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Polychloroprene
Neoprene (also polychloroprene) is a family of synthetic rubbers that are produced by polymerization of chloroprene.Werner Obrecht, Jean-Pierre Lambert, Michael Happ, Christiane Oppenheimer-Stix, John Dunn and Ralf Krüger "Rubber, 4. Emulsion Rubbers" in Ullmann's Encyclopedia of Industrial Chemistry, 2012, Wiley-VCH, Weinheim. Neoprene exhibits good chemical stability and maintains flexibility over a wide temperature range. Neoprene is sold either as solid rubber or in latex form and is used in a wide variety of commercial applications, such as laptop sleeves, orthopaedic braces (wrist, knee, etc.), electrical insulation, medical gloves, liquid and sheet-applied elastomeric membranes or flashings, and automotive fan belts. Production Neoprene is produced by free-radical polymerization of chloroprene. In commercial production, this polymer is prepared by free radical emulsion polymerization. Polymerization is initiated using potassium persulfate. Bifunctional nucleophiles, me ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Chloroprene
Chloroprene (IUPAC name 2-chlorobuta-1,3-diene) is a chemical compound with the molecular formula CH2=CCl−CH=CH2. Chloroprene is a colorless volatile liquid, almost exclusively used as a monomer for the production of the polymer polychloroprene, better known as neoprene, a type of synthetic rubber. History Although it may have been discovered earlier, chloroprene was largely developed by DuPont during the early 1930s, specifically with the formation of neoprene in mind. The chemists Elmer K. Bolton, Wallace Carothers, Arnold Collins and Ira Williams are generally accredited with its development and commercialisation although the work was based upon that of Julius Arthur Nieuwland, with whom they collaborated. Production Chloroprene is produced in three steps from 1,3-butadiene: (i) chlorination, (ii) isomerization of part of the product stream, and (iii) dehydrochlorination of 3,4-dichlorobut-1-ene. Chlorine adds to 1,3-butadiene to afford a mixture of 3,4-dichlorobut-1-e ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Plasticizer
A plasticizer ( UK: plasticiser) is a substance that is added to a material to make it softer and more flexible, to increase its plasticity, to decrease its viscosity, and/or to decrease friction during its handling in manufacture. Plasticizers are commonly added to polymers and plastics such as PVC, either to facilitate the handling of the raw material during fabrication, or to meet the demands of the end product's application. Plasticizers are especially key to the usability of polyvinyl chloride (PVC), the third most widely used plastic. In the absence of plasticizers, PVC is hard and brittle; with plasticizers, it is suitable for products such as vinyl siding, roofing, vinyl flooring, rain gutters, plumbing, and electric wire insulation/coating. Plasticizers are also often added to concrete formulations to make them more workable and fluid for pouring, thus allowing the water contents to be reduced. Similarly, they are often added to clays, stucco, solid rocket fuel, ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Hydrogen Chloride
The Chemical compound, compound hydrogen chloride has the chemical formula and as such is a hydrogen halide. At room temperature, it is a colorless gas, which forms white fumes of hydrochloric acid upon contact with atmospheric water vapor. Hydrogen chloride gas and hydrochloric acid are important in technology and industry. Hydrochloric acid, the aqueous solution of hydrogen chloride, is also commonly given the formula HCl. Reactions Hydrogen chloride is a diatomic molecule, consisting of a hydrogen atom H and a chlorine atom Cl connected by a Polar-covalent bond, polar covalent bond. The chlorine atom is much more Electronegativity, electronegative than the hydrogen atom, which makes this bond polar. Consequently, the molecule has a large Molecular dipole moment, dipole moment with a negative partial charge (δ−) at the chlorine atom and a positive partial charge (δ+) at the hydrogen atom. In part because of its high polarity, HCl is very soluble in water (and in other ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Thiourea
