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Lixiviant
A lixiviant is a chemical used in hydrometallurgy to extract particular elements from its ore. One of the most famous lixiviants is cyanide, which is used in extracting 90% of mined gold. The combination of cyanide and air converts gold particles into a soluble salt. Once separated from the bulk gangue, the solution is processed in a series of steps to give the metal. Etymology The origin is the word 'lixiviate', meaning to leach or to dissolve out, deriving from the Latin ''lixivium''.The New English Dictionary A lixiviant assists in rapid and complete leaching, for example during in situ leach In-situ leaching (ISL), also called in-situ recovery (ISR) or solution mining, is a mining process used to recover minerals such as copper and uranium through boreholes drilled into a deposit, ''in situ''. In situ leach works by artificially disso ...ing. The metal can be recovered from it in a concentrated form after leaching. Further reading * References Metallurgical process ...
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In Situ Leach
In-situ leaching (ISL), also called in-situ recovery (ISR) or solution mining, is a mining process used to recover minerals such as copper and uranium through boreholes drilled into a deposit, ''in situ''. In situ leach works by artificially dissolving minerals occurring naturally in a solid state. For recovery of material occurring naturally in solution, see: Brine mining. The process initially involves the drilling of holes into the ore deposit. Explosive or pathways in the deposit for solution to penetrate. Leaching solution is pumped into the deposit where it makes contact with the ore. The solution bearing the dissolved ore content is then pumped to the surface and processed. This process allows the extraction of metals and salts from an ore body without the need for conventional mining involving drill-and-blast, open-cut or underground mining. Process In-situ leach mining involves pumping of a lixiviant into the ore body via a borehole, which circulates through the poro ...
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Hydrometallurgy
Hydrometallurgy is a technique within the field of extractive metallurgy, the obtaining of metals from their ores. Hydrometallurgy involve the use of aqueous solutions for the recovery of metals from ores, concentrates, and recycled or residual materials.Brent Hiskey "Metallurgy, Survey" in Kirk-Othmer Encyclopedia of Chemical Technology, 2000, Wiley-VCH, Weinheim. Processing techniques that complement hydrometallurgy are pyrometallurgy, vapour metallurgy, and molten salt electrometallurgy. Hydrometallurgy is typically divided into three general areas: *Leaching *Solution concentration and purification *Metal or metal compound recovery Leaching Leaching involves the use of aqueous solutions to extract metal from metal bearing materials which is brought into contact with a material containing a valuable metal. The first examples come from 11-12th centuries China where it was applied to extraction of copper and accounted for a significant share of total copper production. In the ...
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Chemical
A chemical substance is a form of matter having constant chemical composition and characteristic properties. Some references add that chemical substance cannot be separated into its constituent elements by physical separation methods, i.e., without breaking chemical bonds. Chemical substances can be simple substances (substances consisting of a single chemical element), chemical compounds, or alloys. Chemical substances are often called 'pure' to set them apart from mixtures. A common example of a chemical substance is pure water; it has the same properties and the same ratio of hydrogen to oxygen whether it is isolated from a river or made in a laboratory. Other chemical substances commonly encountered in pure form are diamond (carbon), gold, table salt ( sodium chloride) and refined sugar ( sucrose). However, in practice, no substance is entirely pure, and chemical purity is specified according to the intended use of the chemical. Chemical substances exist as solids, ...
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Cyanide
Cyanide is a naturally occurring, rapidly acting, toxic chemical that can exist in many different forms. In chemistry, a cyanide () is a chemical compound that contains a functional group. This group, known as the cyano group, consists of a carbon atom triple-bonded to a nitrogen atom. In inorganic cyanides, the cyanide group is present as the anion . Soluble salts such as sodium cyanide (NaCN) and potassium cyanide (KCN) are highly toxic. Hydrocyanic acid, also known as hydrogen cyanide, or HCN, is a highly volatile liquid that is produced on a large scale industrially. It is obtained by acidification of cyanide salts. Organic cyanides are usually called nitriles. In nitriles, the group is linked by a covalent bond to carbon. For example, in acetonitrile (), the cyanide group is bonded to methyl (). Although nitriles generally do not release cyanide ions, the cyanohydrins do and are thus rather toxic. Bonding The cyanide ion is isoelectronic with carbon monoxi ...
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Gold Extraction
Gold extraction refers to the processes required to extract gold from its ores. The great majority of gold is extracted from dilute ores using a combination of chemical processes. About 2000 tons are obtained from the earth annually, plus another 300 tons from recycling. Types of ore Gold occurs principally as a native metal, i.e., gold itself. Sometimes it is alloyed to a greater or lesser extent with silver, which is called electrum. Native gold can occur as sizeable nuggets, as fine grains or flakes in alluvial deposits, or as grains or microscopic particles (known as colour) embedded in rock minerals. Other forms of gold are the minerals calaverite (AuTe), aurostibnite (AuSb2), and maldonite (Au2Bi). These latter three, although rarer that native gold, can be slow to react with cyanide and thus difficult to process. Still other gold-containing ores include various tellurides ( sylvanite, nagyagite, petzite, and krennerite). Certain contaminants in ores can interfer ...
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Leaching (metallurgy)
Leaching is a process widely used in extractive metallurgy where ore is treated with chemicals to convert the valuable metals within into soluble salts while the impurity remains insoluble. These can then be washed out and processed to give the pure metal; the materials left over are commonly known as tailings. Compared to pyrometallurgy, leaching is easier to perform, requires less energy and is potentially less harmful as no gaseous pollution occurs. Drawbacks of leaching include its lower efficiency and the often significant quantities of waste effluent and tailings produced, which are usually either highly acidic or alkali as well as toxic (e.g. bauxite tailings). There are four types of leaching: # Cyanide leaching (e.g. gold ore) # Ammonia leaching (e.g. crushed ore) # Alkali leaching (e.g. bauxite ore) # Acid leaching (e.g. sulfide ore) Chemistry Leaching is done in long pressure vessels which are cylindrical (horizontal or vertical) or of horizontal tube form ...
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