Chalk is a soft, white, porous, sedimentary

carbonate rock Carbonate rocks are a class of sedimentary rocks composed primarily of carbonate minerals. The two major types are limestone, which is composed of calcite or aragonite (different crystal forms of CaCO3), and Dolomite (rock), dolomite rock (also kn ...

. It is a form of

limestone Limestone is a type of carbonate rock, carbonate sedimentary rock which is the main source of the material Lime (material), lime. It is composed mostly of the minerals calcite and aragonite, which are different Polymorphism (materials science) ...

composed of the mineral

calcite Calcite is a Carbonate minerals, carbonate mineral and the most stable Polymorphism (materials science), polymorph of calcium carbonate (CaCO3). It is a very common mineral, particularly as a component of limestone. Calcite defines hardness 3 on ...

and originally formed deep under the sea by the compression of microscopic

plankton Plankton are the diverse collection of organisms that drift in Hydrosphere, water (or atmosphere, air) but are unable to actively propel themselves against ocean current, currents (or wind). The individual organisms constituting plankton are ca ...

that had settled to the sea floor. Chalk is common throughout

Western Europe Western Europe is the western region of Europe. The region's extent varies depending on context. The concept of "the West" appeared in Europe in juxtaposition to "the East" and originally applied to the Western half of the ancient Mediterranean ...

, where deposits underlie parts of

France France, officially the French Republic, is a country located primarily in Western Europe. Overseas France, Its overseas regions and territories include French Guiana in South America, Saint Pierre and Miquelon in the Atlantic Ocean#North Atlan ...

, and steep cliffs are often seen where they meet the sea in places such as the Dover cliffs on the

Kent Kent is a Ceremonial counties of England, ceremonial county in South East England. It is bordered by Essex across the Thames Estuary to the north, the Strait of Dover to the south-east, East Sussex to the south-west, Surrey to the west, and Gr ...

coast of the

English Channel The English Channel, also known as the Channel, is an arm of the Atlantic Ocean that separates Southern England from northern France. It links to the southern part of the North Sea by the Strait of Dover at its northeastern end. It is the busi ...

. Chalk is mined for use in industry, such as for quicklime,

brick A brick is a type of construction material used to build walls, pavements and other elements in masonry construction. Properly, the term ''brick'' denotes a unit primarily composed of clay. But is now also used informally to denote building un ...

s and builder's

putty PuTTY () is a free and open-source terminal emulator, serial console and network file transfer application. It supports several network protocols, including SCP, SSH, Telnet, rlogin, and raw socket connection. It can also connect to a se ...

, and in

agriculture Agriculture encompasses crop and livestock production, aquaculture, and forestry for food and non-food products. Agriculture was a key factor in the rise of sedentary human civilization, whereby farming of domesticated species created ...

, for raising pH in soils with high acidity. It is also used for " blackboard chalk" for writing and drawing on various types of surfaces, although these can also be manufactured from other carbonate-based minerals, or gypsum.

Description

Chalk is a fine-textured, earthy type of

distinguished by its light colour, softness, and high porosity. It is composed mostly of tiny fragments of the

shells or skeletons of

, such as foraminifera or

coccolithophore Coccolithophores, or coccolithophorids, are single-celled organisms which are part of the phytoplankton, the autotrophic (self-feeding) component of the plankton community. They form a group of about 200 species, and belong either to the kingdom ...

s. These fragments mostly take the form of calcite plates ranging from 0.5 to 4 microns in size, though about 10% to 25% of a typical chalk is composed of fragments that are 10 to 100 microns in size. The larger fragments include intact plankton skeletons and skeletal fragments of larger organisms, such as

mollusc Mollusca is a phylum of protostome, protostomic invertebrate animals, whose members are known as molluscs or mollusks (). Around 76,000 extant taxon, extant species of molluscs are recognized, making it the second-largest animal phylum ...

echinoderm An echinoderm () is any animal of the phylum Echinodermata (), which includes starfish, brittle stars, sea urchins, sand dollars and sea cucumbers, as well as the sessile sea lilies or "stone lilies". While bilaterally symmetrical as ...

s, or

bryozoans Bryozoa (also known as the Polyzoa, Ectoprocta or commonly as moss animals) are a phylum of simple, aquatic animal, aquatic invertebrate animals, nearly all living in sedentary Colony (biology), colonies. Typically about long, they have a spe ...

