Ion exchange is a reversible interchange of one species of ion present in an insoluble solid with another of like charge present in a solution surrounding the solid. Ion exchange is used in softening or demineralizing of water, purification of chemicals, and separation of substances. Ion exchange usually describes a process of purification of aqueous solutions using solid

polymer A polymer () is a chemical substance, substance or material that consists of very large molecules, or macromolecules, that are constituted by many repeat unit, repeating subunits derived from one or more species of monomers. Due to their br ...

ic ion-exchange resin. More precisely, the term encompasses a large variety of processes where ions are exchanged between two

electrolyte An electrolyte is a substance that conducts electricity through the movement of ions, but not through the movement of electrons. This includes most soluble Salt (chemistry), salts, acids, and Base (chemistry), bases, dissolved in a polar solven ...

s. Aside from its use to purify drinking water, the technique is widely applied for purification and separation of a variety of industrially and medicinally important chemicals. Although the term usually refers to applications of synthetic (human-made) resins, it can include many other materials such as soil. Typical ion exchangers are ion-exchange resins (functionalized porous or gel polymer),

zeolite Zeolites are a group of several microporous, crystalline aluminosilicate minerals commonly used as commercial adsorbents and catalysts. They mainly consist of silicon, aluminium, oxygen, and have the general formula ･y where is either a meta ...

montmorillonite Montmorillonite is a very soft phyllosilicate group of minerals that form when they precipitate from water solution as microscopic crystals, known as clay. It is named after Montmorillon in France. Montmorillonite, a member of the smectite grou ...

clay Clay is a type of fine-grained natural soil material containing clay minerals (hydrous aluminium phyllosilicates, e.g. kaolinite, ). Most pure clay minerals are white or light-coloured, but natural clays show a variety of colours from impuriti ...

, and

soil Soil, also commonly referred to as earth, is a mixture of organic matter, minerals, gases, water, and organisms that together support the life of plants and soil organisms. Some scientific definitions distinguish dirt from ''soil'' by re ...

humus In classical soil science, humus is the dark organic matter in soil that is formed by the decomposition of plant and animal matter. It is a kind of soil organic matter. It is rich in nutrients and retains moisture in the soil. Humus is the Lati ...

. Ion exchangers are either cation exchangers, which exchange positively charged ions (

cation An ion () is an atom or molecule with a net electrical charge. The charge of an electron is considered to be negative by convention and this charge is equal and opposite to the charge of a proton, which is considered to be positive by convent ...

s), or anion exchangers, which exchange negatively charged ions (

anion An ion () is an atom or molecule with a net electrical charge. The charge of an electron is considered to be negative by convention and this charge is equal and opposite to the charge of a proton, which is considered to be positive by conven ...

s). There are also amphoteric exchangers that are able to exchange both cations and anions simultaneously. However, the simultaneous exchange of cations and anions is often performed in ''mixed beds'', which contain a mixture of anion- and cation-exchange resins, or passing the solution through several different ion-exchange materials. Ionenaustauscher

Ion exchangers can have binding preferences for certain ions or classes of ions, depending on the physical properties and

chemical structure A chemical structure of a molecule is a spatial arrangement of its atoms and their chemical bonds. Its determination includes a chemist's specifying the molecular geometry and, when feasible and necessary, the electronic structure of the target m ...

of both the ion exchanger and ion. This can be dependent on the size, charge, or structure of the ions. Common examples of ions that can bind to ion exchangers are: * H⁺ (

proton A proton is a stable subatomic particle, symbol , Hydron (chemistry), H+, or 1H+ with a positive electric charge of +1 ''e'' (elementary charge). Its mass is slightly less than the mass of a neutron and approximately times the mass of an e ...

) and OH⁻ (

hydroxide Hydroxide is a diatomic anion with chemical formula OH−. It consists of an oxygen and hydrogen atom held together by a single covalent bond, and carries a negative electric charge. It is an important but usually minor constituent of water. It ...

