Georg Wittig (; 16 June 1897 – 26 August 1987) was a

German German(s) may refer to: * Germany (of or related to) ** Germania (historical use) * Germans, citizens of Germany, people of German ancestry, or native speakers of the German language ** For citizens of Germany, see also German nationality law **Ge ...

chemist A chemist (from Greek ''chēm(ía)'' alchemy; replacing ''chymist'' from Medieval Latin ''alchemist'') is a scientist trained in the study of chemistry. Chemists study the composition of matter and its properties. Chemists carefully describe th ...

who reported a method for synthesis of

alkene In organic chemistry, an alkene is a hydrocarbon containing a carbon–carbon double bond. Alkene is often used as synonym of olefin, that is, any hydrocarbon containing one or more double bonds.H. Stephen Stoker (2015): General, Organic, an ...

s from

aldehyde In organic chemistry, an aldehyde () is an organic compound containing a functional group with the structure . The functional group itself (without the "R" side chain) can be referred to as an aldehyde but can also be classified as a formyl grou ...

s and

ketone In organic chemistry, a ketone is a functional group with the structure R–C(=O)–R', where R and R' can be a variety of carbon-containing substituents. Ketones contain a carbonyl group –C(=O)– (which contains a carbon-oxygen double bo ...

s using compounds called

phosphonium In polyatomic cations with the chemical formula (where R is a hydrogen or an alkyl, aryl, or halide group). These cations have tetrahedral structures. The salts are generally colorless or take the color of the anions. Types of phosphonium ...

ylide An ylide or ylid () is a neutral dipolar molecule containing a formally negatively charged atom (usually a carbanion) directly attached to a heteroatom with a formal positive charge (usually nitrogen, phosphorus or sulfur), and in which both atoms ...

s in the

Wittig reaction The Wittig reaction or Wittig olefination is a chemical reaction of an aldehyde or ketone with a triphenyl phosphonium ylide called a Wittig reagent. Wittig reactions are most commonly used to convert aldehydes and ketones to alkenes. Most o ...

. He shared the

Nobel Prize in Chemistry ) , image = Nobel Prize.png , alt = A golden medallion with an embossed image of a bearded man facing left in profile. To the left of the man is the text "ALFR•" then "NOBEL", and on the right, the text (smaller) "NAT•" then "M ...

with

Herbert C. Brown Herbert Charles Brown (May 22, 1912 – December 19, 2004) was an American chemist and recipient of the 1979 Nobel Prize in Chemistry for his work with organoboranes. Life and career Brown was born Herbert Brovarnik in London, to Ukrainian Jewis ...

in 1979.

Biography

Wittig was born in

Berlin, Germany Berlin ( , ) is the capital and largest city of Germany by both area and population. Its 3.7 million inhabitants make it the European Union's most populous city, according to population within city limits. One of Germany's sixteen constituent ...

and shortly after his birth moved with his family to

Kassel Kassel (; in Germany, spelled Cassel until 1926) is a city on the Fulda River in northern Hesse, Germany. It is the administrative seat of the Regierungsbezirk Kassel and the district of the same name and had 201,048 inhabitants in December 2020 ...

, where his father was professor at the applied arts high school. He attended school in Kassel and started studying chemistry at the

University of Tübingen The University of Tübingen, officially the Eberhard Karl University of Tübingen (german: Eberhard Karls Universität Tübingen; la, Universitas Eberhardina Carolina), is a public research university located in the city of Tübingen, Baden-Wü ...

1916. He was drafted and became a lieutenant in the cavalry of

Hesse-Kassel The Landgraviate of Hesse-Kassel (german: Landgrafschaft Hessen-Kassel), spelled Hesse-Cassel during its entire existence, was a state in the Holy Roman Empire that was directly subject to the Emperor. The state was created in 1567 when the Lan ...

(or Hesse-Cassel). After being an Allied prisoner of war from 1918 until 1919, Wittig found it hard to restart his chemistry studies owing to overcrowding at the universities. By a direct plea to

Karl von Auwers Karl Friedrich von Auwers (September 16, 1863 – May 3, 1939) was a German chemist, and was the academic adviser of both Karl Ziegler and Georg Wittig at the University of Marburg. Life Karl Friedrich von Auwers was born the son of the renowned ...

, who was professor for organic chemistry at the

University of Marburg The Philipps University of Marburg (german: Philipps-Universität Marburg) was founded in 1527 by Philip I, Landgrave of Hesse, which makes it one of Germany's oldest universities and the oldest still operating Protestant university in the wor ...

at the time, he was able to resume university study and after 3 years was awarded the Ph.D. in organic chemistry. Karl von Auwers was able to convince him to start an academic career, leading to his habilitation in 1926. He became a close friend of

Karl Ziegler Karl Waldemar Ziegler (26 November 1898 – 12 August 1973) was a German chemist who won the Nobel Prize in Chemistry in 1963, with Giulio Natta, for work on polymers. The Nobel Committee recognized his "excellent work on organometallic compounds ...

, who was also doing his habilitation with Auwers during that time. The successor of

Hans Meerwein Hans Meerwein (May 20, 1879 in Hamburg, Germany – October 24, 1965 in Marburg, Germany) was a German chemist. Several reactions and reagents bear his name, most notably the Meerwein–Ponndorf–Verley reduction, the Wagner–Meerwein rearran ...

