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Yttrium Orthovanadate
Yttrium orthovanadate (YVO4) is a transparent crystal. Undoped YVO4 is also used to make efficient high-power polarizing prisms similar to Glan–Taylor prisms. There are two principal applications for doped Yttrium orthovanadate: *Doped with neodymium it forms Nd:YVO4, an active laser medium used in diode-pumped solid-state lasers. *Doped with europium it forms Eu:YVO4, the dominant red phosphor used in cathode ray tubes especially in color TVs. Basic properties *Crystal structure: **Zircon tetragonal ( tetragonal bipyramidal) ** Space group D4h ** Lattice parameters ''a'' = ''b'' = 7.119 Å, ''c'' = 6.290 Å *Density: 4.24 g/cm3 *Melting point: 1810–1940 °C *Mohs hardness: glass-like, ~5 *Knoop hardness: 480 kg/mm2 *Thermal expansion coefficient: ** αa = 4.43×10−6/ K ** αc = 11.37×10−6/K *Thermal conductivity coefficient: **parallel to ''c''-axis: 5.23 W·m−1·K−1 **perpendicular to ''c''-axis: 5.10 W·m−1·K−1 * Refractive indices, bi ...
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Glan–Taylor Prism
A Glan–Taylor prism is a type of prism which is used as a polarizer or polarizing beam splitter. It is one of the most common types of modern polarizing prism. It was first described by Archard and Taylor in 1948. The prism is made of two right-angled prisms of calcite (or sometimes other birefringent materials) separated on their long faces with an air gap. The optical axes of the calcite crystals are aligned parallel to the plane of reflection. Total internal reflection of ''s''-polarized light at the air gap ensures that only ''p''-polarized light is transmitted by the device. Because the angle of incidence at the gap can be reasonably close to Brewster's angle, unwanted reflection of ''p''-polarized light is reduced, giving the Glan–Taylor prism better transmission than the Glan–Foucault design. Note that while the transmitted beam is completely polarized, the reflected beam is not. The sides of the crystal can be polished to allow the reflected beam to exit or can be ...
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Mohs Scale Of Mineral Hardness
The Mohs scale of mineral hardness () is a qualitative ordinal scale, from 1 to 10, characterizing scratch resistance of various minerals through the ability of harder material to scratch softer material. The scale was introduced in 1812 by the German geologist and mineralogist Friedrich Mohs, in his book ''"Versuch einer Elementar-Methode zur naturhistorischen Bestimmung und Erkennung der Fossilien"''; it is one of several definitions of hardness in materials science, some of which are more quantitative. The method of comparing hardness by observing which minerals can scratch others is of great antiquity, having been mentioned by Theophrastus in his treatise ''On Stones'', , followed by Pliny the Elder in his '' Naturalis Historia'', . The Mohs scale is useful for identification of minerals in the field, but is not an accurate predictor of how well materials endure in an industrial setting – ''toughness''. Minerals The Mohs scale of mineral hardness is based on the ...
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Vanadates
Vanadates can refer to: * Ammonium vanadate (other) Ammonium vanadate may refer to: * Ammonium metavanadate (ammonium trioxovanadate(V)), NH4VO3 * Ammonium orthovanadate (ammonium tetraoxovanadate(V)), (NH4)3VO4, a compound related to Ammonium metavanadate * Ammonium hexavanadate, (NH4)2V6O16, a ... * Sodium vanadate (other) {{disambig ...
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Neodymium-doped Yttrium Orthovanadate
Neodymium-doped yttrium orthovanadate (Nd:YVO4) is a crystalline material formed by adding neodymium ions to yttrium orthovanadate. It is commonly used as an active laser medium for diode-pumped solid-state lasers. It comes as a transparent blue-tinted material. It is birefringent, therefore rods made of it are usually rectangular. As in all neodymium-doped laser crystals, the lasing action of Nd:YVO4 is due to its content of neodymium ions, which may be excited by visible or infrared light, and undergo an electronic transition resulting in emission of coherent infrared light at a lower frequency, usually at 1064 nm (other transitions in Nd are available, and can be selected for by external optics). Basic properties * Atomic density: ~1.37×1020 atoms/cm3 * Crystal structure: **zircon tetragonal ( tetragonal bipyramidal) ** space group D4h ** ''a''=''b''=7.12, ''c''=6.29 *Density: 4.22 g/cm3 *Mohs hardness: Glass-like, ~5 *Thermal expansion coefficient: ** αa=4.43×10−6 ...
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Wavelength
In physics, the wavelength is the spatial period of a periodic wave—the distance over which the wave's shape repeats. It is the distance between consecutive corresponding points of the same phase on the wave, such as two adjacent crests, troughs, or zero crossings, and is a characteristic of both traveling waves and standing waves, as well as other spatial wave patterns. The inverse of the wavelength is called the spatial frequency. Wavelength is commonly designated by the Greek letter '' lambda'' (λ). The term ''wavelength'' is also sometimes applied to modulated waves, and to the sinusoidal envelopes of modulated waves or waves formed by interference of several sinusoids. Assuming a sinusoidal wave moving at a fixed wave speed, wavelength is inversely proportional to frequency of the wave: waves with higher frequencies have shorter wavelengths, and lower frequencies have longer wavelengths. Wavelength depends on the medium (for example, vacuum, air, or water) that ...
