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UCl4
Uranium tetrachloride is an inorganic compound, a salt of uranium and chlorine, with the formula UCl4. It is a hygroscopic olive-green solid. It was used in the electromagnetic isotope separation (EMIS) process of uranium enrichment. It is one of the main starting materials for organouranium chemistry. Synthesis and structure Uranium tetrachloride is synthesised generally by the reaction of uranium trioxide (UO3) and hexachloropropene. Solvent UCl4 adducts can be formed by a simpler reaction of UI4 with hydrogen chloride in organic solvents. According to X-ray crystallography the uranium centers are eight-coordinate, being surrounded by eight chlorine atoms, four at 264 pm and the other four at 287pm. Chemical properties Dissolution in protic solvents is more complicated. When UCl4 is added to water the uranium aqua ion is formed. :UCl4 + H2O → (H2O)sup>4+ + 4Cl− The aqua ion (H2O)sup>4+, (x is 8 or 9) is strongly hydrolyzed. : (H2O)sup>4+ (H2O)(OH)sup>3+ + H+ ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Uranium Trichloride
Uranium(III) chloride, UCl3, is a water soluble salt of uranium. UCl3 is used mostly to reprocess spent nuclear fuel. Uranium(III) chloride is synthesized in various ways from uranium(IV) chloride; however, UCl3 is less stable than UCl4. Preparation There are two ways to synthesize uranium(III) chloride. The following processes describe how to produce uranium(III) chloride. (1) In a mixture of NaCl-KCl at 670–710 °C, add uranium tetrachloride with uranium metal. :3 UCl4 + U → 4UCl3 (2) Heat uranium(IV) chloride in hydrogen gas. :2 UCl4 + H2 → 2UCl3 + 2HCl Properties In solid uranium(III) chloride each uranium atom has nine chlorine atoms as near neighbours, at approximately the same distance, in a tricapped trigonal prismatic configuration. Uranium(III) chloride is a green crystalline solid at room temperature. UCl3 melts at 837 °C and boils at 1657 °C. Uranium(III) chloride has a density of 5500 kg/m3 or 5.500 g/cm3. Its composition by weig ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Dimethyl Formamide
Dimethylformamide is an organic compound with the formula ( CH3)2NC(O)H. Commonly abbreviated as DMF (although this initialism is sometimes used for dimethylfuran, or dimethyl fumarate), this colourless liquid is miscible with water and the majority of organic liquids. DMF is a common solvent for chemical reactions. Dimethylformamide is odorless, but technical-grade or degraded samples often have a fishy smell due to impurity of dimethylamine. Dimethylamine degradation impurities can be removed by sparging samples with an inert gas such as argon or by sonicating the samples under reduced pressure. As its name indicates, it is structurally related to formamide, having two methyl groups in the place of the two hydrogens. DMF is a polar (hydrophilic) aprotic solvent with a high boiling point. It facilitates reactions that follow polar mechanisms, such as SN2 reactions. Structure and properties As for most amides, the spectroscopic evidence indicates partial double bond characte ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Enriched Uranium
Enriched uranium is a type of uranium in which the percent composition of uranium-235 (written 235U) has been increased through the process of isotope separation. Naturally occurring uranium is composed of three major isotopes: uranium-238 (238U with 99.2739–99.2752% natural abundance), uranium-235 (235U, 0.7198–0.7202%), and uranium-234 (234U, 0.0050–0.0059%). 235U is the only nuclide existing in nature (in any appreciable amount) that is fissile with thermal neutrons. Enriched uranium is a critical component for both civil nuclear power generation and military nuclear weapons. The International Atomic Energy Agency attempts to monitor and control enriched uranium supplies and processes in its efforts to ensure nuclear power generation safety and curb nuclear weapons proliferation. There are about 2,000 tonnes of highly enriched uranium in the world, produced mostly for nuclear power, nuclear weapons, naval propulsion, and smaller quantities for research reactors ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Depleted Uranium
