Atacamite is a
copper
Copper is a chemical element; it has symbol Cu (from Latin ) and atomic number 29. It is a soft, malleable, and ductile metal with very high thermal and electrical conductivity. A freshly exposed surface of pure copper has a pinkish-orang ...
halide mineral
Halide minerals are those minerals with a dominant halide anion (, , and ). Complex halide minerals may also have Polyatomic ion, polyatomic anions.
Examples include the following:
*Atacamite
*Avogadrite (K,Cs)BF
*Bararite (β)
*Bischofite
* ...
: a
copper(II) chloride hydroxide with formula Cu
2Cl(OH)
3. It was first described for deposits in the
Atacama Desert
The Atacama Desert () is a desert plateau located on the Pacific Ocean, Pacific coast of South America, in the north of Chile. Stretching over a strip of land west of the Andes Mountains, it covers an area of , which increases to if the barre ...
of
Chile
Chile, officially the Republic of Chile, is a country in western South America. It is the southernmost country in the world and the closest to Antarctica, stretching along a narrow strip of land between the Andes, Andes Mountains and the Paci ...
in 1802 by
Dmitri de Gallitzin.
The Atacama Desert is also the namesake of the mineral.
Occurrence
Atacamite is
polymorphous with
botallackite,
clinoatacamite, and
paratacamite.
Atacamite is a comparatively rare mineral, formed from primary copper minerals in the
oxidation
Redox ( , , reduction–oxidation or oxidation–reduction) is a type of chemical reaction in which the oxidation states of the reactants change. Oxidation is the loss of electrons or an increase in the oxidation state, while reduction is ...
or
weathering
Weathering is the deterioration of rocks, soils and minerals (as well as wood and artificial materials) through contact with water, atmospheric gases, sunlight, and biological organisms. It occurs '' in situ'' (on-site, with little or no move ...
zone of arid climates. It has also been reported as a
volcanic sublimate
A volcano is commonly defined as a vent or fissure in the crust of a planetary-mass object, such as Earth, that allows hot lava, volcanic ash, and gases to escape from a magma chamber below the surface.
On Earth, volcanoes are most often fou ...
from
fumarole
A fumarole (or fumerole) is a vent in the surface of the Earth or another rocky planet from which hot volcanic gases and vapors are emitted, without any accompanying liquids or solids. Fumaroles are characteristic of the late stages of volcani ...
deposits, as sulfide alteration products in
black smoker
Hydrothermal vents are fissures on the seabed from which geothermally heated water discharges. They are commonly found near volcanically active places, areas where tectonic plates are moving apart at mid-ocean ridges, ocean basins, and hots ...
s.
The mineral has also been found naturally on oxidized copper deposits in Chile,
China
China, officially the People's Republic of China (PRC), is a country in East Asia. With population of China, a population exceeding 1.4 billion, it is the list of countries by population (United Nations), second-most populous country after ...
,
Russia
Russia, or the Russian Federation, is a country spanning Eastern Europe and North Asia. It is the list of countries and dependencies by area, largest country in the world, and extends across Time in Russia, eleven time zones, sharing Borders ...
,
Czech Republic
The Czech Republic, also known as Czechia, and historically known as Bohemia, is a landlocked country in Central Europe. The country is bordered by Austria to the south, Germany to the west, Poland to the northeast, and Slovakia to the south ...
,
Arizona
Arizona is a U.S. state, state in the Southwestern United States, Southwestern region of the United States, sharing the Four Corners region of the western United States with Colorado, New Mexico, and Utah. It also borders Nevada to the nort ...
, and
Australia
Australia, officially the Commonwealth of Australia, is a country comprising mainland Australia, the mainland of the Australia (continent), Australian continent, the island of Tasmania and list of islands of Australia, numerous smaller isl ...
.
It occurs in association with
cuprite
Cuprite is an oxide mineral composed of copper(I) oxide Cu2O, and is a minor ore of copper.
Its dark crystals with red internal reflections are in the isometric system hexoctahedral class, appearing as cubic, octahedral, or dodecahedral forms, ...
,
brochantite
Brochantite is a sulfate mineral, one of a number of cupric sulfates. Its chemical formula is Cu4SO4(OH)6. Formed in arid climates or in rapidly oxidizing copper sulfide deposits, it was named by Armand Lévy (mineralogist), Armand Lévy for his ...