. Chalk is typically almost pure calcite, , with just 2% to 4% of other minerals. These are usually

quartz Quartz is a hard, crystalline mineral composed of silica (silicon dioxide). The Atom, atoms are linked in a continuous framework of SiO4 silicon–oxygen Tetrahedral molecular geometry, tetrahedra, with each oxygen being shared between two tet ...

and clay minerals, though collophane (cryptocrystalline

apatite Apatite is a group of phosphate minerals, usually hydroxyapatite, fluorapatite and chlorapatite, with high concentrations of Hydroxide, OH−, Fluoride, F− and Chloride, Cl− ion, respectively, in the crystal. The formula of the admixture of ...

, a

phosphate Phosphates are the naturally occurring form of the element phosphorus. In chemistry, a phosphate is an anion, salt, functional group or ester derived from a phosphoric acid. It most commonly means orthophosphate, a derivative of orthop ...

mineral) is also sometimes present, as nodules or as small pellets interpreted as fecal pellets. In some chalk beds, the calcite has been converted to dolomite, , and in a few cases the dolomitized chalk has been dedolomitized back to calcite. Chalk is highly porous, with typical values of porosity ranging from 35 to 47 per cent. While it is similar in appearance to both gypsum and diatomite, chalk is identifiable by its hardness,

fossil A fossil (from Classical Latin , ) is any preserved remains, impression, or trace of any once-living thing from a past geological age. Examples include bones, shells, exoskeletons, stone imprints of animals or microbes, objects preserve ...

content, and its reaction to

acid An acid is a molecule or ion capable of either donating a proton (i.e. Hydron, hydrogen cation, H+), known as a Brønsted–Lowry acid–base theory, Brønsted–Lowry acid, or forming a covalent bond with an electron pair, known as a Lewis ...

(it produces effervescence on contact).

Formation

In Western Europe, chalk was formed in the Late

Cretaceous The Cretaceous ( ) is a geological period that lasted from about 143.1 to 66 mya (unit), million years ago (Mya). It is the third and final period of the Mesozoic Era (geology), Era, as well as the longest. At around 77.1 million years, it is the ...

Epoch and the early Palaeocene Epoch (between 100 and 61 million years ago). It was deposited on extensive continental shelves at depths between , during a time of nonseasonal (likely arid) climate that reduced the amount of erosion from nearby exposed rock. The lack of nearby erosion explains the high purity of chalk. The coccolithophores, foraminifera, and other microscopic organisms from which the chalk came mostly form low-magnesium calcite skeletons, so the sediments were already in the form of highly stable low-magnesium calcite when deposited. This is in contrast with most other limestones, which formed from high-magnesium calcite or aragonite that rapidly converted to the more stable low-magnesium calcite after deposition, resulting in the early cementation of such limestones. In chalk, the absence of calcium carbonate conversion process prevented early cementation, and it accounts for chalk's high porosity. Additionally, chalk is the only form of limestone that commonly shows signs of compaction.

Flint Flint, occasionally flintstone, is a sedimentary cryptocrystalline form of the mineral quartz, categorized as the variety of chert that occurs in chalk or marly limestone. Historically, flint was widely used to make stone tools and start ...

(a type of chert) is very common as bands parallel to the

bedding Bedding, also called bedclothes or bed linen, is the materials laid above the mattress of a bed for hygiene, warmth, protection of the mattress, and decorative effect. Bedding is the removable and washable portion of a human sleeping environment ...

or as nodules in seams, or linings to

fractures Fracture is the appearance of a crack or complete separation of an object or material into two or more pieces under the action of stress (mechanics), stress. The fracture of a solid usually occurs due to the development of certain displacemen ...

, embedded in chalk. It is probably derived from sponge spicules or other siliceous organisms as water is expelled upwards during compaction. Flint is often deposited around larger

s such as Echinoidea which may be silicified (i.e. replaced molecule by molecule by flint).

