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Isotopes Of Vanadium
Naturally occurring vanadium (23V) is composed of one stable isotope 51V and one radioactive isotope 50V with a half-life of 2.71×1017 years. 24 artificial radioisotopes have been characterized (in the range of mass number between 40 and 65) with the most stable being 49V with a half-life of 330 days, and 48V with a half-life of 15.9735 days. All of the remaining radioactive isotopes have half-lives shorter than an hour, the majority of them below 10 seconds, the least stable being 42V with a half-life shorter than 55 nanoseconds, with all of the isotopes lighter than it, and none of the heavier, have unknown half-lives. In 4 isotopes, metastable excited states were found (including 2 metastable states for 60V), which adds up to 5 meta states. The primary decay mode before the most abundant stable isotope 51V is electron capture. The next most common mode is beta decay. The primary decay products before 51V are element 22 (titanium) isotopes and the primary products after are el ...
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Vanadium
Vanadium is a chemical element; it has Symbol (chemistry), symbol V and atomic number 23. It is a hard, silvery-grey, malleable transition metal. The elemental metal is rarely found in nature, but once isolated artificially, the formation of an oxide layer (passivation (chemistry), passivation) somewhat stabilizes the free metal against further oxidation. Spain, Spanish-Mexico, Mexican scientist Andrés Manuel del Río discovered compounds of vanadium in 1801 by analyzing a new lead-bearing mineral he called "brown lead". Though he initially presumed its qualities were due to the presence of a new element, he was later erroneously convinced by French chemist Hippolyte Victor Collet-Descotils that the element was just chromium. Then in 1830, Nils Gabriel Sefström generated chlorides of vanadium, thus proving there was a new element, and named it "vanadium" after the Scandinavian goddess of beauty and fertility, Vanadís (Freyja). The name was based on the wide range of colors fo ...
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Alpha Decay
Alpha decay or α-decay is a type of radioactive decay in which an atomic nucleus emits an alpha particle (helium nucleus). The parent nucleus transforms or "decays" into a daughter product, with a mass number that is reduced by four and an atomic number that is reduced by two. An alpha particle is identical to the nucleus of a helium-4 atom, which consists of two protons and two neutrons. It has a charge of and a mass of , and is represented as ^_\alpha. For example, uranium-238 undergoes alpha decay to form thorium-234. While alpha particles have a charge , this is not usually shown because a nuclear equation describes a nuclear reaction without considering the electrons – a convention that does not imply that the nuclei necessarily occur in neutral atoms. Alpha decay typically occurs in the heaviest nuclides. Theoretically, it can occur only in nuclei somewhat heavier than nickel (element 28), where the overall binding energy per nucleon is no longer a maximum a ...
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Isotopes Of Vanadium
Naturally occurring vanadium (23V) is composed of one stable isotope 51V and one radioactive isotope 50V with a half-life of 2.71×1017 years. 24 artificial radioisotopes have been characterized (in the range of mass number between 40 and 65) with the most stable being 49V with a half-life of 330 days, and 48V with a half-life of 15.9735 days. All of the remaining radioactive isotopes have half-lives shorter than an hour, the majority of them below 10 seconds, the least stable being 42V with a half-life shorter than 55 nanoseconds, with all of the isotopes lighter than it, and none of the heavier, have unknown half-lives. In 4 isotopes, metastable excited states were found (including 2 metastable states for 60V), which adds up to 5 meta states. The primary decay mode before the most abundant stable isotope 51V is electron capture. The next most common mode is beta decay. The primary decay products before 51V are element 22 (titanium) isotopes and the primary products after are el ...
