2,6-Diisopropylaniline on:
[Wikipedia]
[Google]
[Amazon]
2,6-Diisopropylaniline is an organic compound with the formula H2NC6H3(CHMe2)2 (Me = CH3). It is a colorless liquid although, like many anilines, samples can appear yellow or brown. 2,6-Diisopropylaniline is a bulky aromatic amine that is often used to make ligands in 
coordination chemistry
A coordination complex consists of a central atom or ion, which is usually metallic and is called the ''coordination centre'', and a surrounding array of bound molecules or ions, that are in turn known as ''ligands'' or complexing agents. Many ...
. The Schrock carbene
A transition metal carbene complex is an organometallic compound featuring a divalent organic ligand. The divalent organic ligand coordinated to the metal center is called a carbene. Carbene complexes for almost all transition metals have been rep ...
s often are transition metal imido complexes derived from this aniline. Condensation with diacetylpyridine and acetylacetone
Acetylacetone is an organic compound with the chemical formula . It is a colorless liquid, classified as a 1,3-diketone. It exists in equilibrium with a tautomer . These tautomers interconvert so rapidly under most conditions that they are tre ...
gives, respectively, diiminopyridine Diiminopyridines (DIP, also known a pyridine diimines, PDIs) are a class of diimine ligands. They featuring a pyridine nucleus with imine sidearms appended to the 2,6–positions. The three nitrogen centres bind metals in a tridentate fashion, fo ...
and NacNac ligands.
left, 220px, Typical Schrock-style olefin metathesis catalysts feature bulky imides as spectator ligands.">spectator_ligand.html" ;"title="olefin metathesis catalysts feature bulky imides as spectator ligand">olefin metathesis catalysts feature bulky imides as spectator ligands.
References