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Fusible core injection molding, also known as lost core injection molding, is a specialized
plastic Plastics are a wide range of synthetic or semi-synthetic materials that use polymers as a main ingredient. Their plasticity makes it possible for plastics to be moulded, extruded or pressed into solid objects of various shapes. This adaptab ...
injection molding Injection moulding (U.S. spelling: injection molding) is a manufacturing process for producing parts by injecting molten material into a mould, or mold. Injection moulding can be performed with a host of materials mainly including metals (for ...
process used to mold internal cavities or undercuts that are not possible to mold with demoldable cores. Strictly speaking the term "fusible core injection molding" refers to the use of a
fusible alloy A fusible alloy is a metal alloy capable of being easily fused, i.e. easily meltable, at relatively low temperatures. Fusible alloys are commonly, but not necessarily, eutectic alloys. Sometimes the term "fusible alloy" is used to describe alloys ...
as the core material; when the core material is made from a
soluble In chemistry, solubility is the ability of a substance, the solute, to form a solution with another substance, the solvent. Insolubility is the opposite property, the inability of the solute to form such a solution. The extent of the solubil ...
plastic the process is known as soluble core injection molding. This process is often used for automotive parts, such as
intake manifold In automotive engineering, an inlet manifold or intake manifold (in American English) is the part of an engine that supplies the fuel/air mixture to the cylinders. The word ''manifold'' comes from the Old English word ''manigfeald'' (from the ...
s and brake housings, however it is also used for
aerospace Aerospace is a term used to collectively refer to the atmosphere and outer space. Aerospace activity is very diverse, with a multitude of commercial, industrial and military applications. Aerospace engineering consists of aeronautics and astrona ...
parts,
plumbing Plumbing is any system that conveys fluids for a wide range of applications. Plumbing uses pipes, valves, plumbing fixtures, tanks, and other apparatuses to convey fluids. Heating and cooling (HVAC), waste removal, and potable water delivery ...
parts,
bicycle wheel A bicycle wheel is a wheel, most commonly a wire wheel, designed for a bicycle. A pair is often called a wheelset, especially in the context of ready built "off the shelf" performance-oriented wheels. Bicycle wheels are typically designed ...
s, and
footwear Footwear refers to garments worn on the feet, which typically serves the purpose of protection against adversities of the environment such as wear from ground textures and temperature. Footwear in the manner of shoes therefore primarily serves th ...
... The most common molding materials are glass-filled
nylon 6 Nylon 6 or polycaprolactam is a polymer, in particular semicrystalline polyamide. Unlike most other nylons, nylon 6 is not a condensation polymer, but instead is formed by ring-opening polymerization; this makes it a special case in the comparis ...
and
nylon 66 Nylon 66 (loosely written nylon 6-6, nylon 6/6, nylon 6,6, or nylon 6:6) is a type of polyamide or nylon. It, and nylon 6, are the two most common for textile and plastic industries. Nylon 66 is made of two monomers each containing 6 carbon atoms, ...
. Other materials include unfilled nylons,
polyphenylene sulfide Polyphenylene sulfide (PPS) is an organic polymer consisting of aromatic rings linked by sulfides. Synthetic fiber and textiles derived from this polymer resist chemical and thermal attack. PPS is used in filter fabric for coal boilers, paper ...
, glass-filled
polyaryletherketone Polyaryletherketone (PAEK) is a family of semi-crystalline thermoplastics with high-temperature stability and high mechanical strength whose molecular backbone contains alternately ketone (R-CO-R) and ether groups (R-O-R). The linking group R bet ...
(PAEK), glass-filled
polypropylene Polypropylene (PP), also known as polypropene, is a thermoplastic polymer used in a wide variety of applications. It is produced via chain-growth polymerization from the monomer propylene. Polypropylene belongs to the group of polyolefins and ...
(PP), rigid thermoplastic urethane, and
elastomeric An elastomer is a polymer with viscoelasticity (i.e. both viscosity and elasticity) and with weak intermolecular forces, generally low Young's modulus and high failure strain compared with other materials. The term, a portmanteau of ''elastic p ...
thermoplastic
polyurethane Polyurethane (; often abbreviated PUR and PU) refers to a class of polymers composed of organic chemistry, organic units joined by carbamate (urethane) links. In contrast to other common polymers such as polyethylene and polystyrene, polyurethan ...
...