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Isotopes Of Calcium
Calcium (Ca) has 26 known isotopes, ranging from Ca to Ca. There are five stable isotopes (Ca, Ca, Ca, Ca and Ca), plus one isotope ( Ca) with such a long half-life that it is for all practical purposes stable. The most abundant isotope, Ca, as well as the rare Ca, are theoretically unstable on energetic grounds, but their decay has not been observed. Calcium also has a cosmogenic isotope, Ca, with half-life 99,400 years. Unlike cosmogenic isotopes that are produced in the air, Ca is produced by neutron activation of Ca. Most of its production is in the upper metre of the soil column, where the cosmogenic neutron flux is still strong enough. Ca has received much attention in stellar studies because it decays to K, a critical indicator of solar system anomalies. The most stable artificial isotopes are Ca with half-life 163 days and Ca with half-life 4.5 days. All other calcium isotopes have half-lives of minutes or less. Stable Ca comprises about 97% of natural calcium and is mai ...
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Isotopes Of Scandium
Naturally occurring scandium (21Sc) is composed of one stable isotope, 45Sc. Twenty-seven radioisotopes have been characterized, with the most stable being 46Sc with a half-life of 83.8 days, 47Sc with a half-life of 3.35 days, and 48Sc with a half-life of 43.7 hours and 44Sc with a half-life of 3.97 hours. All the remaining isotopes have half-lives that are less than four hours, and the majority of these have half-lives that are less than two minutes, the least stable being proton unbound 39Sc with a half-life shorter than 300 nanoseconds. This element also has 13 meta states with the most stable being 44m3Sc (t1/2 58.6 h). The isotopes of scandium range from 37Sc to 62Sc. The primary decay mode at masses lower than the only stable isotope, 45Sc, is beta-plus or electron capture, and the primary mode at masses above it is beta-minus. The primary decay products at atomic weights below 45Sc are calcium isotopes and the primary products from higher atomic weights are titan ...
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Isotopes Of Titanium
Naturally occurring titanium (22Ti) is composed of five stable isotopes; 46Ti, 47Ti, 48Ti, 49Ti and 50Ti with 48Ti being the most abundant (73.8% natural abundance). Twenty-one radioisotopes have been characterized, with the most stable being 44Ti with a half-life of 60 years, 45Ti with a half-life of 184.8 minutes, 51Ti with a half-life of 5.76 minutes, and 52Ti with a half-life of 1.7 minutes. All of the remaining radioactive isotopes have half-lives that are less than 33 seconds, and the majority of these have half-lives that are less than half a second. The isotopes of titanium range in atomic mass from 39.00  Da (39Ti) to 64.00 Da (64Ti). The primary decay mode for isotopes lighter than the stable isotopes (lighter than 46Ti) is β+ and the primary mode for the heavier ones (heavier than 50Ti) is β−; their respective decay products are scandium isotopes and the primary products after are vanadium isotopes. Two stable isotopes of titanium (47Ti and 49Ti) have ...
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Isotopes Of Chromium
Naturally occurring chromium (24Cr) is composed of four stable isotopes; 50Cr, 52Cr, 53Cr, and 54Cr with 52Cr being the most abundant (83.789% natural abundance). 50Cr is suspected of decaying by β+β+ to 50Ti with a half-life of (more than) 1.8×1017 years. Twenty-two radioisotopes, all of which are entirely synthetic, have been characterized, the most stable being 51Cr with a half-life of 27.7 days. All of the remaining radioactive isotopes have half-lives that are less than 24 hours and the majority of these have half-lives that are less than 1 minute. This element also has two meta states, 45mCr, the more stable one, and 59mCr, the least stable isotope or isomer. 53Cr is the radiogenic decay product of 53 Mn. Chromium isotopic contents are typically combined with manganese isotopic contents and have found application in isotope geology. Mn-Cr isotope ratios reinforce the evidence from 26Al and 107 Pd for the early history of the Solar System. Variations in 53Cr/52Cr and Mn ...
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Neutron Emission
Neutron emission is a mode of radioactive decay in which one or more neutrons are ejected from a Atomic nucleus, nucleus. It occurs in the most neutron-rich/proton-deficient nuclides, and also from excited states of other nuclides as in photodisintegration, photoneutron emission and beta-delayed neutron emission. As only a neutron is lost by this process the number of protons remains unchanged, and an atom does not become an atom of a different element, but a different isotope of the same element. Neutrons are also produced in the spontaneous fission, spontaneous and nuclear fission, induced fission of certain heavy nuclides. Spontaneous neutron emission As a consequence of the Pauli exclusion principle, nuclei with an excess of protons or neutrons have a higher average energy per nucleon. Nuclei with a sufficient excess of neutrons have a greater energy than the combination of a free neutron and a nucleus with one less neutron, and therefore can decay by neutron emission. Nuclei ...