Depleted uranium (DU; also referred to in the past as Q-metal, depletalloy or D-38) is uranium with a lower content of the fissile isotope than natural uranium.: "Depleted uranium possesses only 60% of the radioactivity of natural uranium, having been 'depleted' of much of its most highly radioactive U234 and U235 isotopes." Natural uranium contains about , while the DU used by the U.S. Department of Defense contains or less. The less radioactive and non-fissile constitutes the main component of depleted uranium. Uses of DU take advantage of its very high density of ( denser than lead). Civilian uses include counterweights in aircraft, radiation shielding in medical radiation therapy and industrial radiography equipment, and containers for transporting radioactive materials. Military uses include Vehicle armour, armor plating and Armor-piercing shot and shell, armor-piercing projectiles. Most depleted uranium arises as a by-product of the production of enriched uranium f ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Magnetic Field
A magnetic field is a vector field that describes the magnetic influence on moving electric charges, electric currents, and magnetic materials. A moving charge in a magnetic field experiences a force perpendicular to its own velocity and to the magnetic field. A permanent magnet's magnetic field pulls on ferromagnetic materials such as iron, and attracts or repels other magnets. In addition, a nonuniform magnetic field exerts minuscule forces on "nonmagnetic" materials by three other magnetic effects: paramagnetism, diamagnetism, and antiferromagnetism, although these forces are usually so small they can only be detected by laboratory equipment. Magnetic fields surround magnetized materials, and are created by electric currents such as those used in electromagnets, and by electric fields varying in time. Since both strength and direction of a magnetic field may vary with location, it is described mathematically by a function assigning a vector to each point of space ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Plasma (physics)
Plasma ()πλάσμα , Henry George Liddell, Robert Scott, ''A Greek English Lexicon'', on Perseus is one of the four fundamental states of matter. It contains a significant portion of charged particles – ions and/or s. The presence of these charged particles is what primarily sets plasma apart from the other fundamental states of matter. It is the most abundant form of ordi ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Iraq
Iraq,; ku, عێراق, translit=Êraq officially the Republic of Iraq, '; ku, کۆماری عێراق, translit=Komarî Êraq is a country in Western Asia. It is bordered by Turkey to the north, Iran to the east, the Persian Gulf and Kuwait to the southeast, Saudi Arabia to the south, Jordan to the southwest and Syria to the west. The capital and largest city is Baghdad. Iraq is home to diverse ethnic groups including Iraqi Arabs, Kurds, Turkmens, Assyrians, Armenians, Yazidis, Mandaeans, Persians and Shabakis with similarly diverse geography and wildlife. The vast majority of the country's 44 million residents are Muslims – the notable other faiths are Christianity, Yazidism, Mandaeism, Yarsanism and Zoroastrianism. The official languages of Iraq are Arabic and Kurdish; others also recognised in specific regions are Neo-Aramaic, Turkish and Armenian. Starting as early as the 6th millennium BC, the fertile alluvial plains between Iraq's Tigris and Euphrates ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Uranium Hexafluoride
Uranium hexafluoride (), (sometimes called "hex") is an inorganic compound with the formula UF6. Uranium hexafluoride is a volatile white solid that reacts with water, releasing corrosive hydrofluoric acid. The compound reacts mildly with aluminium, forming a thin surface layer of AlF3 that resists any further reaction from the compound. UF6 is used in the process of enriching uranium, which produces fuel for nuclear reactors and nuclear weapons. Preparation Milled uranium ore—U3O8 or "yellowcake"—is dissolved in nitric acid, yielding a solution of uranyl nitrate UO2(NO3)2. Pure uranyl nitrate is obtained by solvent extraction, then treated with ammonia to produce ammonium diuranate ("ADU", (NH4)2U2O7). Reduction with hydrogen gives UO2, which is converted with hydrofluoric acid (HF) to uranium tetrafluoride, UF4. Oxidation with fluorine yields UF6. During nuclear reprocessing, uranium is reacted with chlorine trifluoride to give UF6: :U + 2 ClF3 → UF6 + Cl2 Prope ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Calutron
