Enstatite is a mineral; the magnesium endmember of the

pyroxene The pyroxenes (commonly abbreviated Px) are a group of important rock-forming inosilicate minerals found in many igneous and metamorphic rocks. Pyroxenes have the general formula , where X represents ions of calcium (Ca), sodium (Na), iron ( ...

silicate mineral Silicate minerals are rock-forming minerals made up of silicate groups. They are the largest and most important class of minerals and make up approximately 90 percent of Earth's crust. In mineralogy, the crystalline forms of silica (silicon dio ...

series enstatite (MgSiO₃) – ferrosilite (FeSiO₃). The magnesium rich members of the

solid solution A solid solution, a term popularly used for metals, is a homogeneous mixture of two compounds in solid state and having a single crystal structure. Many examples can be found in metallurgy, geology, and solid-state chemistry. The word "solutio ...

series are common rock-forming

mineral In geology and mineralogy, a mineral or mineral species is, broadly speaking, a solid substance with a fairly well-defined chemical composition and a specific crystal structure that occurs naturally in pure form.John P. Rafferty, ed. (2011): Mi ...

s found in

igneous Igneous rock ( ), or magmatic rock, is one of the three main rock types, the others being sedimentary and metamorphic. Igneous rocks are formed through the cooling and solidification of magma or lava. The magma can be derived from partial ...

and

metamorphic Metamorphic rocks arise from the transformation of existing rock to new types of rock in a process called metamorphism. The original rock (protolith) is subjected to temperatures greater than and, often, elevated pressure of or more, causi ...

rocks. The intermediate composition, , has historically been known as hypersthene, although this name has been formally abandoned and replaced by orthopyroxene. When determined petrographically or chemically the composition is given as relative proportions of enstatite (En) and ferrosilite (Fs) (e.g., En₈₀Fs₂₀).

Polymorphs and varieties

Most natural

crystal A crystal or crystalline solid is a solid material whose constituents (such as atoms, molecules, or ions) are arranged in a highly ordered microscopic structure, forming a crystal lattice that extends in all directions. In addition, macros ...

s are

orthorhombic In crystallography, the orthorhombic crystal system is one of the 7 crystal systems. Orthorhombic Lattice (group), lattices result from stretching a cubic crystal system, cubic lattice along two of its orthogonal pairs by two different factors, res ...

(

space group In mathematics, physics and chemistry, a space group is the symmetry group of a repeating pattern in space, usually in three dimensions. The elements of a space group (its symmetry operations) are the rigid transformations of the pattern that ...

P''bca'') although three polymorphs are known. The high temperature, low pressure polymorphs are protoenstatite and protoferrosilite (also orthorhombic, space group P''bcn'') while the low temperature forms, clinoenstatite and clinoferrosilite, are

monoclinic In crystallography, the monoclinic crystal system is one of the seven crystal systems. A crystal system is described by three Vector (geometric), vectors. In the monoclinic system, the crystal is described by vectors of unequal lengths, as in t ...

(space group P2''₁/c''). Weathered enstatite with a small amount of iron takes on a submetallic luster and a bronze-like color. This material is termed bronzite, although it is more correctly called altered enstatite. Bronzite and hypersthene were known long before enstatite, which was first described by G. A. Kenngott in 1855. Enstatite-pas-146b

An emerald-green variety of enstatite is called chrome-enstatite and is cut as a

gemstone A gemstone (also called a fine gem, jewel, precious stone, semiprecious stone, or simply gem) is a piece of mineral crystal which, when cut or polished, is used to make jewellery, jewelry or other adornments. Certain Rock (geology), rocks (such ...

. The green color is caused by traces of

chromium Chromium is a chemical element; it has Symbol (chemistry), symbol Cr and atomic number 24. It is the first element in Group 6 element, group 6. It is a steely-grey, Luster (mineralogy), lustrous, hard, and brittle transition metal. Chromium ...

, hence the varietal name. In addition, black, chatoyant hypersthene and brownish bronzite are also used as semi-precious gemstones.

Identification

Enstatite and the other orthorhombic pyroxenes are distinguished from those of the monoclinic series by their optical characteristics, such as straight extinction, much weaker double refraction and stronger

pleochroism Pleochroism is an optical phenomenon in which a substance has different colors when observed at different angles, especially with Polarization (waves), polarized light. Etymology The roots of the word are from Greek (). It was first made compou ...

. They also have a prismatic

cleavage Cleavage may refer to: Science * Cleavage (crystal), the way in which a crystal or mineral tends to split * Cleavage (embryo), the division of cells in an early embryo * Cleavage (geology), foliation of rock perpendicular to stress, a result of ...

that is perfect in two directions at 90 degrees. Enstatite is white, gray, greenish, or brown in color; its

hardness In materials science, hardness (antonym: softness) is a measure of the resistance to plastic deformation, such as an indentation (over an area) or a scratch (linear), induced mechanically either by Pressing (metalworking), pressing or abrasion ...

is 5–6 on the

Mohs scale The Mohs scale ( ) of mineral hardness is a qualitative ordinal scale, from 1 to 10, characterizing scratch resistance of minerals through the ability of harder material to scratch softer material. The scale was introduced in 1812 by the Ger ...

