Decamethylzirconocene Dichloride
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Decamethylzirconocene dichloride is an
organozirconium compound Organozirconium chemistry is the science of exploring the properties, structure, and reactivity of organozirconium compounds, which are organometallic compounds containing chemical bonds between carbon and zirconium. Organozirconium compounds have ...
with the formula Cp*2ZrCl2 (where Cp* is C5(CH3)5, derived from
pentamethylcyclopentadiene 1,2,3,4,5-Pentamethylcyclopentadiene is a cyclic diene with the formula C5Me5H (Me = CH3). 1,2,3,4,5-Pentamethylcyclopentadiene is the precursor to the ligand ''1,2,3,4,5-pentamethylcyclopentadienyl'', which is often denoted Cp* (C5Me5) and read ...
). It is a pale yellow, moisture sensitive solid that is soluble in nonpolar organic solvents. The complex has been the subject of extensive research. It is a precursor to many other complexes, including the
dinitrogen complex Transition metal dinitrogen complexes are coordination compounds that contain transition metals as ion centers the dinitrogen molecules (N2) as ligands. Historical background Transition metal complexes of N2 have been studied since 1965 when ...
p*2Zrsub>2(N2)3). It is a precatalyst for the polymerization of
ethylene Ethylene (IUPAC name: ethene) is a hydrocarbon which has the formula or . It is a colourless, flammable gas with a faint "sweet and musky" odour when pure. It is the simplest alkene (a hydrocarbon with carbon-carbon double bonds). Ethylene i ...
and
propylene Propylene, also known as propene, is an unsaturated organic compound with the chemical formula CH3CH=CH2. It has one double bond, and is the second simplest member of the alkene class of hydrocarbons. It is a colorless gas with a faint petrole ...
.


Further reading

* *{{cite journal , first= U., last= Rosenthal, title = What Do Titano- and Zirconocenes Do with Diynes and Polyynes? , journal = Chemical Reviews, volume = 33 , year = 2000 , issue= 2, pages = 119–129 , doi = 10.1021/ar9900109, pmid= 10673320, display-authors=etal


References

Organozirconium compounds Metallocenes Metal halides Chloro complexes Cyclopentadienyl complexes Zirconium(IV) compounds