Mayenite
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Mayenite
Chlormayenite (after Mayen, Germany), Ca12Al14O32 4Cl2 is a rare calcium aluminium oxide mineral of cubic symmetry. It was originally reported from Eifel volcanic complex (Germany) in 1964. It is also found at pyrometamorphic sites such as in the Hatrurim Formation of Israel and in some burned coal dumps. It occurs in thermally altered limestone xenoliths within basalts in Mayen, Germany and Klöch, Styria, Austria. In the Hatrurim of Israel it occurs in thermally altered limestones. It occurs with calcite, ettringite, wollastonite, larnite, brownmillerite, gehlenite, diopside, pyrrhotite, grossular, spinel, afwillite, jennite, portlandite, jasmundite, melilite, kalsilite and corundum in the limestone xenoliths. In the Hatrurim it occurs with spurrite, larnite, grossite and brownmillerite. Synthetic Ca12Al14O33 and Ca12Al14O32(OH)2 are known, they are stabilized by moisture instead of chlorine. The formula can be written as a12Al14O32, which refers to the unique feature: ...
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Brownmillerite
Brownmillerite is a rare oxide mineral with chemical formula . It is named for Lorrin Thomas Brownmiller (1902–1990), chief chemist of the Alpha Portland Cement Company, Easton, Pennsylvania. Discovery and occurrence The chemical compound was first recognized in 1932 and named for the chemist who identified it. The naturally occurring mineral form of the compound was first recognized in 1964 for occurrences in the Bellerberg volcano, Ettringen, Mayen-Koblenz, Germany. At the type locality the mineral occurs within limestone blocks that are contained in a volcanic flow. The limestone blocks had undergone thermal metamorphism. The mineral also occurs in the thermally altered strata of the Hatrurim Formation of Israel. Minerals associated with brownmillerite in the Mayen locality include calcite, ettringite, wollastonite, larnite, mayenite, gehlenite, diopside, pyrrhotite, grossular, spinel, afwillite, jennite, portlandite and jasmundite. In an Austrian occurrence near K ...
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Ettringite
Ettringite is a hydrous calcium aluminium sulfate mineral with formula: . It is a colorless to yellow mineral crystallizing in the trigonal system. The prismatic crystals are typically colorless, turning white on partial dehydration. It is part of the ettringite-group which includes other sulfates such as thaumasite and bentorite.Ettringite-group
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Discovery and occurrence

Ettringite was first described in 1874 by , for an occurrence near the Ettringer ,
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Portlandite
Portlandite is a hydroxide-bearing mineral typically included in the oxide mineral class. It is the naturally occurring form of calcium hydroxide (Ca(OH)2) and the calcium analogue of brucite (Mg(OH)2). Occurrence Portlandite occurs in a variety of environments. At the type location in Northern Ireland it occurs as an alteration of calc–silicate rocks by contact metamorphism of larnite–spurrite. It occurs as fumarole deposits in the Vesuvius area. In Jebel Awq, Oman it occurs as precipitates from an alkaline spring emanating from ultramafic bedrock. In the Chelyabinsk coal basin of Russia it is produced by combustion of coal seams and similarly by spontaneous combustion of bitumen in the Hatrurim Formation of the Negev desert in Israel and the Maqarin area, Jordan. It also occurs in the manganese mining area of Kuruman, Cape Province, South Africa in the Kalahari Desert where it occurs as large crystals and masses. It occurs in association with afwillite, calcite, larnite, s ...
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Oxide Mineral
The oxide mineral class includes those minerals in which the oxide anion (O2−) is bonded to one or more metal alloys. The hydroxide-bearing minerals are typically included in the oxide class. The minerals with complex anion groups such as the silicates, sulfates, carbonates and phosphates are classed separately. Simple oxides: *XO **Periclase group ***Periclase ***Manganosite **Zincite group ***Zincite *** Bromellite ***Tenorite ***Litharge * **Cuprite **Ice * **Hematite group ***Corundum ***Hematite ***Ilmenite * **Rutile group ***Rutile ***Pyrolusite ***Cassiterite **Baddeleyite **Uraninite **Thorianite * **Spinel group ***Spinel ***Gahnite ***Magnetite ***Franklinite ***Chromite **Chrysoberyl **Columbite *Hydroxide subgroup: **Brucite **Manganite ** Romanèchite **Goethite group: ***Diaspore ***Goethite Nickel–Strunz Classification -04- Oxides IMA-CNMNC proposes a new hierarchical scheme (Mills et al., 2009). This list uses it to modify ...
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Melilite
Melilite refers to a mineral of the melilite group. Minerals of the group are solid solutions of several endmembers, the most important of which are gehlenite and åkermanite. A generalized formula for common melilite is ( Ca, Na)2( Al, Mg, Fe2+) SiOxygen.html" ;"title="Silicon">Si)Silicon.html" ;"title="Silicon.html" ;"title=" Al,Silicon">Si)Silicon">SiOxygen">O7]. Discovered in 1793 near Rome, it has a yellowish, greenish-brown color. The name derives from the Greek words meli (μέλι) "honey" and lithos (λίθους) "stone".The name refers to a group of minerals (melilite group) with chemically similar composition, nearly always minerals in åkermanite-gehlenite series. Minerals of the melilite group are sorosilicates. They have the same basic structure, of general formula ''A''2''B(T''2O7). The melilite structure consist of pairs of fused ''T''O4, where ''T'' may be Si, Al, B, in bow-tie form. Sharing one corner, the formula of the pair is ''T''2O7. These bow-ties a ...