History

The first patent for this type of molding process was taken out in 1968, however it was rarely used until the 1980s. That is when the
automotive industry The automotive industry comprises a wide range of company, companies and organizations involved in the design, Business development, development, manufacturing, marketing, and selling of motor vehicles. It is one of the world's largest industry ...
took interest in it to develop intake manifolds.


Process

The process consists of three major steps: casting or molding a core, inserting the core into the mold and shooting the mold, and finally removing the molding and melting out the core.


Core

First, a core is molded or
die cast Die casting is a metal casting process that is characterized by forcing molten metal under high pressure into a mold cavity. The mold cavity is created using two hardened tool steel dies which have been machined into shape and work similarly ...
in the shape of the cavity specified for the molded component. It can be made from a
low melting point metal A fusible alloy is a metal alloy capable of being easily fused, i.e. easily meltable, at relatively low temperatures. Fusible alloys are commonly, but not necessarily, eutectic alloys. Sometimes the term "fusible alloy" is used to describe alloys ...
, such as a
tin Tin is a chemical element with the symbol Sn (from la, stannum) and atomic number 50. Tin is a silvery-coloured metal. Tin is soft enough to be cut with little force and a bar of tin can be bent by hand with little effort. When bent, t ...
-
bismuth Bismuth is a chemical element with the Symbol (chemistry), symbol Bi and atomic number 83. It is a post-transition metal and one of the pnictogens, with chemical properties resembling its lighter group 15 siblings arsenic and antimony. Elemental ...
alloy An alloy is a mixture of chemical elements of which at least one is a metal. Unlike chemical compounds with metallic bases, an alloy will retain all the properties of a metal in the resulting material, such as electrical conductivity, ductility, ...
, or a
polymer A polymer (; Greek '' poly-'', "many" + ''-mer'', "part") is a substance or material consisting of very large molecules called macromolecules, composed of many repeating subunits. Due to their broad spectrum of properties, both synthetic a ...
, such as a soluble
acrylate Acrylates (IUPAC: prop-2-enoates) are the salts, esters, and conjugate bases of acrylic acid. The acrylate ion is the anion C H2=CHC OO−. Often, acrylate refers to esters of acrylic acid, the most common member being methyl acrylate. These acry ...
. The polymer has approximately the same melting temperature as the alloy, , however the alloy ratios can be modified to alter the melting point. Another advantage to using a metal core is that multiple smaller cores can be cast with mating plugs and holes so they can be assembled into a final large core... One key in casting metal cores is to make sure they do not contain any
porosity Porosity or void fraction is a measure of the void (i.e. "empty") spaces in a material, and is a fraction of the volume of voids over the total volume, between 0 and 1, or as a percentage between 0% and 100%. Strictly speaking, some tests measure ...
as it will induce flaws into the molded part. In order to minimize porosity the metal may be gravity cast or the molding cavity may be pressurized. Another system slowly rocks the casting dies as the molding cavity fills to "shake" the air bubbles out.. The metal cores can be made from a number of low melting point alloys, with the most common being a mixture of 58% bismuth and 42% tin, which is used for molding nylon 66. One of the main reasons it is used is because it expands as it cools which packs the mold well. Other alloys include tin-lead-silver alloys and tin-lead-antimony alloys. Between these three alloy groups a melting point between 98 and 800 °F (37–425 °C) can be achieved. Polymer cores are not as common as metal cores and are usually only used for moldings that require simple internal surface details. They are usually thick hollow cross-sections that are molded in two halves and are ultrasonically welded together. Their greatest advantage is that they can be molded in traditional injection molding machines that the company already has instead of investing into new die casting equipment and learning how to use it. Because of this polymer core materials are most adventitious for small production runs that cannot justify the added expense of metal cores. Unfortunately it is not as recyclable as the metal alloys used in cores, because 10% new material must be added with the recycled material...


Molding

In the second step, the core is then inserted into the mold. For simple molds this is as simple as inserting the core and closing the dies. However, more complex tools require multiple steps from the programmed robot. For instance, some complex tools can have multiple conventional
side pull Side or Sides may refer to: Geometry * Edge (geometry) of a polygon (two-dimensional shape) * Face (geometry) of a polyhedron (three-dimensional shape) Places * Side (Ainis), a town of Ainis, ancient Thessaly, Greece * Side (Caria), a town of ...
s that mate with the core to add rigidity to the core and reduce the core mass. After the core is loaded and the press closed the plastic is shot.


