Esbit Brand Hexamine Tablets
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A hexamine fuel tablet (or heat tablet, Esbit) is a form of
solid fuel Solid fuel refers to various forms of solid material that can be burnt to release energy, providing heat and light through the process of combustion. Solid fuels can be contrasted with liquid fuels and gaseous fuels. Common examples of solid fuels ...
in
tablet Tablet may refer to: Medicine * Tablet (pharmacy), a mixture of pharmacological substances pressed into a small cake or bar, colloquially called a "pill" Computing * Tablet computer, a mobile computer that is primarily operated by touching the s ...
form. The tablets burn smokelessly, have a high
energy density In physics, energy density is the amount of energy stored in a given system or region of space per unit volume. It is sometimes confused with energy per unit mass which is properly called specific energy or . Often only the ''useful'' or extract ...
, do not liquefy while burning and leave no
ash Ash or ashes are the solid remnants of fires. Specifically, ''ash'' refers to all non-aqueous, non- gaseous residues that remain after something burns. In analytical chemistry, to analyse the mineral and metal content of chemical samples, ash ...
es. Invented in
Murrhardt Murrhardt is a town in the Rems-Murr district, in Baden-Württemberg, Germany. It is located 12 km east of Backnang, and 18 km southwest of Schwäbisch Hall. The source of the Murr is situated in Murrhardt. Local council (Gemeinder ...
,
Germany Germany,, officially the Federal Republic of Germany, is a country in Central Europe. It is the second most populous country in Europe after Russia, and the most populous member state of the European Union. Germany is situated betwe ...
, in 1936, the main component is
hexamine Hexamethylenetetramine, also known as methenamine, hexamine, or urotropin, is a heterocyclic organic compound with the formula (CH2)6N4. This white crystalline compound is highly soluble in water and polar organic solvents. It has a cage-like s ...
, which was discovered by
Aleksandr Butlerov Alexander Mikhaylovich Butlerov (Алекса́ндр Миха́йлович Бу́тлеров; 15 September 1828 – 17 August 1886) was a Russian chemist, one of the principal creators of the theory of chemical structure (1857–1861 ...
in 1859. Some fuel tablets use
1,3,5-trioxane 1,3,5-Trioxane, sometimes also called trioxane or trioxin, is a chemical compound with molecular formula CHO. It is a white, highly water-soluble solid with a chloroform-like odor. It is a stable cyclic trimer of formaldehyde, and one of the thr ...
as another ingredient. ''Esbit'' is a
genericized trademark A generic trademark, also known as a genericized trademark or proprietary eponym, is a trademark or brand name that, because of its popularity or significance, has become the generic term for, or synonymous with, a general class of products or ...
that people often use to refer to similar products made by other companies. In most countries from the former Soviet bloc, fuel tablets are called ''dry
alcohol Alcohol most commonly refers to: * Alcohol (chemistry), an organic compound in which a hydroxyl group is bound to a carbon atom * Alcohol (drug), an intoxicant found in alcoholic drinks Alcohol may also refer to: Chemicals * Ethanol, one of sev ...
''.


Uses

The tablets are used for cooking by campers, the military and relief organizations. They are often used with disposable metal stoves that are included with
field ration A field ration (combat ration, ration pack, or food packet) is a type of prepackaged or canned military ration. Field rations are distinguished from garrison rations by virtue of being designed for minimal preparation in the field, as well ...
packs. An Esbit
beverage-can stove A beverage-can stove, or pop-can stove, is a do it yourself, ultralight, alcohol-burning portable stove. It is made using parts from two aluminium beverage cans. Basic designs can be relatively simple, but many variations exist. Total weight, i ...
can be made by cutting off the bottom of an aluminium soft drink can, and turning it upside down to support the fuel tablet. A pot can be supported above this with a circle of
chicken wire Chicken wire, or poultry netting, is a mesh of wire commonly used to fence in fowl, such as chickens, in a run or coop. It is made of thin, flexible, galvanized steel wire with hexagonal gaps. Available in 1 inch (about 2.5 cm) diameter, ...
or metal tent pegs. The burning tablets are sensitive to wind, so a simple windscreen should be used, such as a strip of aluminium foil curved in a circle around the pot and stove. If necessary, the fuel tablet can be placed on a rock or on the soil, with a pot supported above it by rocks, but this is less than ideal. Another common use is to provide a relatively safe (see disadvantages below) heat source for model
steam engine A steam engine is a heat engine that performs mechanical work using steam as its working fluid. The steam engine uses the force produced by steam pressure to push a piston back and forth inside a cylinder. This pushing force can be trans ...
s, such as those manufactured by
Wilesco Wilesco is the trade name of German toy company Wilhelm Schröder GmbH & Co. KG, known for manufacturing live steam toys such as steamrollers, traction engines, stationary steam engines, and numerous accessories such as Line shaft, countershafts ...
and
Mamod Mamod is a British toy manufacturer that specializes in manufacturing live steam models. The company was founded in Birmingham by Geoffrey Malins in 1937. The name is a portmanteau of Malins Models. The first models produced were of stationary ...
, and other external combustion engines such as
Stirling engine A Stirling engine is a heat engine that is operated by the cyclic compression and expansion of air or other gas (the ''working fluid'') between different temperatures, resulting in a net conversion of heat energy to mechanical work. More specif ...
s and
pop pop boat A pop-pop boat is a toy with a very simple steam engine without moving parts, typically powered by a candle or vegetable oil burner. The name comes from the noise made by some versions of the boats. Other names are putt-putt boat, crazy boat, fla ...
s.


