Carl Erengisle Hyltén-Cavallius
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''Carl'' Erengisle Hyltén-Cavallius, born 19 February 1817 in
Vislanda Vislanda () is a locality situated in Alvesta Municipality, Kronoberg County, Sweden Sweden, formally the Kingdom of Sweden, is a Nordic countries, Nordic country located on the Scandinavian Peninsula in Northern Europe. It borders Norway ...
; died 29 October 1853 in
Gothenburg Gothenburg ( ; ) is the List of urban areas in Sweden by population, second-largest city in Sweden, after the capital Stockholm, and the fifth-largest in the Nordic countries. Situated by the Kattegat on the west coast of Sweden, it is the gub ...
, was a Swedish pharmacist and chemist; he invented the now dominating technology of tanning by using chromium salts.


Biography

He was the son of the priest Carl Fredrik Cavallius and his wife Anna Elisabet Hylténius. Like his siblings, the naval officer and botanist Gustaf Erik H-C, and the ethnologist and diplomat Gunnar Olof H-C, he transformed his surname into a combination of his father's and his mother's names, according to his grandfather's wishes. In international publications, where his scientific achievements have been noted, his surname has on several occasions been distorted to Hyltén-Cavallin and also to Cavallin, Cavalin and even French Cavalin. He studied pharmacy and chemistry at the
Uppsala University Uppsala University (UU) () is a public university, public research university in Uppsala, Sweden. Founded in 1477, it is the List of universities in Sweden, oldest university in Sweden and the Nordic countries still in operation. Initially fou ...
and at the Stockholm Institute of Technology (later
KTH Royal Institute of Technology KTH Royal Institute of Technology (), abbreviated KTH, is a Public university, public research university in Stockholm, Sweden. KTH conducts research and education in Institute of technology, engineering and technology and is Sweden's largest te ...
in Stockholm) and also received a journeyman's certificate as a tanner at the latter school.