). * Singly charged monatomic (i.e., monovalent) ions like Na⁺, K⁺, and Cl⁻. * Doubly charged monatomic (i.e., divalent) ions like Ca²⁺ and Mg²⁺. * Polyatomic

inorganic An inorganic compound is typically a chemical compound that lacks carbon–hydrogen bonds⁠that is, a compound that is not an organic compound. The study of inorganic compounds is a subfield of chemistry known as '' inorganic chemistry''. Inor ...

ions like and . * Organic bases, usually

molecule A molecule is a group of two or more atoms that are held together by Force, attractive forces known as chemical bonds; depending on context, the term may or may not include ions that satisfy this criterion. In quantum physics, organic chemi ...

s containing the

amine In chemistry, amines (, ) are organic compounds that contain carbon-nitrogen bonds. Amines are formed when one or more hydrogen atoms in ammonia are replaced by alkyl or aryl groups. The nitrogen atom in an amine possesses a lone pair of elec ...

functional group In organic chemistry, a functional group is any substituent or moiety (chemistry), moiety in a molecule that causes the molecule's characteristic chemical reactions. The same functional group will undergo the same or similar chemical reactions r ...

−NR₂H⁺. *

Organic acid An organic acid is an organic compound with acidic properties. The most common organic acids are the carboxylic acids, whose acidity is associated with their carboxyl group –COOH. Sulfonic acids, containing the group –SO2OH, are re ...

s, often

s containing −COO⁻ (

carboxylic acid In organic chemistry, a carboxylic acid is an organic acid that contains a carboxyl group () attached to an Substituent, R-group. The general formula of a carboxylic acid is often written as or , sometimes as with R referring to an organyl ...

) functional groups. *

Biomolecule A biomolecule or biological molecule is loosely defined as a molecule produced by a living organism and essential to one or more typically biological processes. Biomolecules include large macromolecules such as proteins, carbohydrates, lipids ...

s that can be ionized:

amino acid Amino acids are organic compounds that contain both amino and carboxylic acid functional groups. Although over 500 amino acids exist in nature, by far the most important are the 22 α-amino acids incorporated into proteins. Only these 22 a ...

peptide Peptides are short chains of amino acids linked by peptide bonds. A polypeptide is a longer, continuous, unbranched peptide chain. Polypeptides that have a molecular mass of 10,000 Da or more are called proteins. Chains of fewer than twenty am ...

protein Proteins are large biomolecules and macromolecules that comprise one or more long chains of amino acid residue (biochemistry), residues. Proteins perform a vast array of functions within organisms, including Enzyme catalysis, catalysing metab ...

s, etc. Along with absorption and

adsorption Adsorption is the adhesion of atoms, ions or molecules from a gas, liquid or dissolved solid to a surface. This process creates a film of the ''adsorbate'' on the surface of the ''adsorbent''. This process differs from absorption, in which a ...

, ion exchange is a form of sorption. Ion exchange is a reversible process, and the ion exchanger can be ''regenerated'' or ''loaded'' with desirable ions by washing with an excess of these ions. Ion exchange schematic

Types

Cation exchange

# CM (Carboxymethyl group, weak cation exchange) # SP (sulphopropyl group, strong cation exchange)

Anion exchange

* DEAE-Sepharose * QFF

Ion exchange resins

Ion exchange resins are the physical medium that facilitates ion exchange reactions. The resin is composed of cross-linked organic polymers, typically polystyrene matrix and functional groups where the ion exchange process takes place.

Cation exchange resins

* Strong acid cation (SAC) resins: Composed of a polystyrene matrix with a sulphonate (SO₃⁻) functional group. Used in softening or demineralization processes. * Weak acid cation (WAC) resins: Composed of an acrylic polymer and carboxylic acid functional groups. Used to selectively remove cations associated with alkalinity.