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Vanadium-51 Nuclear Magnetic Resonance
Vanadium-51 nuclear magnetic resonance (51V NMR spectroscopy) is a method for the characterization of vanadium-containing compounds and materials. 51V comprises 99.75% of naturally occurring vanadium. The nucleus is quadrupolar with I = , which is not favorable for NMR spectroscopy, although its quadrupole moment and thus the linewidths are unusually small, while its magnetogyric ratio is relatively high (+7.0492 rad T−1s−1), so that 51V has 38% receptivity vs 1H. Its resonance frequency is close to that of 13C (gyromagnetic ratio = 6.728284 rad T−1s−1). The chemical shift dispersion is great as illustrated by this series: 0 for VOCl3 (chemical shift standard), −309 for VOCl2(O-i-Pr), −506 VOCl(O-i-Pr)2, and −629 VO(O-i-Pr)3. For vanadates, the parent orthovanadate and its conjugate acid absorb at −541 ( O4sup>3-) and 534 ( VO4sup>2-). For decavanadate Sodium decavanadate describes any member of the family of inorganic compounds with the formula Na6 10O28H2O)n. ...
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Radionuclide
A radionuclide (radioactive nuclide, radioisotope or radioactive isotope) is a nuclide that has excess numbers of either neutrons or protons, giving it excess nuclear energy, and making it unstable. This excess energy can be used in one of three ways: emitted from the nucleus as gamma radiation; transferred to one of its electrons to release it as a conversion electron; or used to create and emit a new particle (alpha particle or beta particle) from the nucleus. During those processes, the radionuclide is said to undergo radioactive decay. These emissions are considered ionizing radiation because they are energetic enough to liberate an electron from another atom. The radioactive decay can produce a stable nuclide or will sometimes produce a new unstable radionuclide which may undergo further decay. Radioactive decay is a random process at the level of single atoms: it is impossible to predict when one particular atom will decay. However, for a collection of atoms of a single nu ...
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Primordial Nuclide
In geochemistry, geophysics and nuclear physics, primordial nuclides, also known as primordial isotopes, are nuclides found on Earth that have existed in their current form since before Earth was formed. Primordial nuclides were present in the interstellar medium from which the Solar System was formed, and were formed in, or after, the Big Bang, by nucleosynthesis in stars and supernovae followed by mass ejection, by cosmic ray spallation, and potentially from other processes. They are the stable nuclides plus the long-lived fraction of radionuclides surviving in the primordial solar nebula through planet accretion until the present; 286 such nuclides are known. Stability All of the known 251 stable nuclides, plus another 35 nuclides that have half-lives long enough to have survived from the formation of the Earth, occur as primordial nuclides. These 35 primordial radionuclides represent isotopes of 28 separate elements. Cadmium, tellurium, xenon, neodymium, samarium, osmi ...
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Isomeric Transition
A nuclear isomer is a metastable state of an atomic nucleus, in which one or more nucleons (protons or neutrons) occupy excited state levels (higher energy levels). "Metastable" describes nuclei whose excited states have half-lives of 10−9 seconds or longer, 100 to 1000 times longer than the half-lives of the excited nuclear states that decay with a "prompt" half life (ordinarily on the order of 10−12 seconds). Some references recommend seconds to distinguish the metastable half life from the normal "prompt" gamma-emission half-life. Occasionally the half-lives are far longer than this and can last minutes, hours, or years. For example, the nuclear isomer survives so long (at least years) that it has never been observed to decay spontaneously. The half-life of a nuclear isomer can even exceed that of the ground state of the same nuclide, as shown by as well as , , , , and multiple holmium isomers. Sometimes, the gamma decay from a metastable state is referred ...
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