Transuranic Element
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Transuranic Element
The transuranium elements (also known as transuranic elements) are the chemical elements with atomic numbers greater than 92, which is the atomic number of uranium. All of these elements are unstable and decay radioactively into other elements. With the exception of neptunium and plutonium (which have been found in trace amounts in nature), all do not occur naturally on Earth and are synthetic. Overview Of the elements with atomic numbers 1 to 92, most can be found in nature, having stable isotopes (such as hydrogen) or very long-lived radioisotopes (such as uranium), or existing as common decay products of the decay of uranium and thorium (such as radon). The exceptions are elements 43, 61, 85, and 87; all four occur in nature, but only in very minor branches of the uranium and thorium decay chains, and thus all save element 87 were first discovered by synthesis in the laboratory rather than in nature (and even element 87 was discovered from purified samples of its paren ...
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Periodic Table
The periodic table, also known as the periodic table of the (chemical) elements, is a rows and columns arrangement of the chemical elements. It is widely used in chemistry, physics, and other sciences, and is generally seen as an icon of chemistry. It is a graphic formulation of the periodic law, which states that the properties of the chemical elements exhibit an approximate periodic dependence on their atomic numbers. The table is divided into four roughly rectangular areas called blocks. The rows of the table are called periods, and the columns are called groups. Elements from the same group of the periodic table show similar chemical characteristics. Trends run through the periodic table, with nonmetallic character (keeping their own electrons) increasing from left to right across a period, and from down to up across a group, and metallic character (surrendering electrons to other atoms) increasing in the opposite direction. The underlying reason for these trends is ...
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Half-life
Half-life (symbol ) is the time required for a quantity (of substance) to reduce to half of its initial value. The term is commonly used in nuclear physics to describe how quickly unstable atoms undergo radioactive decay or how long stable atoms survive. The term is also used more generally to characterize any type of exponential (or, rarely, non-exponential) decay. For example, the medical sciences refer to the biological half-life of drugs and other chemicals in the human body. The converse of half-life (in exponential growth) is doubling time. The original term, ''half-life period'', dating to Ernest Rutherford's discovery of the principle in 1907, was shortened to ''half-life'' in the early 1950s. Rutherford applied the principle of a radioactive element's half-life in studies of age determination of rocks by measuring the decay period of radium to lead-206. Half-life is constant over the lifetime of an exponentially decaying quantity, and it is a characteristic unit for ...
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Curium
Curium is a transuranic, radioactive chemical element with the symbol Cm and atomic number 96. This actinide element was named after eminent scientists Marie and Pierre Curie, both known for their research on radioactivity. Curium was first intentionally made by the team of Glenn T. Seaborg, Ralph A. James, and Albert Ghiorso in 1944, using the cyclotron at Berkeley. They bombarded the newly discovered element plutonium (the isotope 239Pu) with alpha particles. This was then sent to the Metallurgical Laboratory at University of Chicago where a tiny sample of curium was eventually separated and identified. The discovery was kept secret until after the end of World War II. The news was released to the public in November 1947. Most curium is produced by bombarding uranium or plutonium with neutrons in nuclear reactors – one tonne of spent nuclear fuel contains ~20 grams of curium. Curium is a hard, dense, silvery metal with a high melting and boiling point for an actinide. It ...
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Particle Accelerator
A particle accelerator is a machine that uses electromagnetic fields to propel charged particles to very high speeds and energies, and to contain them in well-defined beams. Large accelerators are used for fundamental research in particle physics. The largest accelerator currently active is the Large Hadron Collider (LHC) near Geneva, Switzerland, operated by the CERN. It is a collider accelerator, which can accelerate two beams of protons to an energy of 6.5  TeV and cause them to collide head-on, creating center-of-mass energies of 13 TeV. Other powerful accelerators are, RHIC at Brookhaven National Laboratory in New York and, formerly, the Tevatron at Fermilab, Batavia, Illinois. Accelerators are also used as synchrotron light sources for the study of condensed matter physics. Smaller particle accelerators are used in a wide variety of applications, including particle therapy for oncological purposes, radioisotope production for medical diagnostics, ion ...
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Nuclear Reactor
A nuclear reactor is a device used to initiate and control a fission nuclear chain reaction or nuclear fusion reactions. Nuclear reactors are used at nuclear power plants for electricity generation and in nuclear marine propulsion. Heat from nuclear fission is passed to a working fluid (water or gas), which in turn runs through steam turbines. These either drive a ship's propellers or turn electrical generators' shafts. Nuclear generated steam in principle can be used for industrial process heat or for district heating. Some reactors are used to produce isotopes for medical and industrial use, or for production of weapons-grade plutonium. , the International Atomic Energy Agency reports there are 422 nuclear power reactors and 223 nuclear research reactors in operation around the world. In the early era of nuclear reactors (1940s), a reactor was known as a nuclear pile or atomic pile (so-called because the graphite moderator blocks of the first reactor were placed into a tall pi ...
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Synthetic Element
A synthetic element is one of 24 known chemical elements that do not occur naturally on Earth: they have been created by human manipulation of fundamental particles in a nuclear reactor, a particle accelerator, or the explosion of an atomic bomb; thus, they are called "synthetic", "artificial", or "man-made". The synthetic elements are those with atomic numbers 95–118, as shown in purple on the accompanying periodic table: these 24 elements were first created between 1944 and 2010. The mechanism for the creation of a synthetic element is to force additional protons into the nucleus of an element with an atomic number lower than 95. All synthetic elements are unstable, but they decay at widely varying rates: the half-lives of their longest-lived isotopes range from microseconds to millions of years. Five more elements that were created artificially are strictly speaking not ''synthetic'' because they were later found in nature in trace quantities: 43Tc, 61Pm, 85At, 93Np, and ...