Geology and geographic distribution

Chalk is so common in Cretaceous marine beds that the

Period was named for these deposits. The name Cretaceous was derived from

Latin Latin ( or ) is a classical language belonging to the Italic languages, Italic branch of the Indo-European languages. Latin was originally spoken by the Latins (Italic tribe), Latins in Latium (now known as Lazio), the lower Tiber area aroun ...

''creta'', meaning ''chalk''. Some deposits of chalk were formed after the Cretaceous. The Chalk Group is a

Europe Europe is a continent located entirely in the Northern Hemisphere and mostly in the Eastern Hemisphere. It is bordered by the Arctic Ocean to the north, the Atlantic Ocean to the west, the Mediterranean Sea to the south, and Asia to the east ...

an stratigraphic unit deposited during the late

Period. It forms the famous White Cliffs of Dover in

, England, as well as their counterparts of the Cap Blanc Nez on the other side of the Dover Strait. The Champagne region of France is mostly underlain by chalk deposits, which contain artificial caves used for wine storage. Some of the highest chalk cliffs in the world occur at Jasmund National Park in

Germany Germany, officially the Federal Republic of Germany, is a country in Central Europe. It lies between the Baltic Sea and the North Sea to the north and the Alps to the south. Its sixteen States of Germany, constituent states have a total popu ...

and at Møns Klint in

Denmark Denmark is a Nordic countries, Nordic country in Northern Europe. It is the metropole and most populous constituent of the Kingdom of Denmark,, . also known as the Danish Realm, a constitutionally unitary state that includes the Autonomous a ...

. Chalk deposits are also found in Cretaceous beds on other continents, such as the Austin Chalk, Selma Group, and Niobrara Formations of the North American interior. Chalk is also found in western Egypt (Khoman Formation) and western Australia ( Miria Formation). Chalk of

Oligocene The Oligocene ( ) is a geologic epoch (geology), epoch of the Paleogene Geologic time scale, Period that extends from about 33.9 million to 23 million years before the present ( to ). As with other older geologic periods, the rock beds that defin ...

Neogene The Neogene ( ,) is a geologic period and system that spans 20.45 million years from the end of the Paleogene Period million years ago ( Mya) to the beginning of the present Quaternary Period million years ago. It is the second period of th ...

age has been found in drill cores of rock under the Pacific Ocean at Stewart Arch in the

Solomon Islands Solomon Islands, also known simply as the Solomons,John Prados, ''Islands of Destiny'', Dutton Caliber, 2012, p,20 and passim is an island country consisting of six major islands and over 1000 smaller islands in Melanesia, part of Oceania, t ...

. There are layers of chalk, containing '' Globorotalia'', in the Nicosia Formation of

Cyprus Cyprus (), officially the Republic of Cyprus, is an island country in the eastern Mediterranean Sea. Situated in West Asia, its cultural identity and geopolitical orientation are overwhelmingly Southeast European. Cyprus is the List of isl ...

, which formed during the

Pliocene The Pliocene ( ; also Pleiocene) is the epoch (geology), epoch in the geologic time scale that extends from 5.33 to 2.58

Mining

Chalk is mined from chalk deposits both above ground and underground. Chalk mining boomed during the

Industrial Revolution The Industrial Revolution, sometimes divided into the First Industrial Revolution and Second Industrial Revolution, was a transitional period of the global economy toward more widespread, efficient and stable manufacturing processes, succee ...

, due to the need for chalk products such as quicklime and

Uses

Most people first encounter chalk in school where it refers to blackboard chalk, which was originally made of mineral chalk, since it readily crumbles and leaves particles that stick loosely to rough surfaces, allowing it to make writing that can be readily erased. Blackboard chalk manufacturers now may use mineral chalk, other mineral sources of calcium carbonate, or the mineral gypsum ( calcium sulfate). While gypsum-based blackboard chalk is the lowest cost to produce, and thus widely used in the developing world, use of carbonate-based chalk produces larger particles and thus less dust, and it is marketed as "dustless chalk". Coloured chalks, pastel chalks, and sidewalk chalk (shaped into larger sticks and often coloured), used to draw on sidewalks, streets, and driveways, are primarily made of gypsum rather than calcium carbonate chalk. Hojer jan 0429

Magnesium carbonate chalk is commonly used as a drying agent to obtain better grip by gymnasts and rock climbers. Glazing

mainly contains chalk as a filler in

linseed oil Linseed oil, also known as flaxseed oil or flax oil (in its edible form), is a colorless to yellowish oil obtained from the dried, ripened seeds of the flax plant (''Linum usitatissimum''). The oil is obtained by pressing, sometimes followed by ...