, and its

specific gravity Relative density, also called specific gravity, is a dimensionless quantity defined as the ratio of the density (mass of a unit volume) of a substance to the density of a given reference material. Specific gravity for solids and liquids is nea ...

is 3.2–3.3. This prismatic form is used in gemstones, and for academic purposes.

Occurrence

Isolated crystals are rare, but orthopyroxene is an essential constituent of various types of

igneous rock Igneous rock ( ), or magmatic rock, is one of the three main rock types, the others being sedimentary and metamorphic. Igneous rocks are formed through the cooling and solidification of magma or lava. The magma can be derived from partial ...

s and

metamorphic rock Metamorphic rocks arise from the transformation of existing rock to new types of rock in a process called metamorphism. The original rock ( protolith) is subjected to temperatures greater than and, often, elevated pressure of or more, caus ...

s. Magnesian orthopyroxene occurs in plutonic rocks such as

gabbro Gabbro ( ) is a phaneritic (coarse-grained and magnesium- and iron-rich), mafic intrusive igneous rock formed from the slow cooling magma into a holocrystalline mass deep beneath the Earth's surface. Slow-cooling, coarse-grained gabbro is ch ...

(norite) and

diorite Diorite ( ) is an intrusive rock, intrusive igneous rock formed by the slow cooling underground of magma (molten rock) that has a moderate content of silica and a relatively low content of alkali metals. It is Intermediate composition, inter ...

. It may form small idiomorphic phenocrysts and also groundmass grains in volcanic rocks such as

basalt Basalt (; ) is an aphanite, aphanitic (fine-grained) extrusive igneous rock formed from the rapid cooling of low-viscosity lava rich in magnesium and iron (mafic lava) exposed at or very near the planetary surface, surface of a terrestrial ...

andesite Andesite () is a volcanic rock of intermediate composition. In a general sense, it is the intermediate type between silica-poor basalt and silica-rich rhyolite. It is fine-grained (aphanitic) to porphyritic in texture, and is composed predomina ...

, and

dacite Dacite () is a volcanic rock formed by rapid solidification of lava that is high in silica and low in alkali metal oxides. It has a fine-grained (aphanitic) to porphyritic texture and is intermediate in composition between andesite and rhyolite. ...

. Enstatite, close to En₉₀Fs₁₀ in composition, is an essential mineral in typical

peridotite Peridotite ( ) is a dense, coarse-grained igneous rock consisting mostly of the silicate minerals olivine and pyroxene. Peridotite is ultramafic, as the rock contains less than 45% silica. It is high in magnesium (Mg2+), reflecting the high pr ...

and

pyroxenite Pyroxenite is an ultramafic igneous rock consisting essentially of minerals of the pyroxene group, such as augite, diopside, hypersthene, bronzite or enstatite. Pyroxenites are classified into clinopyroxenites, orthopyroxenites, and the w ...

of the

Earth's mantle Earth's mantle is a layer of silicate mineral, silicate rock between the Earth's crust, crust and the Earth's outer core, outer core. It has a mass of and makes up 67% of the mass of Earth. It has a thickness of making up about 46% of Earth's ...

Xenolith A xenolith ("foreign rock") is a rock (geology), rock fragment (Country rock (geology), country rock) that becomes enveloped in a larger rock during the latter's development and solidification. In geology, the term ''xenolith'' is almost exclusi ...

s of peridotite are common in

kimberlite Kimberlite is an igneous rock and a rare variant of peridotite. It is most commonly known as the main host matrix for diamonds. It is named after the town of Kimberley, Northern Cape, Kimberley in South Africa, where the discovery of an 83.5-Car ...

and in some basalt. Measurements of the

calcium Calcium is a chemical element; it has symbol Ca and atomic number 20. As an alkaline earth metal, calcium is a reactive metal that forms a dark oxide-nitride layer when exposed to air. Its physical and chemical properties are most similar to it ...

aluminum Aluminium (or aluminum in North American English) is a chemical element; it has chemical symbol, symbol Al and atomic number 13. It has a density lower than that of other common metals, about one-third that of steel. Aluminium has ...

, and

contents of enstatite in these xenoliths have been crucial in reconstructing the depths from which the xenoliths were plucked by the ascending magmas. Orthopyroxene is an important constituent of some metamorphic rocks such as granulite. Orthopyroxene near pure enstatite in composition occurs in some metamorphosed serpentines. Large crystals, a foot in length and mostly altered to steatite, were found in 1874 in the

apatite Apatite is a group of phosphate minerals, usually hydroxyapatite, fluorapatite and chlorapatite, with high concentrations of Hydroxide, OH−, Fluoride, F− and Chloride, Cl− ion, respectively, in the crystal. The formula of the admixture of ...

veins traversing

mica Micas ( ) are a group of silicate minerals whose outstanding physical characteristic is that individual mica crystals can easily be split into fragile elastic plates. This characteristic is described as ''perfect basal cleavage''. Mica is co ...

schist Schist ( ) is a medium-grained metamorphic rock generally derived from fine-grained sedimentary rock, like shale. It shows pronounced ''schistosity'' (named for the rock). This means that the rock is composed of mineral grains easily seen with a l ...

and

hornblende Hornblende is a complex silicate minerals#Inosilicates, inosilicate series of minerals. It is not a recognized mineral in its own right, but the name is used as a general or field term, to refer to a dark amphibole. Hornblende minerals are common ...