A calutron is a mass spectrometer originally designed and used for separating the isotopes of uranium. It was developed by Ernest Lawrence during the Manhattan Project and was based on his earlier invention, the cyclotron. Its name was derived from California University Cyclotron, in tribute to Lawrence's institution, the University of California, where it was invented. Calutrons were used in the industrial-scale Y-12 uranium enrichment plant at the Clinton Engineer Works in Oak Ridge, Tennessee. The enriched uranium produced was used in the Little Boy atomic bomb that was detonated over Hiroshima on 6 August 1945. The calutron is a type of sector mass spectrometer, an instrument in which a sample is ionized and then accelerated by electric fields and deflected by magnetic fields. The ions ultimately collide with a plate and produce a measurable electric current. Since the ions of the different isotopes have the same electric charge but different masses, the heavier is ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Ernest O
Ernest is a given name derived from Germanic word ''ernst'', meaning "serious". Notable people and fictional characters with the name include: People *Archduke Ernest of Austria (1553–1595), son of Maximilian II, Holy Roman Emperor *Ernest, Margrave of Austria (1027–1075) * Ernest, Duke of Bavaria (1373–1438) * Ernest, Duke of Opava (c. 1415–1464) * Ernest, Margrave of Baden-Durlach (1482–1553) *Ernest, Landgrave of Hesse-Rheinfels (1623–1693) * Ernest Augustus, Elector of Brunswick-Lüneburg (1629–1698) * Ernest, Count of Stolberg-Ilsenburg (1650–1710) *Ernest Augustus, King of Hanover (1771–1851), son of King George III of Great Britain *Ernest II, Duke of Saxe-Coburg and Gotha (1818–1893), sovereign duke of the Duchy of Saxe-Coburg and Gotha *Ernest Augustus, Crown Prince of Hanover (1845–1923) * Ernest, Landgrave of Hesse-Philippsthal (1846–1925) * Ernest Augustus, Prince of Hanover (1914–1987) * Prince Ernst August of Hanover (born 1954) * Prince ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Y-12 National Security Complex
The Y-12 National Security Complex is a United States Department of Energy National Nuclear Security Administration facility located in Oak Ridge, Tennessee, near the Oak Ridge National Laboratory. It was built as part of the Manhattan Project for the purpose of enriching uranium for the first atomic bombs. It is considered the birthplace of the atomic bomb. In the years after World War II, it has been operated as a manufacturing facility for nuclear weapons components and related defense purposes. Y-12 is managed and operated under contract by Consolidated Nuclear Security, LLC (CNS), which is composed of member companies Bechtel National Inc., Leidos Inc., Orbital ATK, Inc, and SOC LLC, with Booz Allen Hamilton Inc. as a teaming subcontractor. CNS also operates Pantex Plant in Texas. History Y-12 is the World War II code name for the electromagnetic isotope separation plant producing enriched uranium at the Clinton Engineer Works in Oak Ridge, Tennessee, as part o ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Uranium Dioxide
Uranium dioxide or uranium(IV) oxide (), also known as urania or uranous oxide, is an oxide of uranium, and is a black, radioactive, crystalline powder that naturally occurs in the mineral uraninite. It is used in nuclear fuel rods in nuclear reactors. A mixture of uranium and plutonium dioxides is used as MOX fuel. Prior to 1960, it was used as yellow and black color in ceramic glazes and glass. Production Uranium dioxide is produced by reducing uranium trioxide with hydrogen. :UO3 + H2 → UO2 + H2O at 700 °C (973 K) This reaction plays an important part in the creation of nuclear fuel through nuclear reprocessing and uranium enrichment. Chemistry Structure The solid is isostructural with (has the same structure as) fluorite ( calcium fluoride), where each U is surrounded by eight O nearest neighbors in a cubic arrangement. In addition, the dioxides of cerium, thorium, and the transuranic elements from neptunium through californium have the same structu ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
