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Pulsed Field Gradient
A pulsed field gradient is a short, timed pulse with spatial-dependent field intensity. Any gradient is identified by four characteristics: axis, strength, shape and duration. Pulsed field gradient (PFG) techniques are key to magnetic resonance imaging, spatially selective spectroscopy and studies of diffusion via diffusion ordered nuclear magnetic resonance spectroscopy (DOSY). PFG techniques are widely used as an alternative to phase cycling in modern NMR spectroscopy. Common field gradients in NMR The effect of a uniform magnetic field gradient in the z-direction on spin I, is considered to be a rotation around z-axis by an angle = γIGz; where Gz is the gradient magnitude (along the z-direction) and γI is the gyromagnetic ratio of spin I. It introduces a phase factor to the magnetizations: ''Φ (z,τ) = (γI)(Gz)(τ)'' The time duration τ is in the order of milliseconds. See also *Gradient enhanced NMR spectroscopy Gradient enhanced NMR is a method for obtaining high ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Magnetic Resonance Imaging
Magnetic resonance imaging (MRI) is a medical imaging technique used in radiology to form pictures of the anatomy and the physiological processes inside the body. MRI scanners use strong magnetic fields, magnetic field gradients, and radio waves to generate images of the organs in the body. MRI does not involve X-rays or the use of ionizing radiation, which distinguishes it from computed tomography (CT) and positron emission tomography (PET) scans. MRI is a medical application of nuclear magnetic resonance (NMR) which can also be used for imaging in other NMR applications, such as NMR spectroscopy. MRI is widely used in hospitals and clinics for medical diagnosis, staging and follow-up of disease. Compared to CT, MRI provides better contrast in images of soft tissues, e.g. in the brain or abdomen. However, it may be perceived as less comfortable by patients, due to the usually longer and louder measurements with the subject in a long, confining tube, although "open ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Diffusion
Diffusion is the net movement of anything (for example, atoms, ions, molecules, energy) generally from a region of higher concentration to a region of lower concentration. Diffusion is driven by a gradient in Gibbs free energy or chemical potential. It is possible to diffuse "uphill" from a region of lower concentration to a region of higher concentration, like in spinodal decomposition. The concept of diffusion is widely used in many fields, including physics (particle diffusion), chemistry, biology, sociology, economics, and finance (diffusion of people, ideas, and price values). The central idea of diffusion, however, is common to all of these: a substance or collection undergoing diffusion spreads out from a point or location at which there is a higher concentration of that substance or collection. A gradient is the change in the value of a quantity, for example, concentration, pressure, or temperature with the change in another variable, usually distance. A change in c ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Nuclear Magnetic Resonance Spectroscopy
Nuclear magnetic resonance spectroscopy, most commonly known as NMR spectroscopy or magnetic resonance spectroscopy (MRS), is a spectroscopic technique to observe local magnetic fields around atomic nuclei. The sample is placed in a magnetic field and the NMR signal is produced by excitation of the nuclei sample with radio waves into nuclear magnetic resonance, which is detected with sensitive radio receivers. The intramolecular magnetic field around an atom in a molecule changes the resonance frequency, thus giving access to details of the electronic structure of a molecule and its individual functional groups. As the fields are unique or highly characteristic to individual compounds, in modern organic chemistry practice, NMR spectroscopy is the definitive method to identify monomolecular organic compounds. The principle of NMR usually involves three sequential steps: # The alignment (polarization) of the magnetic nuclear spins in an applied, constant magnetic field B0. # The p ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Progress In Nuclear Magnetic Resonance Spectroscopy
Progress is the movement towards a refined, improved, or otherwise desired state. In the context of progressivism, it refers to the proposition that advancements in technology, science, and social organization have resulted, and by extension will continue to result, in an improved human condition; the latter may happen as a result of direct human action, as in social enterprise or through activism, or as a natural part of sociocultural evolution. The concept of progress was introduced in the early-19th-century social theories, especially social evolution as described by Auguste Comte and Herbert Spencer. It was present in the Enlightenment's philosophies of history. As a goal, social progress has been advocated by varying realms of political ideologies with different theories on how it is to be achieved. Measuring progress Specific indicators for measuring progress can range from economic data, technical innovations, change in the political or legal system, and questions bear ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Chem
Chem may refer to: * Chemistry practical waali mam * Chemistry *Chemical * ''Chem'' (journal), a scientific journal published by Cell Press *Post apocalyptic slang for "drugs", medicinal or otherwise in the Fallout video game series. In Ancient Egyptian usage: * ''Khem'' (also spelt ''Chem''), the Egyptian word for "black" *Min (god), in the past erroneously named ''Khem'' CHEM may refer to : *A metabolic panel: for instance, CHEM-7, which is the basic metabolic panel * CHEM-DT, a Canadian television channel See also *Chemo (other) Chemo is a prefix meaning ''chemical'' and commonly used as an abbreviation for chemotherapy. Chemo may also refer to: People * Chemo (musician), an English musician now known as Forest DLG * Chemo Soto, a Puerto Rican politician * José del Sol ... * Kemi, a place in Finland {{disambig ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Gyromagnetic Ratio
In physics, the gyromagnetic ratio (also sometimes known as the magnetogyric ratio in other disciplines) of a particle or system is the ratio of its magnetic moment to its angular momentum, and it is often denoted by the symbol , gamma. Its SI unit is the radian per second per tesla (rad⋅s−1⋅T−1) or, equivalently, the coulomb per kilogram (C⋅kg−1). The term "gyromagnetic ratio" is often used as a synonym for a ''different'' but closely related quantity, the -factor. The -factor only differs from the gyromagnetic ratio in being dimensionless. For a classical rotating body Consider a nonconductive charged body rotating about an axis of symmetry. According to the laws of classical physics, it has both a magnetic dipole moment due to the movement of charge and an angular momentum due to the movement of mass arising from its rotation. It can be shown that as long as its charge and mass density and flow are distributed identically and rotationally symmetric, ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Gradient Enhanced NMR Spectroscopy
Gradient enhanced NMR is a method for obtaining high resolution nuclear magnetic resonance spectra without the need for ''phase cycling''. Gradient methodology is used extensively for two purposes, either rephasing (selection) or dephasing (elimination) of a particular magnetization transfer pathway. It includes the application of magnetic field gradient pulses to select specific coherences. By using actively shielded gradients, a gradient pulse is applied during the evolution period of the selected coherence to dephase the transverse magnetization and another gradient pulse refocuses the desired coherences remaining during the acquisition period. Advantages *Significant reduction in measuring time *Reduced T1 artifacts *Elimination of phase cycling and difference methods *Possibility for three and four-quantum editing *The ability to detect resonances at the same chemical shift as a strong solvent resonance Resonance describes the phenomenon of increased amplitude that ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