Anion exchange resins

* Strong base anion (SBA) resins: ** Type 1 SBA resins: Greatest affinity for the weak acids and commonly present during a water demineralization process. ** Type 3 SBA resins: Lower chemical stability than Type 1 but better regeneration efficiency. * Weak base anion (WBA) resins: Act as acid absorbers; capable of sorbing strong acids with a high capacity and are readily regenerated with caustic.

Chelating resins

Used to exchange heavy metals from alkaline earth and alkali metal solutions.

Adsorbents

Used for organic compound removal.

Applications

Ion exchange is widely used in the food and beverage industry, hydrometallurgy, metals finishing, chemical, petrochemical, pharmaceutical technology, sugar and sweetener production, ground- and potable-water treatment, nuclear, softening, industrial water treatment, semiconductor, power, and many other industries. A typical example of application is preparation of high-purity water for

power engineering Power engineering, also called power systems engineering, is a subfield of electrical engineering that deals with the generation, transmission, distribution, and utilization of electric power, and the electrical apparatus connected to such sy ...

, electronic and nuclear industries; i.e.

ic or inorganic insoluble ion exchangers are widely used for

water softening Water softening is the removal of calcium, magnesium, and certain other metal cations in hard water. The resulting soft water requires less soap for the same cleaning effort, as soap is not wasted bonding with calcium ions. Soft water also extend ...

water purification Water purification is the process of removing undesirable chemicals, biological contaminants, suspended solids, and gases from water. The goal is to produce water that is fit for specific purposes. Most water is purified and disinfected for hu ...

, water

decontamination Decontamination (sometimes abbreviated as decon, dcon, or decontam) is the process of removing contaminants on an object or area, including chemicals, micro-organisms, and/or radioactive substances. This may be achieved by chemical reaction, dis ...

, etc. Ion exchange is a method widely used in household filters to produce soft water for the benefit of laundry detergents, soaps, and water heaters. This is accomplished by exchanging divalent cations (such as

calcium Calcium is a chemical element; it has symbol Ca and atomic number 20. As an alkaline earth metal, calcium is a reactive metal that forms a dark oxide-nitride layer when exposed to air. Its physical and chemical properties are most similar to it ...

Ca²⁺ and

magnesium Magnesium is a chemical element; it has Symbol (chemistry), symbol Mg and atomic number 12. It is a shiny gray metal having a low density, low melting point and high chemical reactivity. Like the other alkaline earth metals (group 2 ...

Mg²⁺) with highly soluble monovalent cations (e.g., Na⁺ or H⁺) (see

). Another application for ion exchange in domestic water treatment is the removal of

nitrate Nitrate is a polyatomic ion with the chemical formula . salt (chemistry), Salts containing this ion are called nitrates. Nitrates are common components of fertilizers and explosives. Almost all inorganic nitrates are solubility, soluble in wa ...

and natural organic matter. In domestic filtration systems ion exchange is one of the alternatives for water softening in households along with reverse osmosis (RO) membranes. Compared to RO membranes, ion exchange requires repetitive regeneration when inlet water is hard (has high mineral content). Industrial and analytical ion-exchange chromatography is another area to be mentioned. Ion-exchange chromatography is a chromatographical method that is widely used for chemical analysis and separation of ions. For example, in

biochemistry Biochemistry, or biological chemistry, is the study of chemical processes within and relating to living organisms. A sub-discipline of both chemistry and biology, biochemistry may be divided into three fields: structural biology, enzymology, a ...

it is widely used to separate charged molecules such as

s. An important area of the application is extraction and purification of biologically produced substances such as proteins (

amino acids Amino acids are organic compounds that contain both amino and carboxylic acid functional groups. Although over 500 amino acids exist in nature, by far the most important are the Proteinogenic amino acid, 22 α-amino acids incorporated into p ...

) and

DNA Deoxyribonucleic acid (; DNA) is a polymer composed of two polynucleotide chains that coil around each other to form a double helix. The polymer carries genetic instructions for the development, functioning, growth and reproduction of al ...

