island country in East Asia. Located in the Pacific Ocean off the northeast coast of the Asia, Asian mainland, it is bordered on the west by the Sea of Japan and extends from the Sea of Okhotsk in the north to the East China Sea ...

United States The United States of America (USA), also known as the United States (U.S.) or America, is a country primarily located in North America. It is a federal republic of 50 U.S. state, states and a federal capital district, Washington, D.C. The 48 ...

and

Sweden Sweden, formally the Kingdom of Sweden, is a Nordic countries, Nordic country located on the Scandinavian Peninsula in Northern Europe. It borders Norway to the west and north, and Finland to the east. At , Sweden is the largest Nordic count ...

Definitions

High-level waste is the highly radioactive waste material resulting from the reprocessing of spent nuclear fuel, including liquid waste produced directly in reprocessing and any solid material derived from such liquid waste that contains fission products in sufficient concentrations; and other highly radioactive material that is determined, consistent with existing law, to require permanent isolation. ''Spent (used) reactor fuel''. *

Spent nuclear fuel Spent nuclear fuel, occasionally called used nuclear fuel, is nuclear fuel that has been irradiated in a nuclear reactor (usually at a nuclear power plant). It is no longer useful in sustaining a nuclear reaction in an ordinary thermal reactor and ...

is used reactor fuel that is no longer efficient in creating electricity, because its fission process has slowed due to a build-up of reaction poisons. However, it is still thermally hot, highly

radioactive Radioactive decay (also known as nuclear decay, radioactivity, radioactive disintegration, or nuclear disintegration) is the process by which an unstable atomic nucleus loses energy by radiation. A material containing unstable nuclei is conside ...

, and potentially harmful. ''Waste materials from reprocessing''. *Materials for

nuclear weapon A nuclear weapon is an explosive device that derives its destructive force from nuclear reactions, either fission (fission or atomic bomb) or a combination of fission and fusion reactions (thermonuclear weapon), producing a nuclear exp ...

s are acquired by reprocessing spent nuclear fuel from

breeder reactor A breeder reactor is a nuclear reactor that generates more fissile material than it consumes. These reactors can be fueled with more-commonly available isotopes of uranium and thorium, such as uranium-238 and thorium-232, as opposed to the ...

s. Reprocessing is a method of chemically treating spent fuel to separate out

uranium Uranium is a chemical element; it has chemical symbol, symbol U and atomic number 92. It is a silvery-grey metal in the actinide series of the periodic table. A uranium atom has 92 protons and 92 electrons, of which 6 are valence electrons. Ura ...

and

plutonium Plutonium is a chemical element; it has symbol Pu and atomic number 94. It is a silvery-gray actinide metal that tarnishes when exposed to air, and forms a dull coating when oxidized. The element normally exhibits six allotropes and four ...

. The byproduct of reprocessing is a highly radioactive sludge residue.

Storage

High-level radioactive waste is stored for 10 or 20 years in

spent fuel pool Spent fuel pools (SFP) are storage pools (or "ponds" in the United Kingdom) for spent fuel from nuclear reactors. They are typically 40 or more feet (12 m) deep, with the bottom 14 feet (4.3 m) equipped with storage racks designed to hold ...

s, and then can be put in

dry cask storage Dry cask storage is a method of storing high-level radioactive waste, such as spent nuclear fuel that has already been cooled in a spent fuel pool for at least one year and often as much as ten years. Casks are typically steel cylinders that are ...

facilities. In 1997, in the 20 countries which account for most of the world's nuclear power generation, spent fuel storage capacity at the reactors was 148,000 tonnes, with 59% of this utilized. Away-from-reactor storage capacity was 78,000 tonnes, with 44% utilized.

Definitions

Storage

See also

Notes

References

External links