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Sellmeier Equation
The Sellmeier equation is an empirical relationship between refractive index and wavelength for a particular transparent medium. The equation is used to determine the dispersion of light in the medium. It was first proposed in 1872 by Wolfgang Sellmeier and was a development of the work of Augustin Cauchy on Cauchy's equation for modelling dispersion. The equation In its original and the most general form, the Sellmeier equation is given as : n^2(\lambda) = 1 + \sum_i \frac , where ''n'' is the refractive index, ''λ'' is the wavelength, and ''B''i and ''C''i are experimentally determined ''Sellmeier coefficients''. These coefficients are usually quoted for λ in micrometres. Note that this λ is the vacuum wavelength, not that in the material itself, which is λ/n. A different form of the equation is sometimes used for certain types of materials, e.g. crystals. Each term of the sum representing an absorption resonance of strength ''B''i at a wavelength . For example, the ...
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Micrometre
The micrometre (American and British English spelling differences#-re, -er, international spelling as used by the International Bureau of Weights and Measures; SI symbol: μm) or micrometer (American and British English spelling differences#-re, -er, American spelling), also commonly known as a micron, is a unit of length in the International System of Units (SI) equalling (SI standard prefix "micro-" = ); that is, one millionth of a metre (or one thousandth of a millimetre, , or about ). The nearest smaller common SI unit is the nanometre, equivalent to one thousandth of a micrometre, one millionth of a millimetre or one billionth of a metre (). The micrometre is a common unit of measurement for wavelengths of infrared radiation as well as sizes of biological cell (biology), cells and bacteria, and for grading wool by the diameter of the fibres. The width of a single human hair ranges from approximately 20 to . The longest human chromosome, chromosome 1 (human), chromosome ...
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Birefringence
Birefringence is the optical property of a material having a refractive index that depends on the polarization and propagation direction of light. These optically anisotropic materials are said to be birefringent (or birefractive). The birefringence is often quantified as the maximum difference between refractive indices exhibited by the material. Crystals with non-cubic crystal structures are often birefringent, as are plastics under mechanical stress. Birefringence is responsible for the phenomenon of double refraction whereby a ray of light, when incident upon a birefringent material, is split by polarization into two rays taking slightly different paths. This effect was first described by Danish scientist Rasmus Bartholin in 1669, who observed it in calcite, a crystal having one of the strongest birefringences. In the 19th century Augustin-Jean Fresnel described the phenomenon in terms of polarization, understanding light as a wave with field components in transverse po ...
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Refractive Index
In optics, the refractive index (or refraction index) of an optical medium is a dimensionless number that gives the indication of the light bending ability of that medium. The refractive index determines how much the path of light is bent, or refracted, when entering a material. This is described by Snell's law of refraction, , where ''θ''1 and ''θ''2 are the angle of incidence and angle of refraction, respectively, of a ray crossing the interface between two media with refractive indices ''n''1 and ''n''2. The refractive indices also determine the amount of light that is reflected when reaching the interface, as well as the critical angle for total internal reflection, their intensity ( Fresnel's equations) and Brewster's angle. The refractive index can be seen as the factor by which the speed and the wavelength of the radiation are reduced with respect to their vacuum values: the speed of light in a medium is , and similarly the wavelength in that medium is , wher ...
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Watt
The watt (symbol: W) is the unit of power or radiant flux in the International System of Units (SI), equal to 1 joule per second or 1 kg⋅m2⋅s−3. It is used to quantify the rate of energy transfer. The watt is named after James Watt (1736–1819), an 18th-century Scottish inventor, mechanical engineer, and chemist who improved the Newcomen engine with his own steam engine in 1776. Watt's invention was fundamental for the Industrial Revolution. Overview When an object's velocity is held constant at one metre per second against a constant opposing force of one newton, the rate at which work is done is one watt. : \mathrm In terms of electromagnetism, one watt is the rate at which electrical work is performed when a current of one ampere (A) flows across an electrical potential difference of one volt (V), meaning the watt is equivalent to the volt-ampere (the latter unit, however, is used for a different quantity from the real power of an electrical c ...
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Thermal Conductivity
The thermal conductivity of a material is a measure of its ability to conduct heat. It is commonly denoted by k, \lambda, or \kappa. Heat transfer occurs at a lower rate in materials of low thermal conductivity than in materials of high thermal conductivity. For instance, metals typically have high thermal conductivity and are very efficient at conducting heat, while the opposite is true for insulating materials like Rockwool or Styrofoam. Correspondingly, materials of high thermal conductivity are widely used in heat sink applications, and materials of low thermal conductivity are used as thermal insulation. The reciprocal of thermal conductivity is called thermal resistivity. The defining equation for thermal conductivity is \mathbf = - k \nabla T, where \mathbf is the heat flux, k is the thermal conductivity, and \nabla T is the temperature gradient. This is known as Fourier's Law for heat conduction. Although commonly expressed as a scalar, the most general form ...
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Kelvin
The kelvin, symbol K, is the primary unit of temperature in the International System of Units (SI), used alongside its prefixed forms and the degree Celsius. It is named after the Belfast-born and University of Glasgow-based engineer and physicist William Thomson, 1st Baron Kelvin (1824–1907). The Kelvin scale is an absolute thermodynamic temperature scale, meaning it uses absolute zero as its null (zero) point. Historically, the Kelvin scale was developed by shifting the starting point of the much-older Celsius scale down from the melting point of water to absolute zero, and its increments still closely approximate the historic definition of a degree Celsius, but since 2019 the scale has been defined by fixing the Boltzmann constant to be exactly . Hence, one kelvin is equal to a change in the thermodynamic temperature that results in a change of thermal energy by . The temperature in degree Celsius is now defined as the temperature in kelvins minus 273.15, mea ...
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