RNA Ribonucleic acid (RNA) is a polymeric molecule that is essential for most biological functions, either by performing the function itself (non-coding RNA) or by forming a template for the production of proteins (messenger RNA). RNA and deoxyrib ...

. Ion-exchange processes are used to separate and purify

metal A metal () is a material that, when polished or fractured, shows a lustrous appearance, and conducts electrical resistivity and conductivity, electricity and thermal conductivity, heat relatively well. These properties are all associated wit ...

s, including separating

uranium Uranium is a chemical element; it has chemical symbol, symbol U and atomic number 92. It is a silvery-grey metal in the actinide series of the periodic table. A uranium atom has 92 protons and 92 electrons, of which 6 are valence electrons. Ura ...

from

plutonium Plutonium is a chemical element; it has symbol Pu and atomic number 94. It is a silvery-gray actinide metal that tarnishes when exposed to air, and forms a dull coating when oxidized. The element normally exhibits six allotropes and four ...

and the other

actinide The actinide () or actinoid () series encompasses at least the 14 metallic chemical elements in the 5f series, with atomic numbers from 89 to 102, actinium through nobelium. Number 103, lawrencium, is also generally included despite being part ...

s, including

thorium Thorium is a chemical element; it has symbol Th and atomic number 90. Thorium is a weakly radioactive light silver metal which tarnishes olive grey when it is exposed to air, forming thorium dioxide; it is moderately soft, malleable, and ha ...

neptunium Neptunium is a chemical element; it has chemical symbol, symbol Np and atomic number 93. A radioactivity, radioactive actinide metal, neptunium is the first transuranic element. It is named after Neptune, the planet beyond Uranus in the Solar Syste ...

, and

americium Americium is a synthetic element, synthetic chemical element; it has Chemical symbol, symbol Am and atomic number 95. It is radioactive and a transuranic member of the actinide series in the periodic table, located under the lanthanide element e ...

. This process is also used to separate the

lanthanide The lanthanide () or lanthanoid () series of chemical elements comprises at least the 14 metallic chemical elements with atomic numbers 57–70, from lanthanum through ytterbium. In the periodic table, they fill the 4f orbitals. Lutetium (el ...

s, such as lanthanum,

cerium Cerium is a chemical element; it has Chemical symbol, symbol Ce and atomic number 58. It is a hardness, soft, ductile, and silvery-white metal that tarnishes when exposed to air. Cerium is the second element in the lanthanide series, and while it ...

neodymium Neodymium is a chemical element; it has Symbol (chemistry), symbol Nd and atomic number 60. It is the fourth member of the lanthanide series and is considered to be one of the rare-earth element, rare-earth metals. It is a hard (physics), hard, sli ...

, praseodymium,

europium Europium is a chemical element; it has symbol Eu and atomic number 63. It is a silvery-white metal of the lanthanide series that reacts readily with air to form a dark oxide coating. Europium is the most chemically reactive, least dense, and soft ...

, and ytterbium, from each other. The separation of neodymium and praseodymium was a particularly difficult one, and those were formerly thought to be just one element didymium – but that is an alloy of the two. There are two series of

rare-earth metal The rare-earth elements (REE), also called the rare-earth metals or rare earths, and sometimes the lanthanides or lanthanoids (although scandium and yttrium, which do not belong to this series, are usually included as rare earths), are a set of ...

s, the lanthanides and the actinides, both of whose families all have very similar chemical and physical properties. Using methods developed by Frank Spedding in the 1940s, ion-exchange processes were formerly the only practical way to separate them in large quantities, until the development of the "solvent extraction" techniques that can be scaled up enormously. A very important case of ion-exchange is the plutonium-uranium extraction process (

PUREX PUREX (plutonium uranium reduction extraction) is a chemical method used to purify fuel for nuclear reactors or nuclear weapons. It is based on liquid–liquid extraction ion-exchange. PUREX is the '' de facto'' standard aqueous nuclear reproc ...

