Smectic
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Smectic
Liquid crystal (LC) is a state of matter whose properties are between those of conventional liquids and those of solid crystals. For example, a liquid crystal may flow like a liquid, but its molecules may be oriented in a crystal-like way. There are many types of LC phases, which can be distinguished by their optical properties (such as textures). The contrasting textures arise due to molecules within one area of material ("domain") being oriented in the same direction but different areas having different orientations. LC materials may not always be in a LC state of matter (just as water may be ice or water vapor). Liquid crystals can be divided into 3 main types: *thermotropic, * lyotropic, and * metallotropic. Thermotropic and lyotropic liquid crystals consist mostly of organic molecules, although a few minerals are also known. Thermotropic LCs exhibit a phase transition into the LC phase as temperature changes. Lyotropic LCs exhibit phase transitions as a function of both ...
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Thermotropic
A liquid crystal phase is thermotropic if its order parameter is determined by temperature. At high temperatures, liquid crystals become an isotropic liquid and at low temperatures, they tend to glassify. In a thermotropic crystal, those phase transitions occur only at temperature extremes; the phase is insensitive to concentration. Most thermotropic liquid crystals are composed of rod-like molecules, and admit nematic, smectic, or cholesterolic phases. References * See also * Thermochromism Thermochromism is the property of substances to change color due to a change in temperature. A mood ring is an excellent example of this phenomenon, but thermochromism also has more practical uses, such as baby bottles which change to a differen ... * Thermotropic liquid crystals External links What are Liquid Crystals? Liquid crystals {{chemistry-stub ...
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Lyotropic
A liquid crystalline mesophase is called lyotropic (a portmanteau of lyo- "dissolve" and -tropic "change" ) if formed by dissolving an amphiphilic mesogen in a suitable solvent, under appropriate conditions of concentration, temperature and pressure. A mixture of soap and water is an everyday example of a lyotropic liquid crystal. Historically, the term was used to describe the common behavior of materials composed of amphiphilic molecules upon the addition of a solvent. Such molecules comprise a water-loving hydrophilic head-group (which may be ionic or non-ionic) attached to a water-hating, hydrophobic group. The micro-phase segregation of two incompatible components on a nanometer scale results in different type of solvent-induced extended anisotropic arrangement, depending on the volume balances between the hydrophilic part and hydrophobic part. In turn, they generate the long-range order of the phases, with the solvent molecules filling the space around the compounds to pr ...
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Liquid-crystal Display
A liquid-crystal display (LCD) is a flat-panel display A flat-panel display (FPD) is an electronic display used to display visual content such as text or images. It is present in consumer, medical, transportation, and industrial equipment. Flat-panel displays are thin, lightweight, provide better l ... or other Electro-optic modulator, electronically modulated optical device that uses the light-modulating properties of liquid crystals combined with polarizers. Liquid crystals do not emit light directly but instead use a backlight or reflector (photography), reflector to produce images in color or monochrome monitor, monochrome. LCDs are available to display arbitrary images (as in a general-purpose computer display) or fixed images with low information content, which can be displayed or hidden. For instance: preset words, digits, and seven-segment displays, as in a digital clock, are all good examples of devices with these displays. They use the same basic technology, exc ...
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Clays
Clay is a type of fine-grained natural soil material containing clay minerals (hydrous aluminium phyllosilicates, e.g. kaolin, Al2 Si2 O5( OH)4). Clays develop plasticity when wet, due to a molecular film of water surrounding the clay particles, but become hard, brittle and non–plastic upon drying or firing. Most pure clay minerals are white or light-coloured, but natural clays show a variety of colours from impurities, such as a reddish or brownish colour from small amounts of iron oxide. Clay is the oldest known ceramic material. Prehistoric humans discovered the useful properties of clay and used it for making pottery. Some of the earliest pottery shards have been dated to around 14,000 BC, and clay tablets were the first known writing medium. Clay is used in many modern industrial processes, such as paper making, cement production, and chemical filtering. Between one-half and two-thirds of the world's population live or work in buildings made with clay, often ...
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Privatdozent
''Privatdozent'' (for men) or ''Privatdozentin'' (for women), abbreviated PD, P.D. or Priv.-Doz., is an academic title conferred at some European universities, especially in German-speaking countries, to someone who holds certain formal qualifications that denote an ability (''facultas docendi'') and permission to teach (''venia legendi'') a designated subject at the highest level. To be granted the title Priv.-Doz. by a university, a recipient has to fulfill the criteria set by the university which usually require excellence in research, teaching, and further education. In its current usage, the title indicates that the holder has completed their habilitation and is therefore granted permission to teach and examine students independently without having a professorship. Conferment and roles A university faculty can confer the title to an academic who has a higher doctoral degree - usually in the form of a habilitation. The title, ''Privatdozent'', as such does not imply a sala ...