Thiourea () is an organosulfur compound with the formula and the structure . It is structurally similar to urea (), with the oxygen atom replaced by sulfur atom (as implied by the '' thio-'' prefix). The properties of urea and thiourea differ significantly. Thiourea is a reagent in organic synthesis. Thioureas are a broad class of compounds with the formula Structure and bonding Thiourea is a planar molecule. The C=S bond distance is 1.71 Å. The C-N distances average 1.33 Å. The weakening of the C-S bond by C-N pi-bonding is indicated by the short C=S bond in thiobenzophenone, which is 1.63 Å. Thiourea occurs in two tautomeric forms, of which the thione form predominates in aqueous solutions. The equilibrium constant has been calculated as ''K''eq is . The thiol form, which is also known as an isothiourea, can be encountered in substituted compounds such as isothiouronium salts. : Production The global annual production of thiourea is around 8,000 tonnes, mo ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Dry Suit
A dry suit or drysuit provides the wearer with environmental protection by way of thermal insulation and exclusion of water, and is worn by underwater diving, divers, boating, boaters, List of water sports, water sports enthusiasts, and others who work or play in or near cold or contaminated water. A dry suit normally protects the whole body except the head, hands, and possibly the feet. In Hazmat suit, hazmat configurations, however, all of these are covered as well. The main difference between dry suits and wetsuits is that dry suits are designed to prevent water from entering. This generally allows better insulation, making them more suitable for use in cold water. Dry suits can be uncomfortably hot in warm or hot air, and are typically more expensive and more complex to don. For divers, they add some degree of operational complexity and hazard as the suit must be inflated and deflated with changes in depth in order to minimize "#Suit squeeze, squeeze" on descent or uncontrolle ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Julius Arthur Nieuwland
Julius Aloysius Arthur Nieuwland, CSC, (14 February 1878 – 11 June 1936) was a Belgian-born Holy Cross priest and professor of chemistry and botany at the University of Notre Dame, Indiana. He is known for his contributions to acetylene research and its use as the basis for one type of synthetic rubber, which eventually led to the invention of neoprene by DuPont. Life and work Nieuwland's parents emigrated from Hansbeke, Belgium in 1880 to South Bend, Indiana. As a young man, Nieuwland enrolled at the University of Notre Dame, where he studied Latin and Greek and received his undergraduate degree in 1899. He soon after began studies for the priesthood. Ordained in 1903, Nieuwland attended graduate school at The Catholic University of America, where he studied botany and chemistry. During his doctoral studies into the chemistry of acetylene, he discovered the chemical compound lewisite, which would later gain fame as a chemical warfare agent. Nieuwland had to be hospi ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Chain Scission
Chain scission is a term used in polymer chemistry describing the degradation of a polymer main chain. It is often caused by thermal stress (heat) or ionizing radiation (e.g. light, UV radiation or gamma radiation), often involving oxygen. During chain cleavage, the polymer chain is broken at a random point in the backbone to form two - mostly still highly molecular - fragments.Sebastian Kotzenburg, Michael Maskus, Oskar Nuyken: ''Polymere – Synthese, Eigenschaften und Anwendungen'', Springer Spektrum, 2014, S. 440–441, . Depolymerization, on the other hand, is the elimination of low molecular weight substances (monomer A monomer ( ; ''mono-'', "one" + '' -mer'', "part") is a molecule that can react together with other monomer molecules to form a larger polymer chain or two- or three-dimensional network in a process called polymerization. Classification Chemis ...s, dimers and suchlike) from a polymer.Otto-Albrecht Neumüller (Herausgeber): ''Römpps Chemie Lexikon ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Strain Crystallization