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Jennite
Jennite is a calcium silicate hydrate mineral of general chemical formula: Ca9Si6O18(OH)6·8H2O. Jennite occurs as an alteration mineral in metamorphosed limestone and skarn. It typically occurs as vein and open space fillings as a late mineral phase. It also occurs in hydrated cement paste. A first specimen of jennite found in 1966 at the Crestmore quarries (Crestmore, Riverside County, California, US) was analysed and identified as a new mineral by Carpenter in 1966 (Carpenter, 1966). They named it in honor of its discoverer: Clarence Marvin Jenni (1896–1973) director of the Geological Museum at the University of Missouri. In contrast to the first analysis made by Carpenter, jennite does not contain appreciable amount of sodium when the Crestmore specimen was reexamined (Gard, 1977). The structure of jennite is made of three distinct modules: ribbons of edge-sharing calcium octahedra, silicate chains of wollastonite-type running along the b axis, and additional calciu ...
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Afwillite
Afwillite is a calcium hydroxide nesosilicate mineral with formula Ca3(SiO3OH)2·2H2O. It occurs as glassy, colorless to white prismatic monoclinic crystals. Its Mohs scale hardness is between 3 and 4. It occurs as an alteration mineral in contact metamorphism of limestone. It occurs in association with apophyllite, natrolite, thaumasite, merwinite, spurrite, gehlenite, ettringite, portlandite, hillebrandite, foshagite, brucite and calcite. It was first described in 1925 for an occurrence in the Dutoitspan Mine, Kimberley, South Africa and was named for Alpheus Fuller Williams (1874–1953), a past official of the De Beers diamond company. Afwillite is typically found in veins of spurrite and it belongs to the nesosilicate sub-class. It is monoclinic, its space group is P2 and its point group is 2. Formation of afwillite It is suggested that afwillite forms in fractured veins of the mineral spurrite. Jennite, afwillite, oyelite and calcite are all minerals that form in layers ...
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Spinel
Spinel () is the magnesium/aluminium member of the larger spinel group of minerals. It has the formula in the cubic crystal system. Its name comes from the Latin word , which means ''spine'' in reference to its pointed crystals. Properties Spinel crystallizes in the isometric system; common crystal forms are octahedra, usually twinned. It has no true cleavage, but shows an octahedral parting and a conchoidal fracture. Its hardness is 8, its specific gravity is 3.5–4.1, and it is transparent to opaque with a vitreous to dull luster. It may be colorless, but is usually various shades of red, lavender, blue, green, brown, black, or yellow. Some spinels are among the most famous gemstones; among them are the Black Prince's Ruby and the "Timur ruby" in the British Crown Jewels, and the "Côte de Bretagne", formerly from the French Crown jewels. The Samarian Spinel is the largest known spinel in the world, weighing . The transparent red spinels were called spinel-rubies or b ...
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Grossular
Grossular is a calcium-aluminium species of the garnet group of minerals. It has the chemical formula of Ca3Al2(SiO4)3 but the calcium may, in part, be replaced by ferrous iron and the aluminium by ferric iron. The name grossular is derived from the botanical name for the gooseberry, ''grossularia'', in reference to the green garnet of this composition that is found in Siberia. Other shades include cinnamon brown (cinnamon stone variety), red, and yellow. Grossular is a gemstone. In geological literature, grossular has often been called ''grossularite''. Since 1971, however, use of the term grossularite for the mineral has been discouraged by the International Mineralogical Association. Hessonite Hessonite or "cinnamon stone" is a common variety of grossular with the general formula: Ca3Al2Si3O12. The name comes from the grc, ἣσσων (hēssōn), meaning ''inferior''; an allusion to its lower hardness and lower density than most other garnet species varieties. It has a char ...
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Pyrrhotite
Pyrrhotite is an iron sulfide mineral with the formula Fe(1-x)S (x = 0 to 0.2). It is a nonstoichiometric variant of FeS, the mineral known as troilite. Pyrrhotite is also called magnetic pyrite, because the color is similar to pyrite and it is weakly magnetic. The magnetism decreases as the iron content increases, and troilite is non-magnetic.Vaughan, D. J.; Craig, J. R. "Mineral Chemistry of Metal Sulfides" Cambridge University Press, Cambridge: 1978. . Structure Pyrrhotite exists as a number of polytypes of hexagonal or monoclinic crystal symmetry; several polytypes often occur within the same specimen. Their structure is based on the NiAs unit cell. As such, Fe occupies an octahedral site and the sulfide centers occupy trigonal prismatic sites. Materials with the NiAs structure often are non-stoichiometric because they lack up to 1/8th fraction of the metal ions, creating vacancies. One of such structures is pyrrhotite-4C (Fe7S8). Here "4" indicates that iron vacancies ...
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Diopside
Diopside is a monoclinic pyroxene mineral with composition . It forms complete solid solution series with hedenbergite () and augite, and partial solid solutions with orthopyroxene and pigeonite. It forms variably colored, but typically dull green crystals in the monoclinic prismatic class. It has two distinct prismatic cleavages at 87 and 93° typical of the pyroxene series. It has a Mohs hardness of six, a Vickers hardness of 7.7 GPa at a load of 0.98 N, and a specific gravity of 3.25 to 3.55. It is transparent to translucent with indices of refraction of nα=1.663–1.699, nβ=1.671–1.705, and nγ=1.693–1.728. The optic angle is 58° to 63°. Formation Diopside is found in ultramafic (kimberlite and peridotite) igneous rocks, and diopside-rich augite is common in mafic rocks, such as olivine basalt and andesite. Diopside is also found in a variety of metamorphic rocks, such as in contact metamorphosed skarns developed from high silica dolomites. It is an important min ...
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