), which is used to separate the plutonium (mainly ) and the

(in that case known as reprocessed uranium) contained in spent fuel from

, curium,

(the minor actinides), and the fission products that come from

nuclear reactor A nuclear reactor is a device used to initiate and control a Nuclear fission, fission nuclear chain reaction. They are used for Nuclear power, commercial electricity, nuclear marine propulsion, marine propulsion, Weapons-grade plutonium, weapons ...

s. Thus the waste products can be separated out for disposal. Next, the plutonium and uranium are available for making nuclear-energy materials, such as new reactor fuel ( MOX-fuel) and (plutonium-based)

nuclear weapon A nuclear weapon is an explosive device that derives its destructive force from nuclear reactions, either fission (fission or atomic bomb) or a combination of fission and fusion reactions (thermonuclear weapon), producing a nuclear exp ...

s. Historically some fission products such as

Strontium-90 Strontium-90 () is a radioactive isotope of strontium produced by nuclear fission, with a half-life of 28.79 years. It undergoes β− decay into yttrium-90, with a decay energy of 0.546 MeV. Strontium-90 has applications in medicine a ...

or Caesium-137 were likewise separated for use as

radionuclide A radionuclide (radioactive nuclide, radioisotope or radioactive isotope) is a nuclide that has excess numbers of either neutrons or protons, giving it excess nuclear energy, and making it unstable. This excess energy can be used in one of three ...

s employed in industry or medicine. The ion-exchange process is also used to separate other sets of very similar chemical elements, such as

zirconium Zirconium is a chemical element; it has Symbol (chemistry), symbol Zr and atomic number 40. First identified in 1789, isolated in impure form in 1824, and manufactured at scale by 1925, pure zirconium is a lustrous transition metal with a greyis ...

and

hafnium Hafnium is a chemical element; it has symbol Hf and atomic number 72. A lustrous, silvery gray, tetravalent transition metal, hafnium chemically resembles zirconium and is found in many zirconium minerals. Its existence was predicted by Dm ...

, which is also very important for the nuclear industry. Physically, zirconium is practically transparent to free neutrons, used in building nuclear reactors, but hafnium is a very strong absorber of neutrons, used in reactor control rods. Thus, ion-exchange is used in

nuclear reprocessing Nuclear reprocessing is the chemical separation of fission products and actinides from spent nuclear fuel. Originally, reprocessing was used solely to extract plutonium for producing nuclear weapons. With commercialization of nuclear power, the ...

and the treatment of

radioactive waste Radioactive waste is a type of hazardous waste that contains radioactive material. It is a result of many activities, including nuclear medicine, nuclear research, nuclear power generation, nuclear decommissioning, rare-earth mining, and nuclear ...

. Ion-exchange resins in the form of thin membranes are also used in

chloralkali process The chloralkali process (also chlor-alkali and chlor alkali) is an industrial process for the electrolysis of sodium chloride (NaCl) solutions. It is the technology used to produce chlorine and sodium hydroxide (caustic soda), which are commodi ...

fuel cell A fuel cell is an electrochemical cell that converts the chemical energy of a fuel (often hydrogen fuel, hydrogen) and an oxidizing agent (often oxygen) into electricity through a pair of redox reactions. Fuel cells are different from most bat ...

s, and vanadium redox batteries. CationExchCartoon

Ion exchange can also be used to remove hardness from water by exchanging calcium and magnesium ions for sodium ions in an ion-exchange column. Liquid-phase (aqueous) ion-exchange

desalination Desalination is a process that removes mineral components from saline water. More generally, desalination is the removal of salts and minerals from a substance. One example is Soil salinity control, soil desalination. This is important for agric ...

has been demonstrated. In this technique anions and cations in salt water are exchanged for carbonate anions and calcium cations respectively using

electrophoresis Electrophoresis is the motion of charged dispersed particles or dissolved charged molecules relative to a fluid under the influence of a spatially uniform electric field. As a rule, these are zwitterions with a positive or negative net ch ...

