Dishwashing Liquid
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Dishwashing liquid (washing-up liquid or fairy liquid in
British English British English is the set of Variety (linguistics), varieties of the English language native to the United Kingdom, especially Great Britain. More narrowly, it can refer specifically to the English language in England, or, more broadly, to ...
), also known as dishwashing soap, dish detergent, or dish soap, is a
detergent A detergent is a surfactant or a mixture of surfactants with Cleanliness, cleansing properties when in Concentration, dilute Solution (chemistry), solutions. There are a large variety of detergents. A common family is the alkylbenzene sulfonate ...
used in dishwashing. Dishwashing detergent for dishwashers comes in various forms such as cartridges, gels, liquids, packs, powder, and tablets.'''' It is usually a highly-
foam Foams are two-phase materials science, material systems where a gas is dispersed in a second, non-gaseous material, specifically, in which gas cells are enclosed by a distinct liquid or solid material. Note, this source focuses only on liquid ...
y mixture of
surfactant Surfactants are chemical compounds that decrease the surface tension or interfacial tension between two liquids, a liquid and a gas, or a liquid and a solid. The word ''surfactant'' is a Blend word, blend of "surface-active agent", coined in ...
s with low skin irritation that consumers primarily use for washing glasses, plates, cutlery, and cooking utensils. In addition to its primary use, dishwashing liquid is also used for various informal applications, like creating bubbles, clothes washing, and cleaning off wildlife affected by oil spills. Dishwashing liquid has long existed in various compositions and under different usage conditions. Currently, most dishwashing liquid functions best with hot water. However, there are some special dishwashing liquids designed to work well with cold water or seawater.


History

Before the invention of detergents in Germany during World War I, consumers used
washing soda Sodium carbonate (also known as washing soda, soda ash, sal soda, and soda crystals) is the inorganic compound with the formula and its various hydrates. All forms are white, odourless, water-soluble salts that yield alkaline solutions in water ...
(sodium carbonate) for dishwashing. The manufacture of liquid detergent for dishwashing began in the middle of the 20th century. Dishwashing detergent production started in the United States in the 1930s–1940s. Teepol, the first dishwashing detergent in Europe, commenced production in 1942. As of 2005, global retail sales of dishwashing detergent totaled nearly US$10 billion.