, accepted Wittig as lecturer, partly because he was impressed by the new 400-page book on stereochemistry that Wittig had written. In 1931 Wittig married Waltraud Ernst, a colleague from the Auwers working group. The invitation of Karl Fries brought him as professor to the

TU Braunschweig The Technische Universität Braunschweig (unofficially University of Braunschweig – Institute of Technology), commonly referred to as TU Braunschweig, is the oldest ' (comparable to an institute of technology in the American system) in Germany. ...

in 1932. The time in

Braunschweig Braunschweig () or Brunswick ( , from Low German ''Brunswiek'' , Braunschweig dialect: ''Bronswiek'') is a city in Lower Saxony, Germany, north of the Harz Mountains at the farthest navigable point of the river Oker, which connects it to the Nor ...

became more and more problematic as the Nazis tried to get rid of Karl Fries and Wittig showed solidarity with him. After the forced retirement of Fries, in 1937

Hermann Staudinger Hermann Staudinger (; 23 March 1881 – 8 September 1965) was a German organic chemist who demonstrated the existence of macromolecules, which he characterized as polymers. For this work he received the 1953 Nobel Prize in Chemistry. He is also ...

offered Wittig a position at the

University of Freiburg The University of Freiburg (colloquially german: Uni Freiburg), officially the Albert Ludwig University of Freiburg (german: Albert-Ludwigs-Universität Freiburg), is a public university, public research university located in Freiburg im Breisg ...

, partly because he knew Wittig from his book on stereochemistry in which he supported Staudinger's highly criticized theory of macromolecules. The foundations of carbanion chemistry were laid during Wittig's time in Freiburg. In 1944 he succeeded the head of the organic chemistry department

Wilhelm Schlenk Wilhelm may refer to: People and fictional characters * William Charles John Pitcher, costume designer known professionally as "Wilhelm" * Wilhelm (name), a list of people and fictional characters with the given name or surname Other uses * Moun ...

at the

. Most of his scientific work, including the development of the

, was performed during this time in Tübingen. The 1956 appointment of the nearly sixty-year-old Wittig as head of the organic chemistry department at the

University of Heidelberg } Heidelberg University, officially the Ruprecht Karl University of Heidelberg, (german: Ruprecht-Karls-Universität Heidelberg; la, Universitas Ruperto Carola Heidelbergensis) is a public research university in Heidelberg, Baden-Württemberg, ...

as successor of

Karl Freudenberg Karl Johann Freudenberg (29 January 1886 Weinheim, Baden – 3 April 1983 Weinheim) was a German chemist who did early seminal work on the absolute configurations to carbohydrates, terpenes, and steroids, and on the structure of cellulose (first ...

was exceptional even at that time. The newly built department and the close connection to the

BASF BASF Societas Europaea, SE () is a German multinational corporation, multinational chemical company and the List of largest chemical producers, largest chemical producer in the world. Its headquarters is located in Ludwigshafen, Germany. The ...

convinced Wittig to take this opportunity. He worked at the

even after his retirement in 1967 and published papers until 1980. Most of his awards were presented during this time at Heidelberg, such as the honorary doctorate of the

Sorbonne Sorbonne may refer to: * Sorbonne (building), historic building in Paris, which housed the University of Paris and is now shared among multiple universities. *the University of Paris (c. 1150 – 1970) *one of its components or linked institution, ...

in 1956 and the

in 1979.

Work

Wittig's contributions also include the preparation of

phenyllithium Phenyllithium or lithobenzene is an organometallic agent with the empirical formula C6H5Li. It is most commonly used as a metalating agent in organic syntheses and a substitute for Grignard reagents for introducing phenyl groups in organic synthes ...

and the discovery of the 1,2-Wittig rearrangement and the

2,3-Wittig rearrangement The ,3Wittig rearrangement is the transformation of an allylic ether into a homoallylic Alcohol (chemistry), alcohol via a concerted, pericyclic reaction, pericyclic process. Because the reaction is concerted, it exhibits a high degree of ster ...

. Wittig was well known in the chemistry community for being a consummate experimenter and observer of chemical transformations, while caring very little for the

theoretical A theory is a rational type of abstract thinking about a phenomenon, or the results of such thinking. The process of contemplative and rational thinking is often associated with such processes as observational study or research. Theories may be ...

and

mechanistic The mechanical philosophy is a form of natural philosophy which compares the universe to a large-scale mechanism (i.e. a machine). The mechanical philosophy is associated with the scientific revolution of early modern Europe. One of the first expo ...

underpinnings of the work he produced. Georg also has his name on a literature work titled on a compound labelled Colopidalol.

References

* * * *

External links

*. * {{DEFAULTSORT:Wittig, Georg 1897 births 1987 deaths 20th-century German chemists Organic chemists German Nobel laureates Nobel laureates in Chemistry Scientists from Berlin University of Marburg faculty Technical University of Braunschweig faculty University of Freiburg faculty University of Tübingen faculty University of Marburg alumni University of Tübingen alumni Stereochemists Grand Crosses with Star and Sash of the Order of Merit of the Federal Republic of Germany Nazi Party members