Strain crystallization is a phenomenon in which an initially amorphous solid material undergoes a phase transformation due to the application of strain. Strain crystallization occurs in natural rubber, as well as other elastomers and polymers. The phenomenon has important effects on strength and fatigue properties. How strain crystallization occurs Strain crystallization occurs when the chains of molecules in a material become ordered during deformation activities in some polymers and elastomers. The three primary factors that affect strain crystallization are the molecular structure of the polymer or elastomer, the temperature, and the deformation being applied to the material. If a polymer's molecular structure is too irregular, strain crystallization can not be induced because it is impossible to order the chains of molecules. In order to induce strain crystallization, the polymer or elastomer is stretched while its temperature is kept above its glass transition temperatur ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Ira Williams
Ira Williams (1894–1977) was an American chemist at DuPont's DuPont Central Research, Jackson Laboratory in New Jersey, who in the summer of 1930, together with Wallace Carothers, Arnold Collins and F. B. Downing, made commercial Neoprene possible by producing a soft, plastic form of chloroprene that could be processed by the rubber industry. Early accounts of the development credited Julius Nieuwland with synthesizing the precursor divinylacetylene. Williams' contribution was the discovery that the rheological behavior of the product could be controlled by quenching the polymerization reaction with alcohol. He won the 1946 Charles Goodyear Medal. References 20th-century American chemists American polymer scientists and engineers 1894 births 1977 deaths {{US-chemist-stub ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Arnold M
Arnold may refer to: People * Arnold (given name), a masculine given name * Arnold (surname), a German and English surname Places Australia * Arnold, Victoria, a small town in the Australian state of Victoria Canada * Arnold, Nova Scotia United Kingdom * Arnold, East Riding of Yorkshire * Arnold, Nottinghamshire United States * Arnold, California, in Calaveras County * Arnold, Carroll County, Illinois * Arnold, Morgan County, Illinois * Arnold, Iowa * Arnold, Kansas * Arnold, Maryland * Arnold, Mendocino County, California * Arnold, Michigan * Arnold, Minnesota * Arnold, Missouri * Arnold, Nebraska * Arnold, Ohio * Arnold, Pennsylvania * Arnold, Texas * Arnold, Brooke County, West Virginia * Arnold, Lewis County, West Virginia * Arnold, Wisconsin * Arnold Arboretum of Harvard University, Massachusetts * Arnold Township, Custer County, Nebraska Other uses * Arnold (automobile), a short-lived English car * Arnold of Manchester, a former English coachbuilder ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Wallace Carothers
Wallace Hume Carothers (; April 27, 1896 – April 29, 1937) was an American chemist, inventor, and the leader of organic chemistry at DuPont, who was credited with the invention of nylon. Carothers was a group leader at the DuPont Experimental Station laboratory, near Wilmington, Delaware, where most polymer research was done. Carothers was an organic chemist who, in addition to first developing nylon, also helped lay the groundwork for neoprene. After receiving his Ph.D., he taught at several universities before he was hired by DuPont to work on fundamental research. He married Helen Sweetman on February 21, 1936. Carothers had been troubled by periods of depression since his youth. Despite his success with nylon, he felt that he had not accomplished much and had run out of ideas. His unhappiness was exacerbated by the death of his sister, and on April 28, 1937, he committed suicide by drinking potassium cyanide. His daughter, Jane, was born on November 27, 1937. Educati ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Patent
A patent is a type of intellectual property that gives its owner the legal right to exclude others from making, using, or selling an invention for a limited period of time in exchange for publishing an sufficiency of disclosure, enabling disclosure of the invention."A patent is not the grant of a right to make or use or sell. It does not, directly or indirectly, imply any such right. It grants only the right to exclude others. The supposition that a right to make is created by the patent grant is obviously inconsistent with the established distinctions between generic and specific patents, and with the well-known fact that a very considerable portion of the patents granted are in a field covered by a former relatively generic or basic patent, are tributary to such earlier patent, and cannot be practiced unless by license thereunder." – ''Herman v. Youngstown Car Mfg. Co.'', 191 F. 579, 584–85, 112 CCA 185 (6th Cir. 1911) In most countries, patent rights fall under private la ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