Composition and Safety

Dishwashing liquid may contain
bleach Bleach is the generic name for any chemical product that is used industrially or domestically to remove color from (i.e. to whiten) fabric or fiber (in a process called bleaching) or to disinfect after cleaning. It often refers specifically t ...
,
enzyme An enzyme () is a protein that acts as a biological catalyst by accelerating chemical reactions. The molecules upon which enzymes may act are called substrate (chemistry), substrates, and the enzyme converts the substrates into different mol ...
s, and rinsing aids.'''' The main ingredient is water; the main active ingredients are detergents. Dishwashing liquid has detergent rather than soap because the soaps would react with any minerals in the water to form
soap scum Soap scum or lime soap is the white solid composed of calcium stearate, magnesium stearate, and similar alkaline earth metal derivatives of fatty acids. These materials result from the addition of soap and other anionic surfactants to hard water ...
. There are other thickening and stabilizing agents in the dishwashing liquid as well. Hand dishwashing detergents utilize surfactants to play the primary role in cleaning. The reduced
surface tension Surface tension is the tendency of liquid surfaces at rest to shrink into the minimum surface area possible. Surface tension (physics), tension is what allows objects with a higher density than water such as razor blades and insects (e.g. Ge ...
of water and increased solubility of modern surfactant mixtures allow water to run off dishes very quickly. Additionally, surfactants remove grease and food particles to aid in cleaning dishes. They may also provide foam. Other ingredients may include hydrotropes, salts, preservatives, fragrances, antibacterial ingredients, and dyes. Preservatives prevent the proliferation of microorganisms within the liquid. Antibacterial ingredients make it difficult for bacteria to survive on surfaces. Some alternatives for dishwashing detergents may be homemade, using ingredients such as
borax The BORAX Experiments were a series of safety experiments on boiling water nuclear reactors conducted by Argonne National Laboratory in the 1950s and 1960s at the National Reactor Testing Station in eastern Idaho.
,
essential oil An essential oil is a concentrated hydrophobic liquid containing volatile (easily evaporated at normal temperatures) chemical compounds from plants. Essential oils are also known as volatile oils, ethereal oils, aetheroleum, or simply as the ...
,
eucalyptus oil Eucalyptus oil is the generic name for distilled oil from the leaves of ''Eucalyptus'', a genus of the plant family Myrtaceae, mostly native to Australia but cultivated worldwide. Eucalyptus oil has a history of wide application, as a pharmace ...
, leftover cooking oil, and bar soap, among others. Items that can be damaged by certain dishwashing liquids (especially with the use of hot water or when put into a
dishwasher A dishwasher is a machine that is used to clean dishware, cookware, and cutlery automatically. Unlike dishwashing, manual dishwashing, which relies on physical scrubbing to remove soiling, the mechanical dishwasher cleans by spraying hot wat ...
) include
household silver Household silver or silverware (the silver, the plate, or silver service) includes tableware, cutlery, and other household items made of sterling silver, silver gilt, Britannia silver, or Sheffield plate silver. Silver is sometimes bought in ...
, fine glassware, gold-leafed objects, disposable plastics, as well as objects made of brass, bronze,
cast iron Cast iron is a class of iron–carbon alloys with a carbon content of more than 2% and silicon content around 1–3%. Its usefulness derives from its relatively low melting temperature. The alloying elements determine the form in which its car ...
, pewter, tin, or wood.'''' Dishwashing liquid components are also harder to rinse off from rough surfaces than smooth surfaces, increasing the chance of accidental ingestion.' In 2010, the United States FDA raised health concerns over
triclosan Triclosan (sometimes abbreviated as TCS) is an antibacterial and antifungal agent present in some consumer products, including toothpaste, soaps, detergents, toys, and surgical cleaning treatments. It is similar in its uses and mechanism of act ...
, an
antibacterial An antibiotic is a type of antimicrobial substance active against bacteria. It is the most important type of antibacterial agent for fighting bacterial infections, and antibiotic medications are widely used in the treatment and prevention ...
substance used in some dish liquids.' Elsewhere, triclosan has been found to create problems at wastewater treatment plants, whereby it can "sabotage some sludge-processing microbes and promote drug resistance in others."' As of 2014, at least one US state has banned triclosan in dishwashing liquids.' Some dishwashing products contain phosphates. Phosphates make dishes cleaner but can also cause
harmful algal bloom A harmful algal bloom (HAB), or excessive algae growth, sometimes called a red tide in marine environments, is an algal bloom that causes negative impacts to other organisms by production of natural algae-produced toxins, water deoxygenation, ...
as the
wastewater Wastewater (or waste water) is water generated after the use of freshwater, raw water, drinking water or saline water in a variety of deliberate applications or processes. Another definition of wastewater is "Used water from any combination of do ...
goes back to the natural environment. Because of this, many places have banned this component. Phosphates can also cause harmful health effects upon skin contact. Many dishwashing liquids contain
perfume Perfume (, ) is a mixture of fragrance, fragrant essential oils or aroma compounds (fragrances), Fixative (perfumery), fixatives and solvents, usually in liquid form, used to give the human body, animals, food, objects, and living-spaces an agre ...
which can cause irritant or
allergic contact dermatitis Allergic contact dermatitis (ACD) is a form of contact dermatitis that is the manifestation of an allergic response caused by contact with a substance; the other type being irritant contact dermatitis (ICD). Although less common than ICD, ACD ...
. It can also cause
hand eczema Hand eczema presents on the palms and soles, and may sometimes be difficult or impossible to differentiate from atopic dermatitis, allergic contact dermatitis, and psoriasis, which also commonly involve the hands. Even a biopsy of all these cond ...
. Those with sensitive skin could use hypoallergenic gloves to avoid direct contact with the liquids. Recent research has found that
Blackcurrant The blackcurrant (''Ribes nigrum''), also known as black currant or cassis, is a deciduous shrub in the family Grossulariaceae grown for its edible berries. It is native to temperate parts of central and northern Europe and northern Asia, w ...
seeds are helpful for lessening the effects of allergies, due to its
hydrophobicity In chemistry, hydrophobicity is the chemical property of a molecule (called a hydrophobe) that is seemingly intermolecular force, repelled from a mass of water. In contrast, hydrophiles are attracted to water. Hydrophobic molecules tend to b ...
. Surfactants that are anionic also showed promising results in preventing skin irritation. Accidental ingestion of rinse aids (components within dishwashing tablets) can lead to vomiting.''''