Operations

He was active as a teacher (assistant professor of chemistry) at the Stockholm Institute of Technology between 1840 and 1843, when he also conducted research in chemistry. It was in connection with this he invented a method for tanning animal skins with
chromium salts Chromium is a chemical element; it has symbol Cr and atomic number 24. It is the first element in group 6. It is a steely-grey, lustrous, hard, and brittle transition metal. Chromium is valued for its high corrosion resistance and hardness. ...
, a method that would revolutionize the
leather Leather is a strong, flexible and durable material obtained from the tanning (leather), tanning, or chemical treatment, of animal skins and hides to prevent decay. The most common leathers come from cattle, sheep, goats, equine animals, buffal ...
industry throughout the world. A very time-consuming, dirty and smelly method of tanning, with different vegetable substances (bark of different types of wood), was replaced by a faster, cheaper and more odorless process. It is the most common tanning method today, but it has negative effects on the environment and people if the chromium residues are not taken care of effectively. During the years 1843 to 1850 he owned a pharmacy in
Kungälv Kungälv () is a cities of Sweden, city and the seat of Kungälv Municipality in Västra Götaland County, Sweden. It is also a part of Greater Gothenburg Metropolitan Area. It had 22,768 inhabitants in 2010. In 2021, the main Kungälv - Ytterby - ...
, in western Sweden. In connection with this, he established a tannery where he had the opportunity to develop his new tanning method, which he applied for a patent in 1850. In the latter year, he got a job as an assistant professor in chemistry at the Chalmers handicraft school (later
Chalmers University of Technology Chalmers University of Technology (, commonly referred to as Chalmers) is a private university, private research university located in Gothenburg, Sweden. Chalmers focuses on engineering and science, but more broadly it also conducts research ...
). Meanwhile, at this school he wrote the ''Elementary Course in Inorganic Chemistry'' which was published in 1854. The patent that was taken out, for the new chrome tanning method, was limited to Sweden. Carl E. Hyltén-Cavallius died of blood poisoning, 36 years old, in 1853, which is why he never had time to apply for a world patent for his tanning method. At the "Fourth Biennial Conference of the International Union of Leather Technologists and Chemists Societies (IULTCS)", which took place at the Royal Institute of Technology in Stockholm, in 1955, he was recognized as the inventor of the epoch-making tanning method. The president of the IULTCS at that time, Professor K.H. Gustavson, told about Mr. Hyltén-Cavallius achievements in his keynote speech:
The name Cavallin is familiar to most of us from the early history of the chrome tanning process. In the outstanding treatise on chemical technology of its day, Muspratt's Chemistry, it is stated in the early 1860 edition that chrome salts were first used for tanning by Cavallin; a statement often repeated in later books on chrome tanning, none however, giving the source of information or literature reference. The results of his experimentation are laid down in Swedish Patent N:o. 1530, granted to him in April 1850. Hyltén-Cavallius stresses the fact that the new method differs from the conventional processes of tanning in so far as no bark or other substances containing tannic acid is required; the tanning being effected by »Chemical salts» such as bichromate of potassium after the hides have been struck through by a solution of »minerals». He points to the speed of the process and stresses that his method will not lead to an »ultimate devastation of the oak forests». Various modes of tanning are exemplified. Thus, tanning with chromium salts entirely, pre-tanning with
alum An alum () is a type of chemical compound, usually a hydrated double salt, double sulfate salt (chemistry), salt of aluminium with the general chemical formula, formula , such that is a valence (chemistry), monovalent cation such as potassium ...
and chromium salts or with alum and ferrous sulphate (
copperas Iron(II) sulfate or ferrous sulfate (British English: sulphate instead of sulfate) denotes a range of salts with the formula Fe SO4·''x''H2O. These compounds exist most commonly as the heptahydrate (''x'' = 7), but several values for ...
). In the latter instance, the pre-tannage is followed up by a bichromate bath. Also, combinations with vegetable
tannin Tannins (or tannoids) are a class of astringent, polyphenolic biomolecules that bind to and Precipitation (chemistry), precipitate proteins and various other organic compounds including amino acids and alkaloids. The term ''tannin'' is widel ...
s are mentioned, e. g. vegetable-mineral tannages in combination. His important contribution is a landmark in the history of the mineral tannage, being a well-balanced combination of three mineral tanning agents''.''


Family

Together with his wife Anna Dorotea (born Wettermark) he had the children Elisabeth Ulrika, born in 1850 and Carl born in 1853. The grandson
Carl Wilhelm Oseen Carl Wilhelm Oseen (17 April 1879 in Lund – 7 November 1944 in Uppsala) was a theoretical physicist in Uppsala and Director of the Nobel Institute for Theoretical Physics in Stockholm. Life Oseen was born in Lund, and took a Fil. Kand. degree ...
(1879–1944), was a professor of
theoretical physics Theoretical physics is a branch of physics that employs mathematical models and abstractions of physical objects and systems to rationalize, explain, and predict List of natural phenomena, natural phenomena. This is in contrast to experimental p ...
and chairman of the
Nobel Committee for Physics The Nobel Committee for Physics is the Nobel Committee responsible for proposing laureates for the Nobel Prize for Physics.
.


References

* Article by Professor K.H. Gustavson in Lädertidningen, published by Sko- och Läderbranschens Fabrikant- och Grossistförening (The Leather Union), Stockholm. N:o 13–14, Aug 1, 1955, pp 3,4,7,22. * Patent granted April 30, 1850 (
Post- och Inrikes Tidningar ''Post- och Inrikes Tidningar'' () or ''PoIT'' is the government newspaper and gazette of Sweden, and the country's official notification medium for announcements like bankruptcy declarations or auctions. The newspaper also carries advertising, t ...
, May 1, 1850) {{DEFAULTSORT:Hylten-Cavallius, Carl Erengisle 1817 births 1853 deaths Uppsala University alumni Swedish chemists People from Alvesta Municipality