Melt-out

In the final step, the molded component and core are both demolded and the core is ''melted-out'' from the molding. This is done in a ''hot bath'', via
induction heating Induction heating is the process of heating electrically conductive materials, namely metals or semi-conductors, by electromagnetic induction, through heat transfer passing through an induction coil that creates an electromagnetic field within th ...
, or through a combination of the two. Hot baths usually use a tub filled with
glycol A diol is a chemical compound containing two hydroxyl groups ( groups). An Aliphatic compound, aliphatic diol is also called a glycol. This pairing of functional groups is pervasive, and many subcategories have been identified. The most common ...
or
Lutron Joel Solon Spira (March 1, 1927 – April 8, 2015) was an American inventor, entrepreneur, and business magnate. He invented a version of the light- dimmer switch for use in homes around the United States and led his Lutron Electronics Co ...
, which is a
phenol Phenol (also called carbolic acid) is an aromatic organic compound with the molecular formula . It is a white crystalline solid that is volatile. The molecule consists of a phenyl group () bonded to a hydroxy group (). Mildly acidic, it req ...
-based liquid. The bath temperature is slightly higher than that of the core alloy’s melting point, but not so high that it damages the molding. In typical commercial applications the parts are dipped into the hot bath via an overhead conveyor. The advantage to using a hot bath is that it is simpler than induction heating and it helps cure thermoset moldings. The disadvantage is that it is uneconomically slow at a cycle time of 60 to 90 minutes and it poses environmental cleanup issues. Typically the hot bath solution needs cleaning or replacement every year or every half year when used in combination with induction heating. For thermoplastic moldings induction heating of the core metal is required, otherwise the prolonged heat from a hot bath can warp it. Induction heating reduces the melt-out time to one to three minutes. The disadvantage is that induction heating does not remove all of the core material so it must then be finished off in a hot bath or be brushed out. Another disadvantage is that the induction coils must be custom built for each molding because the coils must be from the part. Finally, induction heating systems cannot be used with moldings that have
brass Brass is an alloy of copper (Cu) and zinc (Zn), in proportions which can be varied to achieve different mechanical, electrical, and chemical properties. It is a substitutional alloy: atoms of the two constituents may replace each other with ...
or steel inserts because the induction heating process can destroy or oxidize the insert.. For complex parts it can be difficult to get all of the core liquid to drain out in either melt-out process. In order to overcome this the parts may be rotated for up to an hour. Liquid core metal collects on the bottom of the heated bath and is usable for a new core.


Equipment

Traditional horizontal
injection molding machine An injection molding machine (also spelled as injection moulding machine in BrE), also known as an injection press, is a machine for manufacturing plastic products by the injection molding process. It consists of two main parts, an ''injectio ...
s have been used since the mid-1980s, however loading and unloading cores are difficult so two
robot A robot is a machine—especially one programmable by a computer—capable of carrying out a complex series of actions automatically. A robot can be guided by an external control device, or the control may be embedded within. Robots may be c ...
s are required. Moreover, the cycle time is quite long, approximately 28 seconds. These problem are overcome by using rotary or shuttle action injection molding machines. These types of machines only require one robot to load and unload cores and have a 30% shorter cycle time. However, these types of machines cost approximately 35% more than horizontal machines, require more space, and require two bottom molds (because one is in the machine during the cycle and the other is being unloaded and loaded with a new core), which adds approximately 40% to the tooling cost. For small parts, horizontal injection molding machines are still used, because the core does not weigh enough to justify the use of a rotary machine.. For four-cylinder manifolds a 500-ton press is required; for a six- to eight-cylinder manifold a 600- to 800-ton press is required.


