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Charoite ( ) is a rare
silicate mineral Silicate minerals are rock-forming minerals made up of silicate groups. They are the largest and most important class of minerals and make up approximately 90 percent of Earth's crust. In mineralogy, the crystalline forms of silica (silicon dio ...
with the
chemical composition A chemical composition specifies the identity, arrangement, and ratio of the chemical elements making up a compound by way of chemical and atomic bonds. Chemical formulas can be used to describe the relative amounts of elements present in a com ...
, first described in 1978. It is named after the Chara River, despite its being away from the discovery place.Ian Frazier, ''Travels in Siberia'', Farrar, Straus and Giroux, New York (NY), 2010, ISBN 978-0-374-27872-4
page 394
/ref> When it was discovered, it was thought to be a fake, dyed purple to give it its striking appearance.


Properties

Charoite is translucent lavender to purple in color with a pearly luster. Charoite is strictly massive in nature, and fractures are
conchoidal A conchoidal fracture is a break or fracture of a brittle material that does not follow any natural planes of separation. Mindat.org defines ''conchoidal fracture'' as follows: "a fracture with smooth, curved surfaces, typically slightly concave, ...
. It has an unusual swirling, fibrous appearance, sometimes chatoyant, and that, along with its intense color, can lead many to believe at first that it is synthetic or enhanced artificially. Though reportedly discovered in the 1940s, it was not known to most of the world until its description in 1978. It is said to be opaque and unattractive when found in the field; a fact that may have contributed to its late recognition. Charoite consists of oxygen (43.75%), silicon (27.65%) and calcium (17.53%) mainly, but its composition includes potassium (10.69%) - which gives it its radioactive properties - and hydrogen (0.39%) as well. It has a barely detectable, 0.65% radioactivity concentration per Gamma Ray American Petroleum Institute Units. Inclusions mainly come in the swirly patterns of the mineral. The black spots on some specimens are either
augite Augite, also known as Augurite, is a common rock-forming pyroxene mineral with formula . The crystals are monoclinic and prismatic. Augite has two prominent cleavages, meeting at angles near 90 degrees. Characteristics Augite is a solid soluti ...
or aegirine, the latter occurring in almost all charoites since they commonly grow together. Larger round greenish spots are
feldspar Feldspar ( ; sometimes spelled felspar) is a group of rock-forming aluminium tectosilicate minerals, also containing other cations such as sodium, calcium, potassium, or barium. The most common members of the feldspar group are the ''plagiocl ...
. Lighter colored stones or ones with translucent areas are likely due to canasite. The yellowish brown spots are tinaksite, which was discovered at the same time as charoite was. Charoite's silky, fibrous structure results in a shimmery looking polished stone. Sometimes, the very white flashes are tiny white feldspar. Sugilites and charoites can be confused, as both are purple, and sugilite can have black and white inclusions, however sugilite lacks the swirling pattern that are present in charoite stones, and it also lacks the chatoyant effect.


Occurrences

It has been reported only from the Aldan Shield,
Sakha Republic Sakha, officially the Republic of Sakha (Yakutia), is a republics of Russia, republic of Russia, and the largest federal subject of Russia by area. It is located in the Russian Far East, along the Arctic Ocean, with a population of one million ...
, Siberia, Russia. It is found where a
syenite Syenite is a coarse-grained intrusive igneous rock with a general composition similar to that of granite, but deficient in quartz, which, if present at all, occurs in relatively small concentrations (< 5%). It is considered a Murun Massif has intruded into and altered
limestone Limestone is a type of carbonate rock, carbonate sedimentary rock which is the main source of the material Lime (material), lime. It is composed mostly of the minerals calcite and aragonite, which are different Polymorphism (materials science) ...
deposits producing a potassium feldspar metasomatite, and forms between 200 - 250 °C. Tinaksite, canasite and charoite are associated and black aegirine is also common where these three minerals grow. Common impurities include
aluminium Aluminium (or aluminum in North American English) is a chemical element; it has chemical symbol, symbol Al and atomic number 13. It has a density lower than that of other common metals, about one-third that of steel. Aluminium has ...
,
iron Iron is a chemical element; it has symbol Fe () and atomic number 26. It is a metal that belongs to the first transition series and group 8 of the periodic table. It is, by mass, the most common element on Earth, forming much of Earth's o ...
,
manganese Manganese is a chemical element; it has Symbol (chemistry), symbol Mn and atomic number 25. It is a hard, brittle, silvery metal, often found in minerals in combination with iron. Manganese was first isolated in the 1770s. It is a transition m ...
,
strontium Strontium is a chemical element; it has symbol Sr and atomic number 38. An alkaline earth metal, it is a soft silver-white yellowish metallic element that is highly chemically reactive. The metal forms a dark oxide layer when it is exposed to ...
and
barium Barium is a chemical element; it has symbol Ba and atomic number 56. It is the fifth element in group 2 and is a soft, silvery alkaline earth metal. Because of its high chemical reactivity, barium is never found in nature as a free element. Th ...
. Charoitite is a rock like lapis lazuli, but unlike the latter one, charoitite mostly consists of the mineral charoite.


Gallery

Charoitite, sw Yakutia Siberia.jpg, Charoitite, a charoite-dominated potassic metasomatite rock from the type area. Photo is 5.7 cm wide. 2000 Charoite 613.jpg, Charoite postage stamp, 2000, from a series commemorating "300 Years of Mining and Geological Service in Russia."


References

{{Gemstones Calcium minerals Sodium minerals Potassium minerals Inosilicates Monoclinic minerals Minerals in space group 11