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Plutonium-239
Plutonium-239 (239Pu or Pu-239) is an isotope of plutonium. Plutonium-239 is the primary fissile isotope used for the production of nuclear weapons, although uranium-235 is also used for that purpose. Plutonium-239 is also one of the three main isotopes demonstrated usable as fuel in thermal spectrum nuclear reactors, along with uranium-235 and uranium-233. Plutonium-239 has a half-life of 24,110 years. Nuclear properties The nuclear properties of plutonium-239, as well as the ability to produce large amounts of nearly pure 239Pu more cheaply than highly enriched weapons-grade uranium-235, led to its use in nuclear weapons and nuclear power plants. The fissioning of an atom of uranium-235 in the reactor of a nuclear power plant produces two to three neutrons, and these neutrons can be absorbed by uranium-238 to produce plutonium-239 and other isotopes. Plutonium-239 can also absorb neutrons and fission along with the uranium-235 in a reactor. Of all the common nuclear fuels ...
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Neptunium-239
Neptunium (93Np) is usually considered an artificial element, although trace quantities are found in nature, so a standard atomic weight cannot be given. Like all trace or artificial elements, it has no stable isotopes. The first isotope to be synthesized and identified was 239Np in 1940, produced by bombarding with neutrons to produce , which then underwent beta decay to . Trace quantities are found in nature from neutron capture reactions by uranium atoms, a fact not discovered until 1951. Twenty-five neptunium radioisotopes have been characterized, with the most stable being with a half-life of 2.14 million years, with a half-life of 154,000 years, and with a half-life of 396.1 days. All of the remaining radioactive isotopes have half-lives that are less than 4.5 days, and the majority of these have half-lives that are less than 50 minutes. This element also has five meta states, with the most stable being (t1/2 22.5 hours). The isotopes of neptunium range from to , t ...
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Uranium-239
Uranium (92U) is a naturally occurring radioactive element that has no stable isotope. It has two primordial isotopes, uranium-238 and uranium-235, that have long half-lives and are found in appreciable quantity in the Earth's crust. The decay product uranium-234 is also found. Other isotopes such as uranium-233 have been produced in breeder reactors. In addition to isotopes found in nature or nuclear reactors, many isotopes with far shorter half-lives have been produced, ranging from 214U to 242U (with the exceptions of 220U and 241U). The standard atomic weight of natural uranium is . Naturally occurring uranium is composed of three major isotopes, uranium-238 (99.2739–99.2752% natural abundance), uranium-235 (0.7198–0.7202%), and uranium-234 (0.0050–0.0059%). All three isotopes are radioactive (i.e., they are radioisotopes), and the most abundant and stable is uranium-238, with a half-life of (close to the age of the Earth). Uranium-238 is an alpha emitter, decaying ...
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Neutron
The neutron is a subatomic particle, symbol or , which has a neutral (not positive or negative) charge, and a mass slightly greater than that of a proton. Protons and neutrons constitute the nuclei of atoms. Since protons and neutrons behave similarly within the nucleus, and each has a mass of approximately one atomic mass unit, they are both referred to as nucleons. Their properties and interactions are described by nuclear physics. Protons and neutrons are not elementary particles; each is composed of three quarks. The chemical properties of an atom are mostly determined by the configuration of electrons that orbit the atom's heavy nucleus. The electron configuration is determined by the charge of the nucleus, which is determined by the number of protons, or atomic number. The number of neutrons is the neutron number. Neutrons do not affect the electron configuration, but the sum of atomic and neutron numbers is the mass of the nucleus. Atoms of a chemical element t ...
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Uranium-238
Uranium-238 (238U or U-238) is the most common isotope of uranium found in nature, with a relative abundance of 99%. Unlike uranium-235, it is non-fissile, which means it cannot sustain a chain reaction in a thermal-neutron reactor. However, it is fissionable by fast neutrons, and is ''fertile'', meaning it can be transmuted to fissile plutonium-239. 238U cannot support a chain reaction because inelastic scattering reduces neutron energy below the range where fast fission of one or more next-generation nuclei is probable. Doppler broadening of 238U's neutron absorption resonances, increasing absorption as fuel temperature increases, is also an essential negative feedback mechanism for reactor control. Around 99.284% of natural uranium's mass is uranium-238, which has a half-life of 1.41 seconds (4.468 years, or 4.468 billion years). Due to its natural abundance and half-life relative to other radioactive elements, 238U produces ~40% of the radioactive heat produced within th ...
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Beta Decay
In nuclear physics, beta decay (β-decay) is a type of radioactive decay in which a beta particle (fast energetic electron or positron) is emitted from an atomic nucleus, transforming the original nuclide to an isobar of that nuclide. For example, beta decay of a neutron transforms it into a proton by the emission of an electron accompanied by an antineutrino; or, conversely a proton is converted into a neutron by the emission of a positron with a neutrino in so-called ''positron emission''. Neither the beta particle nor its associated (anti-)neutrino exist within the nucleus prior to beta decay, but are created in the decay process. By this process, unstable atoms obtain a more stable ratio of protons to neutrons. The probability of a nuclide decaying due to beta and other forms of decay is determined by its nuclear binding energy. The binding energies of all existing nuclides form what is called the nuclear band or valley of stability. For either electron or positron em ...
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