-schist at the apatite mine of Kjørstad, near Brevik in southern

Norway Norway, officially the Kingdom of Norway, is a Nordic countries, Nordic country located on the Scandinavian Peninsula in Northern Europe. The remote Arctic island of Jan Mayen and the archipelago of Svalbard also form part of the Kingdom of ...

. Enstatite is a common mineral in meteorites.

Crystal A crystal or crystalline solid is a solid material whose constituents (such as atoms, molecules, or ions) are arranged in a highly ordered microscopic structure, forming a crystal lattice that extends in all directions. In addition, macros ...

s have been found in stony and iron

meteorite A meteorite is a rock (geology), rock that originated in outer space and has fallen to the surface of a planet or Natural satellite, moon. When the original object enters the atmosphere, various factors such as friction, pressure, and chemical ...

s, including one that fell at Breitenbach in the

Ore Mountains The Ore Mountains (, or ; ) lie along the Czech–German border, separating the historical regions of Bohemia in the Czech Republic and Saxony in Germany. The highest peaks are the Klínovec in the Czech Republic (German: ''Keilberg'') at ab ...

Bohemia Bohemia ( ; ; ) is the westernmost and largest historical region of the Czech Republic. In a narrow, geographic sense, it roughly encompasses the territories of present-day Czechia that fall within the Elbe River's drainage basin, but historic ...

. In some meteorites, together with

olivine The mineral olivine () is a magnesium iron Silicate minerals, silicate with the chemical formula . It is a type of Nesosilicates, nesosilicate or orthosilicate. The primary component of the Earth's upper mantle (Earth), upper mantle, it is a com ...

it forms the bulk of the material; it can occur in small spherical masses, or

chondrule A chondrule (from Ancient Greek χόνδρος ''chondros'', grain) is a round grain found in a chondrite. Chondrules form as molten or partially molten droplets in space before being Accretion (astrophysics), accreted to their parent asteroids ...

s, with an internal radiated structure.

In space

Enstatite is one of the few silicate minerals that have been observed in crystalline form outside the

Solar System The Solar SystemCapitalization of the name varies. The International Astronomical Union, the authoritative body regarding astronomical nomenclature, specifies capitalizing the names of all individual astronomical objects but uses mixed "Sola ...

, particularly around evolved stars and

planetary nebulae A planetary nebula is a type of emission nebula consisting of an expanding, glowing shell of ionization, ionized gas ejected from red giant stars late in their lives. The term "planetary nebula" is a misnomer because they are unrelated to pla ...

such as

NGC 6302 NGC 6302 (also known as the Bug Nebula, Butterfly Nebula, or Caldwell 69) is a bipolar planetary nebula in the constellation Scorpius. The structure in the nebula is among the most complex ever seen in planetary nebulae. The spectrum of Butte ...

. Enstatite is thought to be one of the early stages for the formation of crystalline silicates in space. Many correlations have been noted between the occurrence of the mineral and the structure of the object around which it has been observed. Enstatite is thought to be a main component of the E-type asteroids.H. U. Keller, et al. - E-Type Asteroid (2867) Steins as Imaged by OSIRIS on Board Rosetta - Science 8 January 2010: Vol. 327. no. 5962, pp. 190 - 193
The Hungaria asteroids are the main examples in the Solar System. A layer of

quartz Quartz is a hard, crystalline mineral composed of silica (silicon dioxide). The Atom, atoms are linked in a continuous framework of SiO4 silicon–oxygen Tetrahedral molecular geometry, tetrahedra, with each oxygen being shared between two tet ...

and enstatite clouds above an

iron Iron is a chemical element; it has symbol Fe () and atomic number 26. It is a metal that belongs to the first transition series and group 8 of the periodic table. It is, by mass, the most common element on Earth, forming much of Earth's o ...

cloud deck are thought to exist in the atmosphere of the young

brown dwarf Brown dwarfs are substellar objects that have more mass than the biggest gas giant planets, but less than the least massive main sequence, main-sequence stars. Their mass is approximately 13 to 80 Jupiter mass, times that of Jupiter ()not big en ...

2M2224-0158.

References

*Deer, W. A., Howie, R. A., and Zussman, J. (1992). '' An introduction to the rock-forming minerals (2nd ed.)''. Harlow: Longman {{Commons category Inosilicates Magnesium minerals Iron(II) minerals Pyroxene group Orthorhombic minerals Minerals in space group 61 Blendes

Polymorphs and varieties

Identification

Occurrence

In space

See also

References