2,2'-Biquinoline
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2,2′-Biquinoline is an
organic compound Some chemical authorities define an organic compound as a chemical compound that contains a carbon–hydrogen or carbon–carbon bond; others consider an organic compound to be any chemical compound that contains carbon. For example, carbon-co ...
with the formula (C9H6N)2. It is one of several bi
quinoline Quinoline is a heterocyclic aromatic organic compound with the chemical formula C9H7N. It is a colorless hygroscopic liquid with a strong odor. Aged samples, especially if exposed to light, become yellow and later brown. Quinoline is only sl ...
s. It is prepared by reductive coupling of 2-chloroquinoline. It is a colorimetric indicator for
organolithium compound In organometallic chemistry, organolithium reagents are chemical compounds that contain carbon–lithium (C–Li) bonds. These reagents are important in organic synthesis, and are frequently used to transfer the organic group or the lithium atom ...
s.


Ligand properties

2,2′-Biquinoline is a
bidentate ligand In coordination chemistry, a ligand is an ion or molecule with a functional group that binds to a central metal atom to form a coordination complex. The bonding with the metal generally involves formal donation of one or more of the ligand's ...
. Unlike the related complexes of
2,2′-bipyridine 2,2′-Bipyridine (bipy or bpy, pronounced ) is an organic compound with the formula . This colorless solid is an important isomer of the bipyridine family. It is a bidentate chelation, chelating ligand, forming complexes with many transition meta ...
, the metal does not typically occupy the plane of the biquinoline.


References

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