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Otto Lehmann (physicist)
Otto Lehmann (13 January 1855 in Konstanz, Germany – 17 June 1922 in Karlsruhe) was a German physicist and "father" of liquid crystal. Life Otto was the son of Franz Xavier Lehmann, a mathematics teacher in the Baden-Wurtemberg school system, with a strong interest in microscopes. Otto learned to experiment and keep records of this findings. Between 1872 and 1877, Lehmann studied natural sciences at the University of Strassburg and obtained the Ph.D. under crystallographer Paul Groth. Otto used polarizers in a microscope so that he might watch for birefringence appearing in the process of crystallization. Initially becoming a school teacher for physics, mathematics and chemistry in Mülhausen ( Alsace-Lorraine), he started university teaching at the RWTH Aachen University in 1883. In 1889, he succeeded Heinrich Hertz as head of the Institute of Physics in Karlsruhe. Lehmann received a letter from Friedrich Reinitzer asking for confirmation of some unusual observations. As Du ...
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Melting Point
The melting point (or, rarely, liquefaction point) of a substance is the temperature at which it changes state from solid to liquid. At the melting point the solid and liquid phase exist in equilibrium. The melting point of a substance depends on pressure and is usually specified at a standard pressure such as 1 atmosphere or 100 kPa. When considered as the temperature of the reverse change from liquid to solid, it is referred to as the freezing point or crystallization point. Because of the ability of substances to supercool, the freezing point can easily appear to be below its actual value. When the "characteristic freezing point" of a substance is determined, in fact, the actual methodology is almost always "the principle of observing the disappearance rather than the formation of ice, that is, the melting point." Examples For most substances, melting and freezing points are approximately equal. For example, the melting point ''and'' freezing point of mercury is . How ...
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Melting
Melting, or fusion, is a physical process that results in the phase transition of a substance from a solid to a liquid. This occurs when the internal energy of the solid increases, typically by the application of heat or pressure, which increases the substance's temperature to the melting point. At the melting point, the ordering of ions or molecules in the solid breaks down to a less ordered state, and the solid "melts" to become a liquid. Substances in the molten state generally have reduced viscosity as the temperature increases. An exception to this principle is the element sulfur, whose viscosity increases in the range of 160 °C to 180 °C due to polymerization. Some organic compounds melt through mesophases, states of partial order between solid and liquid. First order phase transition From a thermodynamics point of view, at the melting point the change in Gibbs free energy ''∆G'' of the substances is zero, but there are non-zero changes in the enthalpy ...
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Cholesteryl Benzoate
Cholesteryl benzoate, also called 5-cholesten-3-yl benzoate, is an organic chemical, an ester of cholesterol and benzoic acid. It is a liquid crystal material forming cholesteric liquid crystals with helical structure. It can be used with cholesteryl nonanoate and cholesteryl oleyl carbonate in some thermochromic liquid crystals. It is used in some hair colors, make-ups, and some other cosmetic preparations. It can be also used as a component of the liquid crystals used for liquid crystal displays. Cholesteryl benzoate was the first material in which liquid crystal properties were discovered. In the late 1880s Friedrich Reinitzer, an Austrian botanist Botany, also called , plant biology or phytology, is the science of plant life and a branch of biology. A botanist, plant scientist or phytologist is a scientist who specialises in this field. The term "botany" comes from the Ancient Greek wo ..., while studying the chemicals in plants, heated cholesteryl benzoate. At 145&nb ...
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Cholesteryl Benzoate
Cholesteryl benzoate, also called 5-cholesten-3-yl benzoate, is an organic chemical, an ester of cholesterol and benzoic acid. It is a liquid crystal material forming cholesteric liquid crystals with helical structure. It can be used with cholesteryl nonanoate and cholesteryl oleyl carbonate in some thermochromic liquid crystals. It is used in some hair colors, make-ups, and some other cosmetic preparations. It can be also used as a component of the liquid crystals used for liquid crystal displays. Cholesteryl benzoate was the first material in which liquid crystal properties were discovered. In the late 1880s Friedrich Reinitzer, an Austrian botanist Botany, also called , plant biology or phytology, is the science of plant life and a branch of biology. A botanist, plant scientist or phytologist is a scientist who specialises in this field. The term "botany" comes from the Ancient Greek wo ..., while studying the chemicals in plants, heated cholesteryl benzoate. At 145&nb ...
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Freezing Point
The melting point (or, rarely, liquefaction point) of a substance is the temperature at which it changes state from solid to liquid. At the melting point the solid and liquid phase exist in equilibrium. The melting point of a substance depends on pressure and is usually specified at a standard pressure such as 1 atmosphere or 100 kPa. When considered as the temperature of the reverse change from liquid to solid, it is referred to as the freezing point or crystallization point. Because of the ability of substances to supercool, the freezing point can easily appear to be below its actual value. When the "characteristic freezing point" of a substance is determined, in fact, the actual methodology is almost always "the principle of observing the disappearance rather than the formation of ice, that is, the melting point." Examples For most substances, melting and freezing points are approximately equal. For example, the melting point ''and'' freezing point of mercury is . Ho ...
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