. Calcium and carbonate ions then react to form

calcium carbonate Calcium carbonate is a chemical compound with the chemical formula . It is a common substance found in Rock (geology), rocks as the minerals calcite and aragonite, most notably in chalk and limestone, eggshells, gastropod shells, shellfish skel ...

, which then precipitates, leaving behind fresh water. The desalination occurs at ambient temperature and pressure and requires no membranes or solid ion exchangers. The theoretical energy efficiency of this method is on par with

electrodialysis Electrodialysis (ED) is used to transport salt ions from one solution through ion-exchange membranes to another solution under the influence of an applied electric potential difference. This is done in a configuration called an electrodialysis ...

and

reverse osmosis Reverse osmosis (RO) is a water purification process that uses a partially permeable membrane, semi-permeable membrane to separate water molecules from other substances. RO applies pressure to overcome osmotic pressure that favors even distribu ...

Other applications

* In

soil science Soil science is the study of soil as a natural resource on the surface of the Earth including soil formation, soil classification, classification and Soil survey, mapping; Soil physics, physical, Soil chemistry, chemical, Soil biology, biologica ...

cation-exchange capacity Cation-exchange capacity (CEC) is a measure of how many cations can be retained on soil particle surfaces. Negative charges on the surfaces of soil particles bind positively-charged atoms or molecules (cations), but allow these to exchange with ot ...

is the ion-exchange capacity of

for positively charged ions. Soils can be considered as natural weak cation exchangers. * In pollution remediation and

geotechnical engineering Geotechnical engineering, also known as geotechnics, is the branch of civil engineering concerned with the engineering behavior of earth materials. It uses the principles of soil mechanics and rock mechanics to solve its engineering problems. I ...

, ion-exchange capacity determines the swelling capacity of swelling or

expansive clay Expansive clay, also called expansive soil, is a clay soil prone to large volume changes (swelling and shrinking) directly related to changes in water content. Soils with a high content of expansive minerals can form deep cracks in drier seasons ...

such as

, which can be used to "capture" pollutants and charged ions. * In planar waveguide manufacturing, ion exchange is used to create the guiding layer of higher index of refraction. * Dealkalization, removal of alkali ions from a

glass Glass is an amorphous (non-crystalline solid, non-crystalline) solid. Because it is often transparency and translucency, transparent and chemically inert, glass has found widespread practical, technological, and decorative use in window pane ...

surface. * Chemically strengthened glass, produced by exchanging K⁺ for Na⁺ in soda glass surfaces using KNO₃ melts.

Advantages and limitations

Advantages

* Selective removal: Ion exchange resins can be designed to selectively remove specific ions from water. * High efficiency: Ion exchange processes can achieve high removal efficiencies for targeted ions. * Regenerability: Ion exchange resins can be regenerated multiple times by flushing them with a regenerating solution, extending their lifespan and reducing operational costs. * Versatility: Ion exchange can be applied to various water treatment applications. * Consistent performance: Ion exchange systems offer consistent and predictable performance, providing reliable water treatment over time. * Scalability: Ion exchange systems can be easily scaled up or down to meet different treatment capacities and requirements.

Limitations

* Removal limitations: If target ions are present in complex mixtures or at low concentrations, additional pre-treatment or post-treatment may be required. * Regeneration requirements: Regeneration of ion exchange resins requires the use of chemicals and generates wastewater containing concentrated contaminants, which may require appropriate handling and disposal measures. * Limited capacity: Ion exchange resins have finite capacities for adsorbing ions, and once saturated, they must be regenerated or replaced, which can limit their effectiveness in treating high-concentration or high-volume streams. * Complexity: Ion exchange systems can be complex to design, operate, and maintain, requiring specialized knowledge and expertise.

