Copaíba
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Copaiba is an
oleoresin Oleoresins are semi-solid extracts composed of resin and essential or fatty oil, obtained by evaporation of the solvents used for their production. The oleoresin of conifers is known as crude turpentine or gum turpentine, which consists of oil o ...
obtained from the trunk of several pinnate-leaved South American leguminous trees (
genus Genus (; : genera ) is a taxonomic rank above species and below family (taxonomy), family as used in the biological classification of extant taxon, living and fossil organisms as well as Virus classification#ICTV classification, viruses. In bino ...
''
Copaifera ''Copaifera'' is a genus of tropical plants in the legume family Fabaceae. It includes 40 species native to the tropical Americas (Nicaragua to northeastern Argentina), west and central tropical Africa, and Borneo.exudate An exudate is a fluid released by an organism through pores or a wound, a process known as exuding or exudation. ''Exudate'' is derived from ''exude'' 'to ooze' from Latin language, Latin 'to (ooze out) sweat' (' 'out' and ' 'to sweat'). Medi ...
varies in color from light gold to dark brown, depending on the ratio of
resin A resin is a solid or highly viscous liquid that can be converted into a polymer. Resins may be biological or synthetic in origin, but are typically harvested from plants. Resins are mixtures of organic compounds, predominantly terpenes. Commo ...
to
essential oil An essential oil is a concentrated hydrophobic liquid containing volatile (easily evaporated at normal temperatures) chemical compounds from plants. Essential oils are also known as volatile oils, ethereal oils, aetheroleum, or simply as the ...
. Copaiba is used in making varnishes and
lacquer Lacquer is a type of hard and usually shiny coating or finish applied to materials such as wood or metal. It is most often made from resin extracted from trees and waxes and has been in use since antiquity. Asian lacquerware, which may be c ...
s. The
balsam Balsam is the resinous exudate (or sap) which forms on certain kinds of trees and shrubs. Balsam (from Latin ''balsamum'' "gum of the balsam tree," ultimately from a Semitic source such as ) owes its name to the biblical Balm of Gilead. Ch ...
may be steam distilled to give ''copaiba oil'', a colorless to light yellow liquid with the characteristic odor of the balsam and an aromatic, slightly bitter, pungent taste. The oil consists primarily of
sesquiterpene Sesquiterpenes are a class of terpenes that consist of three isoprene units and often have the molecular formula C15H24. Like monoterpenes, sesquiterpenes may be cyclic or contain rings, including many combinations. Biochemical modifications s ...
hydrocarbons; its main component is
β-caryophyllene Caryophyllene (), more formally (−)-β-caryophyllene (BCP), is a natural bicyclic sesquiterpene that occurs widely in nature. Caryophyllene is notable for having a cyclobutane ring, as well as a ''trans''-double bond in a 9-membered ring, both ...
. The oil also contains significant amounts of α-bergamotene,
α-copaene Copaene, or more precisely, α-copaene, is the common (or trivial) chemical name of an oily liquid hydrocarbon that is found in a number of essential oil-producing plants. The name is derived from that of the resin-producing tropical copaiba tree, ...
, and β-bisabolene. It is also the primary source of copalic acid. Copaiba is also a common name for several species of trees of the legume family native to
Tropical Africa The Afrotropical realm is one of the Earth's eight biogeographic realms. It includes Sub-Saharan Africa, the southern Arabian Peninsula, the island of Madagascar, and the islands of the western Indian Ocean. It was formerly known as the Ethiopi ...
and North and South America. __TOC__


Uses

Copaiba is particularly interesting as a source of
biodiesel Biodiesel is a renewable biofuel, a form of diesel fuel, derived from biological sources like vegetable oils, animal fats, or recycled greases, and consisting of long-chain fatty acid esters. It is typically made from fats. The roots of bi ...
, because of the high yield of . The resin is tapped from standing trees, with an individual tree yielding per year. Copaiba oil-resins extracted have been used in
folk medicine Traditional medicine (also known as indigenous medicine or folk medicine) refers to the knowledge, skills, and practices rooted in the cultural beliefs of various societies, especially Indigenous groups, used for maintaining health and treatin ...
dating back to the 16th century by the natives of north and northeastern Brazil. The folk remedies were administered orally or used as an ointment in the treatment of various diseases. In Panama, the Yaviza people mix the resin with
honey Honey is a sweet and viscous substance made by several species of bees, the best-known of which are honey bees. Honey is made and stored to nourish bee colonies. Bees produce honey by gathering and then refining the sugary secretions of pl ...
and give it to newborns to impart knowledge and ward off hexes. Within the Peruvian Amazon near Iquitos, it is also used as an insect repellent. The balsam and its oil are used as fixatives in
soap Soap is a salt (chemistry), salt of a fatty acid (sometimes other carboxylic acids) used for cleaning and lubricating products as well as other applications. In a domestic setting, soaps, specifically "toilet soaps", are surfactants usually u ...
perfumes and fragrances. Copaiba is also used as an artist material, especially in oil paint recipes and in ceramic decoration. Mineral painters use a medium made of copaiba, turpentine and lavender to mix with their minerals for adhesion to ceramic vessels before
kiln A kiln is a thermally insulated chamber, a type of oven, that produces temperatures sufficient to complete some process, such as hardening, drying, or Chemical Changes, chemical changes. Kilns have been used for millennia to turn objects m ...
firing. Copaiba makes a good medium for oils and helps with both adhesion and quality of shine.


Industry and commerce

The production of copaiba oil is socially significant to the
Amazon Amazon most often refers to: * Amazon River, in South America * Amazon rainforest, a rainforest covering most of the Amazon basin * Amazon (company), an American multinational technology company * Amazons, a tribe of female warriors in Greek myth ...
because it represents approximately 95% of Brazil's oil-resin production industry. The Annual production of copaiba oil in the Amazon is estimated to be 500 tons/year. The commercialization of copaiba as an oil or in capsule form has grown because of demand by traditional and widespread use, and is exported to other countries, including the
United States The United States of America (USA), also known as the United States (U.S.) or America, is a country primarily located in North America. It is a federal republic of 50 U.S. state, states and a federal capital district, Washington, D.C. The 48 ...
,
France France, officially the French Republic, is a country located primarily in Western Europe. Overseas France, Its overseas regions and territories include French Guiana in South America, Saint Pierre and Miquelon in the Atlantic Ocean#North Atlan ...
, and
Germany Germany, officially the Federal Republic of Germany, is a country in Central Europe. It lies between the Baltic Sea and the North Sea to the north and the Alps to the south. Its sixteen States of Germany, constituent states have a total popu ...
. The Food and Chemicals Codex lists copaiba oil as safe as a flavoring agent for foods. Copaiba oil has both an acute oral and dermal exceeding 5 g/kg, which classifies it as non-toxic.Robert Tisserand, Tony Balacs (1995). ''Essential Oil Safety''. Churchill Livingstone Press, . {{clear


References

Vegetable oils Biodiesel feedstock sources Resins Essential oils Perfume ingredients Plant common names