,
linarite
Linarite is a somewhat rare, crystalline mineral that is known among mineral collectors for its unusually intense, pure blue color. It is formed by the oxidation of galena and chalcopyrite and other copper sulfides. It is a combined copper lead s ...
,
caledonite,
malachite
Malachite () is a copper Carbonate mineral, carbonate hydroxide mineral, with the chemical formula, formula Basic copper carbonate, Cu2CO3(OH)2. This opaque, green-banded mineral crystallizes in the monoclinic crystal system, and most often for ...
,
chrysocolla
Chrysocolla ( ) is a hydrous copper phyllosilicate mineral and mineraloid with the formula (''x'' < 1)[ or .][
The structure of the mineral has been questioned, as a 2006 spectrographic study suggest ma ...]
and its polymorphs.
Synthetic Occurrence
Atacamite has been discovered in the patina of the
Statue of Liberty
The Statue of Liberty (''Liberty Enlightening the World''; ) is a colossal neoclassical sculpture on Liberty Island in New York Harbor, within New York City. The copper-clad statue, a gift to the United States from the people of French Thir ...
, and as alteration of ancient
bronze
Bronze is an alloy consisting primarily of copper, commonly with about 12–12.5% tin and often with the addition of other metals (including aluminium, manganese, nickel, or zinc) and sometimes non-metals (such as phosphorus) or metalloid ...
and copper
artifacts. The bronze of the
Antikythera mechanism
The Antikythera mechanism ( , ) is an Ancient Greece, Ancient Greek hand-powered orrery (model of the Solar System). It is the oldest known example of an Analog computer, analogue computer. It could be used to predict astronomy, astronomical ...
had turned to atacamite under the sea.
The mineral has been found as a pigment in
sculpture
Sculpture is the branch of the visual arts that operates in three dimensions. Sculpture is the three-dimensional art work which is physically presented in the dimensions of height, width and depth. It is one of the plastic arts. Durable sc ...
,
manuscripts
A manuscript (abbreviated MS for singular and MSS for plural) was, traditionally, any document written by hand or typewritten, as opposed to mechanically printed or reproduced in some indirect or automated way. More recently, the term has c ...
,
maps
A map is a symbolic depiction of interrelationships, commonly spatial, between things within a space. A map may be annotated with text and graphics. Like any graphic, a map may be fixed to paper or other durable media, or may be displayed on ...
, and
frescoes
Fresco ( or frescoes) is a technique of mural painting executed upon freshly laid ("wet") lime plaster. Water is used as the vehicle for the dry-powder pigment to merge with the plaster, and with the setting of the plaster, the painting become ...
discovered in
Eurasia
Eurasia ( , ) is a continental area on Earth, comprising all of Europe and Asia. According to some geographers, Physical geography, physiographically, Eurasia is a single supercontinent. The concept of Europe and Asia as distinct continents d ...
,
Russia
Russia, or the Russian Federation, is a country spanning Eastern Europe and North Asia. It is the list of countries and dependencies by area, largest country in the world, and extends across Time in Russia, eleven time zones, sharing Borders ...
, and
Persia
Iran, officially the Islamic Republic of Iran (IRI) and also known as Persia, is a country in West Asia. It borders Iraq to the west, Turkey, Azerbaijan, and Armenia to the northwest, the Caspian Sea to the north, Turkmenistan to the nort ...
.
Biomineral
Atacamite occurs as a biomineral in the jaws of
bloodworms.
Atacamite-235102.jpg, Atacamite prisms from Chile
Harvard Museum of Natural History. Atacamite. Miraflores Mine, Tierra Amarilla, Atacama, Chile (DerHexer) 2012-07-20.jpg, Atacamite from Chile displayed in the Harvard Museum of Natural History
The Harvard Museum of Natural History (HMNH) is a natural history museum housed in the University Museum Building, located on the campus of Harvard University in Cambridge, Massachusetts. It features 16 galleries with 12,000 specimens drawn fr ...
Atacamite-168148.jpg, Atacamite from Mt. Gunson, South Australia
References
External links
Mineral galleries
Copper(II) minerals
Chloride minerals
Hydroxide minerals
Orthorhombic minerals
Minerals in space group 62
Minerals described in 1802
{{Halide-mineral-stub