Waste water produced by resin regeneration

Most ion-exchange systems use columns of ion-exchange

resin A resin is a solid or highly viscous liquid that can be converted into a polymer. Resins may be biological or synthetic in origin, but are typically harvested from plants. Resins are mixtures of organic compounds, predominantly terpenes. Commo ...

that are operated on a cyclic basis. During the filtration process, water flows through the resin column until the resin is considered exhausted. That happens only when water leaving the column contains more than the maximal desired concentration of the ions being removed. Resin is then regenerated by sequentially backwashing the resin bed to remove accumulated suspended solids, flushing removed ions from the resin with a concentrated solution of replacement ions, and rinsing the flushing solution from the resin. Production of backwash, flushing, and rinsing

wastewater Wastewater (or waste water) is water generated after the use of freshwater, raw water, drinking water or saline water in a variety of deliberate applications or processes. Another definition of wastewater is "Used water from any combination of do ...

during regeneration of ion-exchange media limits the usefulness of ion exchange for

wastewater treatment Wastewater treatment is a process which removes and eliminates contaminants from wastewater. It thus converts it into an effluent that can be returned to the water cycle. Once back in the water cycle, the effluent creates an acceptable impact on ...

. Water softeners are usually regenerated with

brine Brine (or briny water) is a high-concentration solution of salt (typically sodium chloride or calcium chloride) in water. In diverse contexts, ''brine'' may refer to the salt solutions ranging from about 3.5% (a typical concentration of seawat ...

containing 10%

sodium chloride Sodium chloride , commonly known as Salt#Edible salt, edible salt, is an ionic compound with the chemical formula NaCl, representing a 1:1 ratio of sodium and chloride ions. It is transparent or translucent, brittle, hygroscopic, and occurs a ...

. Aside from the soluble chloride salts of divalent cations removed from the softened water, softener regeneration wastewater contains the unused 50–70% of the sodium chloride regeneration flushing brine required to reverse ion-exchange resin equilibria. Deionizing resin regeneration with

sulfuric acid Sulfuric acid (American spelling and the preferred IUPAC name) or sulphuric acid (English in the Commonwealth of Nations, Commonwealth spelling), known in antiquity as oil of vitriol, is a mineral acid composed of the elements sulfur, oxygen, ...

and

sodium hydroxide Sodium hydroxide, also known as lye and caustic soda, is an inorganic compound with the formula . It is a white solid ionic compound consisting of sodium cations and hydroxide anions . Sodium hydroxide is a highly corrosive base (chemistry), ...

is approximately 20–40% efficient. Neutralized deionizer regeneration wastewater contains all of the removed ions plus 2.5–5 times their equivalent concentration as

sodium sulfate Sodium sulfate (also known as sodium sulphate or sulfate of soda) is the inorganic compound with formula Na2SO4 as well as several related hydrates. All forms are white solids that are highly soluble in water. With an annual production of 6 mill ...

.Kemmer, pp. 12–18.

References

Further information

* * Ion Exchangers (K. Dorfner, ed.), Walter de Gruyter, Berlin, 1991. * C. E. Harland, Ion exchange: Theory and Practice, The Royal Society of Chemistry, Cambridge, 1994. * * * Ion exchange (D. Muraviev, V. Gorshkov, A. Warshawsky), M. Dekker, New York, 2000. * A. A. Zagorodni
Ion Exchange Materials: Properties and Applications
Elsevier, Amsterdam, 2006. * * Dr., I., & Luqman, M. (2012). ''Ion Exchange Technology I : Theory and Materials.'' Springer Netherlands. * Harland, C. E. (1994). ''Ion exchange : theory and practice (2nd ed.)''. The Royal Society of Chemistry.

External links

* ttps://web.archive.org/web/20070428014113/http://www.ionexchange.books.kth.se/applets.html Some applets illustrating ion exchange processes
A simple explanation of deionization

Ion exchange, BioMineWiki
{{Authority control Analytical chemistry General chemistry Industrial water treatment