Cobalt phosphate is the
inorganic compound
An inorganic compound is typically a chemical compound that lacks carbon–hydrogen bondsthat is, a compound that is not an organic compound. The study of inorganic compounds is a subfield of chemistry known as ''inorganic chemistry''.
Inorgan ...
with the formula Co
3(PO
4)
2. It is a commercial inorganic
pigment
A pigment is a powder used to add or alter color or change visual appearance. Pigments are completely or nearly solubility, insoluble and reactivity (chemistry), chemically unreactive in water or another medium; in contrast, dyes are colored sub ...
known as cobalt violet.
[Hugo Müller, Wolfgang Müller, Manfred Wehner, Heike Liewald "Artists' Colors" in Ullmann's Encyclopedia of Industrial Chemistry 2002, Wiley-VCH, Weinheim. ] Thin films of this material are
water oxidation catalysts.
:
Preparation and structure
The tetrahydrate Co
3(PO
4)
2•4H
2O precipitates as a solid upon mixing aqueous solutions of
cobalt(II) and phosphate salts. Upon heating, the tetrahydrate converts to the anhydrous material. According to
X-ray crystallography
X-ray crystallography is the experimental science of determining the atomic and molecular structure of a crystal, in which the crystalline structure causes a beam of incident X-rays to Diffraction, diffract in specific directions. By measuring th ...
, the anhydrous Co
3(PO
4)
2 consists of discrete phosphate () anions that link centres. The cobalt ions occupy both
octahedral
In geometry, an octahedron (: octahedra or octahedrons) is any polyhedron with eight faces. One special case is the regular octahedron, a Platonic solid composed of eight equilateral triangles, four of which meet at each vertex. Many types of i ...
(six-coordinate) and pentacoordinate sites in a 1:2 ratio.
See also
*
List of inorganic pigments
The following list includes commercially or artistically important inorganic pigments of natural and synthetic origin..
Purple pigments
Aluminosilicate pigments
* Ultramarine violet (): a synthetic or naturally occurring sulfur containing silica ...
References
{{Phosphates
Phosphates
Cobalt(II) compounds
Inorganic pigments