Advantages and disadvantages

The greatest advantage of this process is its ability to produce single-piece injection moldings with highly complex interior geometries without secondary operations. Similarly shaped objects are usually made from aluminum castings, which can weigh 45% to 75% more than a comparable molding. The tooling also lasts longer than metal casting tooling due to the lack of chemical
corrosion Corrosion is a natural process that converts a refined metal into a more chemically stable oxide. It is the gradual deterioration of materials (usually a metal) by chemical or electrochemical reaction with their environment. Corrosion engine ...
and wear. Other advantages include: *Very good surface quality with no weak areas due to joints or welds *High dimensional accuracy and structural integrity *Not labor-intensive due to the few secondary operations required *Little waste *Inserts can be incorporated Two of the major disadvantages of this process are the high cost and long development time. An automotive part can take four years to develop; two years in the prototype stage and two years to reach production. Not all products take this long, for instance a two-way valve produced by
Johnson Controls Johnson Controls International is an American Irish-domiciled multinational conglomerate headquartered in Cork, Ireland, that produces fire, HVAC, and security equipment for buildings. As of mid-2019, it employed 105,000 people in around 2,0 ...
only took 18 months. The initial cost can be as much as US$8 million to produce a four-cylinder engine manifold. However, computer flow analysis has helped reduce lead time and costs.. One of the difficulties that result from these long development times and high costs is making accurate cores repeatably. This is extremely important because the core is an integral part of the mold, so essentially each shot is into a new mold cavity. Another difficulty is keeping the core from melting when the plastic is shot into the mold, because the plastic is approximately twice the melting temperature of the core material. A third difficulty is the low strength of the core. Hollow plastic cores can collapse if too much pressure is used in the shot plastic. Metal cores (with low melting temperatures) are solid so they cannot collapse, but are only 10% as strong as steel cores so they can distort. This is especially a problem when molding manifolds, because the
waviness Waviness is the measurement of the more widely spaced component of surface texture. It is a broader view of roughness because it is more strictly defined as "the irregularities whose spacing is greater than the roughness sampling length". It can ...
of the core can be detrimental to the airflow within the runners. Another disadvantage is the need for a large space to house the injection molding machines, casting machines, melt-out equipment, and robots. Because of these disadvantages, some moldings that would be made via this process are instead made by injection molding two or more parts in a traditional injection molding machine and then
welding Welding is a fabrication (metal), fabrication process that joins materials, usually metals or thermoplastics, by using high heat to melt the parts together and allowing them to cool, causing Fusion welding, fusion. Welding is distinct from lower ...
them together. This process is less expensive and requires much less capital, however it imparts more design constraints. Because of the design constraints, sometimes parts are made with both processes to gain the advantages of both..


Application

The application of the fusible core process is not limited just to the injection of
thermoplastic A thermoplastic, or thermosoft plastic, is any plastic polymer material that becomes pliable or moldable at a certain elevated temperature and solidifies upon cooling. Most thermoplastics have a high molecular weight. The polymer chains associate ...
s, but with corresponding core alloys also to
thermosetting plastic In materials science, a thermosetting polymer, often called a thermoset, is a polymer that is obtained by irreversibly hardening (" curing") a soft solid or viscous liquid prepolymer (resin). Curing is induced by heat or suitable radiation and ...
molding materials (
duroplast Duroplast is a composite thermosetting plastic, a close relative of Formica and Bakelite. It is a resin plastic reinforced with fibers (either cotton or wool) making it a fiber-reinforced plastic similar to fiberglass. Uses Duroplast was used b ...
). The fusible core process finds application, for example, for injection molded passenger car engine intake manifolds. By modifying the equipment, small molded parts like
valve A valve is a device or natural object that regulates, directs or controls the flow of a fluid (gases, liquids, fluidized solids, or slurries) by opening, closing, or partially obstructing various passageways. Valves are technically fittings ...
s or
pump A pump is a device that moves fluids (liquids or gases), or sometimes slurries, by mechanical action, typically converted from electrical energy into hydraulic energy. Pumps can be classified into three major groups according to the method they u ...
housings can be manufactured, as the manufacture of the fusible cores and the injected parts can be carried out on an injection molding machine.


See also

*
Lost-wax casting Lost-wax casting (also called "investment casting", "precision casting", or ''cire perdue'' which has been adopted into English from the French, ) is the process by which a duplicate metal sculpture (often silver, gold, brass, or bronze) is ...


References


Bibliography

*. *. *


External links


Molding materials for fusible core injection molding
{{Webarchive, url=https://web.archive.org/web/20110721044231/http://www2.basf.us//PLASTICSWEB/displayanyfile?id=0901a5e1800047fd , date=July 21, 2011 Casting (manufacturing) Injection molding