. Chalk and other forms of limestone may be used for their properties as a base. Chalk is a source of quicklime by thermal decomposition, or

slaked lime Calcium hydroxide (traditionally called slaked lime) is an inorganic compound with the chemical formula Ca( OH)2. It is a colorless crystal or white powder and is produced when quicklime ( calcium oxide) is mixed with water. Annually, approxim ...

following quenching of quicklime with water. In

, chalk is used for raising pH in soils with high acidity. Small doses of chalk can also be used as an antacid. Additionally, the small particles of chalk make it a substance ideal for cleaning and polishing. For example, toothpaste commonly contains small amounts of chalk, which serves as a mild abrasive. Polishing chalk is chalk prepared with a carefully controlled grain size, for very fine polishing of metals. French chalk (also known as tailor's chalk) is traditionally a hard chalk used to make temporary markings on cloth, mainly by tailors. It is now usually made of talc (magnesium silicate). Chalk beds form important petroleum reservoirs in the

North Sea The North Sea lies between Great Britain, Denmark, Norway, Germany, the Netherlands, Belgium, and France. A sea on the European continental shelf, it connects to the Atlantic Ocean through the English Channel in the south and the Norwegian Se ...

and along the Gulf Coast of North America.

Previous uses

In southeast England, deneholes are a notable example of ancient chalk pits. Such bell pits may also mark the sites of ancient

flint Flint, occasionally flintstone, is a sedimentary cryptocrystalline form of the mineral quartz, categorized as the variety of chert that occurs in chalk or marly limestone. Historically, flint was widely used to make stone tools and start ...

mines, where the prime object was to remove flint nodules for

stone tool Stone tools have been used throughout human history but are most closely associated with prehistoric cultures and in particular those of the Stone Age. Stone tools may be made of either ground stone or knapped stone, the latter fashioned by a ...

manufacture. The surface remains at Cissbury are one such example, but perhaps the most famous is the extensive complex at Grimes Graves in

Norfolk Norfolk ( ) is a Ceremonial counties of England, ceremonial county in England, located in East Anglia and officially part of the East of England region. It borders Lincolnshire and The Wash to the north-west, the North Sea to the north and eas ...

. Chalk was traditionally used in recreation. In field sports, such as tennis played on grass, powdered chalk was used to mark the boundary lines of the playing field or court. If a ball hits the line, a cloud of chalk or pigment dust will be visible. In recent years, powdered chalk has been replaced with titanium dioxide. In gymnastics, rock-climbing,

weightlifting Weightlifting or weight lifting generally refers to physical exercises and sports in which people lift weights, often in the form of dumbbells, barbells or machines. People engage in weightlifting for a variety of different reasons. These can ...

and tug of war, chalk — now usually magnesium carbonate — is applied to the hands and feet to remove perspiration and reduce slipping. Chalk may also be used as a house construction material instead of

or wattle and daub: quarried chalk was cut into blocks and used as

ashlar Ashlar () is a cut and dressed rock (geology), stone, worked using a chisel to achieve a specific form, typically rectangular in shape. The term can also refer to a structure built from such stones. Ashlar is the finest stone masonry unit, a ...

, or loose chalk was rammed into blocks and laid in mortar. There are still houses standing which have been constructed using chalk as the main building material. Most are pre- Victorian though a few are more recent. A mixture of chalk and mercury can be used as fingerprint powder. However, because of the toxicity of the mercury, the use of such mixtures for fingerprinting was abandoned in 1967.

Description

Formation

Geology and geographic distribution

Mining

Uses

Previous uses

See also

References

Further reading