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In physics, the term clusters denotes small, polyatomic particles. As a rule of thumb, any particle made of between 3×100 and 3×107
atom Every atom is composed of a nucleus and one or more electrons bound to the nucleus. The nucleus is made of one or more protons and a number of neutrons. Only the most common variety of hydrogen has no neutrons. Every solid, liquid, gas ...
s is considered a cluster. The term can also refer to the organization of protons and neutrons within an atomic nucleus, e.g. the
alpha particle Alpha particles, also called alpha rays or alpha radiation, consist of two protons and two neutrons bound together into a particle identical to a helium-4 nucleus. They are generally produced in the process of alpha decay, but may also be pro ...
(also known as "α-cluster"Extreme α-clustering in the 18O nucleus.
/ref>), consisting of two protons and two neutrons (as in a
helium Helium (from el, ἥλιος, helios, lit=sun) is a chemical element with the symbol He and atomic number 2. It is a colorless, odorless, tasteless, non-toxic, inert, monatomic gas and the first in the noble gas group in the periodic table. ...
nucleus).


Overview

Although first reports of cluster species date back to the 1940s, cluster science emerged as a separate direction of research in the 1980s, One purpose of the research was to study the gradual development of collective phenomena which characterize a bulk
solid Solid is one of the four fundamental states of matter (the others being liquid, gas, and plasma). The molecules in a solid are closely packed together and contain the least amount of kinetic energy. A solid is characterized by structura ...
. For example, these are the color of a body, its electrical conductivity, its ability to absorb or reflect light, and magnetic phenomena such as ferro-, ferri-, or antiferromagnetism. These are typical collective phenomena which only develop in an aggregate of a large number of atoms. It was found that collective phenomena break down for very small cluster sizes. It turned out, for example, that small clusters of a
ferromagnetic Ferromagnetism is a property of certain materials (such as iron) which results in a large observed magnetic permeability, and in many cases a large magnetic coercivity allowing the material to form a permanent magnet. Ferromagnetic materials ...
material are super-paramagnetic rather than ferromagnetic. Paramagnetism is not a collective phenomenon, which means that the ferromagnetism of the macrostate was not conserved by going into the nanostate. The question then was asked for example, “How many atoms do we need in order to obtain the collective metallic or magnetic properties of a solid?” Soon after the first cluster sources had been developed in 1980, an ever larger community of cluster scientists was involved in such studies. This development led to the discovery of fullerenes in 1986 and
carbon nanotubes A scanning tunneling microscopy image of a single-walled carbon nanotube Rotating single-walled zigzag carbon nanotube A carbon nanotube (CNT) is a tube made of carbon with diameters typically measured in nanometers. ''Single-wall carbon nan ...
a few years later. In science, a lot is known about properties of the gas phase; however, comparatively little is known about the condensed phases (the
liquid A liquid is a nearly incompressible fluid that conforms to the shape of its container but retains a (nearly) constant volume independent of pressure. As such, it is one of the four fundamental states of matter (the others being solid, gas, an ...
phase and
solid Solid is one of the four fundamental states of matter (the others being liquid, gas, and plasma). The molecules in a solid are closely packed together and contain the least amount of kinetic energy. A solid is characterized by structura ...
phase.) The study of clusters attempts to bridge this gap of knowledge by clustering
atoms Every atom is composed of a nucleus and one or more electrons bound to the nucleus. The nucleus is made of one or more protons and a number of neutrons. Only the most common variety of hydrogen has no neutrons. Every solid, liquid, gas ...
together and studying their characteristics. If enough atoms were clustered together, eventually one would obtain a liquid or solid. The study of atomic and molecular clusters also benefits the developing field of
nanotechnology Nanotechnology, also shortened to nanotech, is the use of matter on an atomic, molecular, and supramolecular scale for industrial purposes. The earliest, widespread description of nanotechnology referred to the particular technological goal o ...
. If new materials are to be made out of nanoscale particles, such as nanocatalysts and quantum computers, the properties of the nanoscale particles (the clusters) must first be understood.


See also

*
Cluster chemistry In chemistry, an atom cluster (or simply cluster) is an ensemble of bound atoms or molecules that is intermediate in size between a simple molecule and a nanoparticle; that is, up to a few nanometers (nm) in diameter. The term ''microcluster' ...
*
Nanoparticle A nanoparticle or ultrafine particle is usually defined as a particle of matter that is between 1 and 100 nanometres (nm) in diameter. The term is sometimes used for larger particles, up to 500 nm, or fibers and tubes that are less than 10 ...
* Nanocluster


References


External links


Scientific community portal
for clusters, fullerenes, nanotubes, nanostructures, and similar small systems. Nanomaterials {{nano-tech-stub