Surfactant design

There has been comparisons of different surfactants that reduce the surface tension of water to determine the most efficient dishwashing liquid. Lowering of surface tension helps with the cleaning processes. A study showed that anionic surfactant combined with non-ionic surfactant worked better than anionic and amphoteric surfactants combined. Another study found that cationic and anionic surfactants combined worked better than non-ionic and anionic surfactants combined. Anionic and amphoteric surfactants combined are the least effective out of the three.


Primary uses

Dishwashing liquid is primarily for removing food from dirty dishes and tableware.'''' Consumers usually scrape heavy soil (large food particles) from the dishes before using dishwashing liquid.''''


Hand dishwashing

Consumers handwash dishes in the absence of a dishwashing machine and when large "hard-to-clean" items are present, or through preference.


Automatic dishwashing

Automatic dishwashing is when consumers use a dishwashing machine or other apparatus. It is generally for convenience, sanitation, or personal preference. The cleaning is less reliant on the detergent's surfactants and more so on the machine's hot water as well as the detergent's builders, bleach, and enzymes. Automatic dishwashing detergents' surfactants generally have less foam to avoid disrupting the machine.


Informal uses

''
Reader's Digest ''Reader's Digest'' is an American general-interest family magazine, published ten times a year. Formerly based in Chappaqua, New York, it is now headquartered in midtown Manhattan. The magazine was founded in 1922 by DeWitt Wallace and his wi ...
'' notes it may be used to kill ants and weeds, help spread water-borne fertilizer, and wash human hair.'' Good Housekeeping'' says it can be mixed with vinegar to attract and drown fruit flies. Dishwashing detergent can be used to clean both mirrors and windows. * Twibright Labs published Pling, an open-source general-purpose cleaner for glazed, plastic, chrome, and stainless steel bathroom and kitchen surfaces. It uses dishwashing liquid as one of the active ingredients. * Dishwashing liquid with water and additional ingredients such as
glycerin Glycerol () is a simple triol compound. It is a colorless, odorless, sweet-tasting, viscous liquid. The glycerol backbone is found in lipids known as glycerides. It is also widely used as a sweetener in the food industry and as a humectant in pha ...
and
sugar Sugar is the generic name for sweet-tasting, soluble carbohydrates, many of which are used in food. Simple sugars, also called monosaccharides, include glucose Glucose is a sugar with the Chemical formula#Molecular formula, molecul ...
produces a bubble-blowing solution. * Dishwashing liquid can clean delicate clothing fabrics such as hosiery and lingerie. * Dishwashing liquid in a dilute solution can make
decal A decal (, , ) or transfer is a plastic, cloth, paper, or ceramic substrate that has printed on it a pattern or image that can be moved to another surface upon contact, usually with the aid of heat or water. The word is short for '' decalc ...
s and vinyl graphics easier to position when applying. * In industry, some use dishwashing liquid for inspecting equipment under pressure for leaks, such as
propane Propane () is a three-carbon chain alkane with the molecular formula . It is a gas at standard temperature and pressure, but becomes liquid when compressed for transportation and storage. A by-product of natural gas processing and petroleum ref ...
fittings. They can also use dishwashing liquid for inspecting
pneumatic Pneumatics (from Greek 'wind, breath') is the use of gas or pressurized air in mechanical systems. Pneumatic systems used in Industrial sector, industry are commonly powered by compressed air or compressed inert gases. A centrally located a ...
tire A tire (North American English) or tyre (Commonwealth English) is a ring-shaped component that surrounds a Rim (wheel), wheel's rim to transfer a vehicle's load from the axle through the wheel to the ground and to provide Traction (engineeri ...
s for flats, as well as for
quality assurance Quality assurance (QA) is the term used in both manufacturing and service industries to describe the systematic efforts taken to assure that the product(s) delivered to customer(s) meet with the contractual and other agreed upon performance, design ...
during the installation process, and as a mounting bead lubricant. * Dishwashing liquid can act as an ingredient in making homemade garden pest deterrents.
Oregon State University Oregon State University (OSU) is a Public university, public Land-grant university, land-grant research university in Corvallis, Oregon, United States. OSU offers more than 200 undergraduate degree programs and a variety of graduate and doctor ...
's
Cooperative Extension Service The Cooperative State Research, Education, and Extension Service (CSREES) was an Extension agency within the U.S. Department of Agriculture (USDA), part of the executive branch of the federal government. The 1994 Department Reorganization Act ...
notes the use of dishwashing liquid to get rid of spider mites. Dish soap can also deter aphids. In some instances, the dish soap may be toxic to plant leaves and cause them to "burn". The University of Georgia noted the use of soap or dish detergent to help spread pesticide on plants, however, the institution did not recommend this method. * A solution of dishwashing liquid and water can remove coffee, tea, olive oil, soda and fruit juice stains from fabrics. One dishwashing liquid brand can remove stains from white or lightly colored cloth napkins. * Dishwashing liquid can treat
birds Birds are a group of warm-blooded vertebrates constituting the class (biology), class Aves (), characterised by feathers, toothless beaked jaws, the Oviparity, laying of Eggshell, hard-shelled eggs, a high Metabolism, metabolic rate, a fou ...
in
oil spill An oil spill is the release of a liquid petroleum hydrocarbon into the environment, especially the marine ecosystem, due to human activity, and is a form of pollution. The term is usually given to marine oil spills, where oil is released into th ...
s.