Advantages and disadvantages

Hexamine is prepared by the reaction of
formaldehyde Formaldehyde ( , ) (systematic name methanal) is a naturally occurring organic compound with the formula and structure . The pure compound is a pungent, colourless gas that polymerises spontaneously into paraformaldehyde (refer to section F ...
and
ammonia Ammonia is an inorganic compound of nitrogen and hydrogen with the formula . A stable binary hydride, and the simplest pnictogen hydride, ammonia is a colourless gas with a distinct pungent smell. Biologically, it is a common nitrogenous was ...
. In an acidic environment hexamine is converted to toxic formaldehyde, where the main hazard for
toxicity Toxicity is the degree to which a chemical substance or a particular mixture of substances can damage an organism. Toxicity can refer to the effect on a whole organism, such as an animal, bacterium, or plant, as well as the effect on a subst ...
is by
ingestion Ingestion is the consumption of a substance by an organism. In animals, it normally is accomplished by taking in a substance through the mouth into the gastrointestinal tract, such as through eating or drinking. In single-celled organisms ingest ...
. Fuel tablets are simple, ultra-lightweight, and more compact than other fuel systems; the entire stove system and fuel can be stored inside a 0.5 litre (one pint) cooking pot. As with trioxane, hexamine has an almost infinite shelf life if stored properly, in a sealed dry container. However, the heat given off cannot be easily adjusted, so water can be boiled, but cooking requiring
simmering Simmering is a food preparation technique by which foods are cooked in hot liquids kept just below the boiling point of water (lower than ) and above poaching temperature (higher than ). To create a steady simmer, a liquid is brought to a boil, ...
is more difficult. Tablets are a powerful stove fuel (30.0 MJ/kg), and are sensitive to wind and dampness. Fuel tablets are expensive and are not as widely available compared to alternatives such as alcohol or petrol, but can use very cheap stoves. Esbit's Safety Data Sheet states combustion can create
formaldehyde Formaldehyde ( , ) (systematic name methanal) is a naturally occurring organic compound with the formula and structure . The pure compound is a pungent, colourless gas that polymerises spontaneously into paraformaldehyde (refer to section F ...
,
ammonia Ammonia is an inorganic compound of nitrogen and hydrogen with the formula . A stable binary hydride, and the simplest pnictogen hydride, ammonia is a colourless gas with a distinct pungent smell. Biologically, it is a common nitrogenous was ...
,
nitrogen oxide Nitrogen oxide may refer to a binary compound of oxygen and nitrogen, or a mixture of such compounds: Charge-neutral *Nitric oxide (NO), nitrogen(II) oxide, or nitrogen monoxide *Nitrogen dioxide (), nitrogen(IV) oxide * Nitrogen trioxide (), or n ...
,
hydrogen cyanide Hydrogen cyanide, sometimes called prussic acid, is a chemical compound with the formula HCN and structure . It is a colorless, extremely poisonous, and flammable liquid that boils slightly above room temperature, at . HCN is produced on an ...
and ingestion may cause
nausea Nausea is a diffuse sensation of unease and discomfort, sometimes perceived as an urge to vomit. While not painful, it can be a debilitating symptom if prolonged and has been described as placing discomfort on the chest, abdomen, or back of the ...
,
vomiting Vomiting (also known as emesis and throwing up) is the involuntary, forceful expulsion of the contents of one's stomach through the mouth and sometimes the Human nose, nose. Vomiting can be the result of ailments like Food-poisoning, foo ...
, gastrointestinal disturbances, and
kidney damage Kidney disease, or renal disease, technically referred to as nephropathy, is damage to or disease of a kidney. Nephritis is an inflammatory kidney disease and has several types according to the location of the inflammation. Inflammation can b ...
. When burned, the chemical oxidation of the fuel yields noxious fumes, which requires cooking foods in a container, such as a pot or pan, with a tight fitting lid. Burned tablets leave a sticky dark
residue Residue may refer to: Chemistry and biology * An amino acid, within a peptide chain * Crop residue, materials left after agricultural processes * Pesticide residue, refers to the pesticides that may remain on or in food after they are applied ...
on the bottom of pots. If tablets are stored or used under damp conditions they can break up while burning and shed burning fragments, though this claim is hard to verify or reproduce. Hexamine is a precursor for the simplest synthesis of the chemical explosive
RDX RDX (abbreviation of "Research Department eXplosive") or hexogen, among other names, is an organic compound with the formula (O2N2CH2)3. It is a white solid without smell or taste, widely used as an explosive. Chemically, it is classified as a n ...
; in many areas its availability is tightly regulated due to this.


See also

*
Metaldehyde Metaldehyde is an organic compound with the chemical formula, formula (C8H16O4). It is used as a pesticide against slugs, snails, and other gastropods. It is the cyclic tetramer of acetaldehyde. Production and properties Metaldehyde is flammable, ...
*
Sterno Sterno is a brand of jellied, denatured alcohol sold in a can and meant to be burned directly in its can. Its primary uses are in food service for buffet heating, in the home for fondue, and as a chafing fuel for heating chafing dishes. Other use ...
*
Firelighter A firelighter is a small, solid fuel tablet for fire making. Firelighters marketed as consumer products may be used to start a wood or coal fire in a fireplace, wood-burning stove, or solid-fuel portable stove. As a hazardous material, firelig ...


References


External links


Esbit Compagnie GmbH website
{{DEFAULTSORT:Hexamine Fuel Tablet Fuels Camping equipment Solid fuels