Market share

Currently, market research companies like Euromonitor and Grand View Research collect data on different brands' market share. Grand View Research gives the general global market trend. For example, for 2021, the company reported dishwashing detergent market share to be at 17.98 billion US dollars worldwide. Euromonitor International collects market trends of many big brands like
Procter and Gamble The Procter & Gamble Company (P&G) is an American multinational consumer goods corporation headquartered in Cincinnati, Ohio. It was founded in 1837 by William Procter and James Gamble. It specializes in a wide range of personal health/cons ...
,
Colgate-Palmolive The Colgate-Palmolive Company, commonly known as Colgate-Palmolive, is an American multinational corporation, multinational consumer products company headquartered on Park Avenue in Midtown Manhattan, New York City. The company specializes in ...
,
Henkel Henkel AG & Co. KGaA, commonly known as Henkel, is a German multinational chemical and consumer goods company headquartered in Düsseldorf, Germany. Founded in 1876, the DAX company is organized into two globally operating business units (Cons ...
,
Reckitt Benckiser Reckitt Benckiser Group PLC, currently branded as Reckitt, formerly known as Reckitt Benckiser, is a British multinational consumer goods company headquartered in Slough, United Kingdom. It is a producer of health, hygiene and nutrition prod ...
,
Unilever Unilever PLC () is a British multinational consumer packaged goods company headquartered in London, England. It was founded on 2 September 1929 following the merger of Dutch margarine producer Margarine Unie with British soap maker Lever B ...
,
Ajax Ajax may refer to: Greek mythology and tragedy * Ajax the Great, a Greek mythological hero, son of King Telamon and Periboea * Ajax the Lesser, a Greek mythological hero, son of Oileus, the king of Locris * Ajax (play), ''Ajax'' (play), by the an ...
.'''' For example, according to Euromonitor International in 2013, Reckitt Benckiser held the highest retail value share percentages in nine countries:'''' Italy (31%), Spain (29%); with Finish brand: Australia (38%), New Zealand (38%), Austria (32%), Ireland (29%), and
Israel Israel, officially the State of Israel, is a country in West Asia. It Borders of Israel, shares borders with Lebanon to the north, Syria to the north-east, Jordan to the east, Egypt to the south-west, and the Mediterranean Sea to the west. Isr ...
(27%); Denmark (30%) with Neophos brand; and Portugal (22%) with Calgonit brand.


See also

* Dishwasher detergent *
Cleaning agent Cleaning agents or hard-surface cleaners are substances (usually liquids, powders, sprays, or granules) used to remove dirt, including dust, stains, foul odors, and clutter on surfaces. Purposes of cleaning agents include health, beauty, removing ...
** List of cleaning agents ** List of cleaning products *
Soap Soap is a salt (chemistry), salt of a fatty acid (sometimes other carboxylic acids) used for cleaning and lubricating products as well as other applications. In a domestic setting, soaps, specifically "toilet soaps", are surfactants usually u ...
* Green cleaning *
Washing Washing is a method of cleaning, usually with water and soap or detergent. Regularly washing and then rinsing both body and clothing is an essential part of good hygiene and health. Often people use soaps and detergents to assist in the emulsific ...


References


Further reading

* * *


External links

* * * {{Authority control Cleaning products Dishwashing